X-ray absorption experiments at Ce L₃ and M₅ edges and theoretical calculations demonstrate that in addition to the nanoceria charge stability, the formation of hydroxyl groups at the surface affects the chemical performance of nanomaterials.

Diamond properties down to the quantum-size region are still poorly understood. High-pressure high-temperature (HPHT) synthesis from chloroadamantane molecules allows precise control of nanodiamond size. Thermal stability and optical properties of nanodiamonds with sizes spanning range from <1 to 8 nm are investigated. It is shown that the existing hypothesis about enhanced thermal stability of nanodiamonds smaller than 2 nm is incorrect. The most striking feature in IR absorption of these samples is the appearance of an enhanced transmission band near the diamond Raman mode (1332 cm${}^{-1}$). Following the previously proposed explanation, we attribute this phenomenon to the Fano effect caused by resonance of the diamond Raman mode with continuum of conductive surface states. We assume that these surface states may be formed by reconstruction of broken bonds on the nanodiamond surfaces. This effect is also responsible for the observed asymmetry of Raman scattering peak. The mechanism of nanodiamond formation in HPHT synthesis is proposed, explaining peculiarities of their structure and properties.

Nanoparticles are ubiquitous in nature and are increasingly important for technology. They are subject to bombardment by ionizing radiation in a diverse range of environments. In particular, nanodiamonds represent a variety of nanoparticles of significant fundamental and applied interest. Here we present a combined experimental and computational study of the behaviour of nanodiamonds under irradiation by xenon ions. Unexpectedly, we observed a pronounced size effect on the radiation resistance of the nanodiamonds: particles larger than 8 nm behave similarly to macroscopic diamond (i.e. characterized by high radiation resistance) whereas smaller particles can be completely destroyed by a single impact from an ion in a defined energy range. This latter observation is explained by extreme heating of the nanodiamonds by the penetrating ion. The obtained results are not limited to nanodiamonds, making them of interest for several fields, putting constraints on processes for the controlled modification of nanodiamonds, on the survival of dust in astrophysical environments, and on the behaviour of actinides released from nuclear waste into the environment.

Consideration is given to the estimates for the strength of the consolidated material forming the bulk of the nucleus of comet 67P Churyumov–Gerasimenko and those for the strength of the surface material overlying the consolidated material at the sites of the first and last contact of the lander with the nucleus. The strength of the consolidated material was estimated by analyzing the terrain characteristics of the steep cliffs, where the material is exposed on the surface. Based on these estimates, the tensile strength of the material is in the range from 1.5 to 100 Pa; the shear strength, from ∼13 to ⩾30 Pa; and the compressive strength, from 30 to 150 Pa, possibly up to 1.5 kPa. These are very low strength values. Given the dependence of the measurement results on the size of the measured object, they are similar to those of fresh dry snow at –10°C. The (compressive) strength of the surface material at the site of the first touchdown of on the nucleus is estimated from the measurements of the dynamics of the surface impact by the spacecraft’s legs and the geometry of the impact pits as 1–3 kPa. For comparison with the measurement results for ice-containing materials in terrestrial laboratories, it needs to be taken into account that the rate of deformation by ’s legs is four orders of magnitude higher than that in typical terrestrial measurements, leading to a possible overestimation of the strength by roughly an order of magnitude. There was an attemp to put one of the MUPUS sensors into the surface material at the site of the last contact of with the nucleus. Noticeable penetration of the tester probe was not achieved that led to estimation of the minimum compressive strength of the material to be ⩾4 MPa4 This fairly high strength appears to indicate the presence of highly porous ice with grains “frozen” at contacts.

The present work focused on the experimental study of the performance of a scaled system of adsorbed natural gas (ANG) storage and transportation based on carbon adsorbents. For this purpose, three different samples of activated carbons (AC) were prepared by varying the size of coconut shell char granules and steam activation conditions. The parameters of their porous structure, morphology, and chemical composition were determined from the nitrogen adsorption at 77 K, X-ray diffraction (XRD), small-angle X-ray scattering (SAXS), and scanning electron microscopy (SEM) measurements. The methane adsorption data measured within the temperature range from 178 to 360 K and at pressures up to 25 MPa enabled us to identify the most efficient adsorbent among the studied materials: AC-90S. The differential heats of methane adsorption on AC-90S were determined in order to simulate the gas charge/discharge processes in the ANG system using a mathematical model with consideration for thermal effects. The results of simulating the charge/discharge processes under two different conditions of heat exchange are consistent with the experimentally determined temperature distribution over a scaled ANG storage tank filled with the compacted AC-90S adsorbent and equipped with temperature sensors and heat-exchanger devices. The amounts of methane delivered from the ANG storage system employing AC-90S as an adsorbent differ from the model predictions by 4–6%. Both the experiments and mathematical modeling showed that the thermal regulation of the ANG storage tank ensured the higher rates of charge/discharge processes compared to the thermal insulation.