The assurance of drinking water supply is one of the biggest emerging global challenges, especially in urban areas. In this respect, groundwater and its management in the urban environment are gaining importance. This paper presents the modeling of nitrogen load from the leaky sewer system and from agriculture and the impact of this pressure on the groundwater quality (nitrate concentration) in the urban aquifer located beneath the City of Ljubljana. The estimated total nitrogen load in the model area of 58 km² is 334 ton/year, 38% arising from the leaky sewer system and 62% from agriculture. This load was used as input into the groundwater solute transport model to simulate the distribution of nitrate concentration in the aquifer. The modeled nitrate concentrations at the observation locations were found to be on average slightly lower (2.7 mg/L) than observed, and in general reflected the observed contamination pattern. The ability of the presented model to relate and quantify the impact of pressures from different contamination sources on groundwater quality can be beneficially used for the planning and optimization of groundwater management measures for the improvement of groundwater quality.

Urban areas can significantly alter the quality status of aquifers if appropriate strategies to prevent and detect groundwater contamination are not implemented in time. The prevention of groundwater contamination should be a priority due to its potential long-term impact on the environment and the high cost of remediation. For effective and sustainable groundwater management, it is crucial to proactively monitor a wide range of compounds to prevent their spread, progression and increasing concentrations. This study is one of the few to analyse the trends of various urban groundwater contaminants (nitrate, sulphate, hexavalent chromium, pesticides, PCE and TCE) from a groundwater management perspective. Characteristic trends are assessed using linear regression and the Mann–Kendall method, while significant changes in trends are determined using the Darken and Pettitt tests. The time span of the analysed trends covers the transition period before and after the implementation of the Water Framework Directive (2000/60/EC) and the Groundwater Directive (2000/60/EC). This study confirms the effectiveness of enforcement measures to protect groundwater quality, as evidenced by several statistically significant decreasing trends. On the other hand, this study emphasises the importance of intervention-targeted sampling campaigns and the reporting of raw analytical values according to the ISO 11843 series of standards. This approach is essential to detect upward trends in emerging contaminants at an early stage and prevent them from reaching levels that could negatively impact the economy or even jeopardise the safety of drinking water supplies.

The isotope and elemental composition of tap water reflects its multiple distinct inputs and provides a link between infrastructure and the environment over a range of scales. For example, on a local scale, they can be helpful in understanding the geological, hydrogeological, and hydrological conditions and monitor the proper functioning of the water supply system (WSS). However, despite this, studies examining the urban water system remain limited. This study sought to address this knowledge gap by performing a 24 h multiparameter analysis of tap water extracted from a region where the mixing of groundwater between two recharge areas occurs. This work included measurements of temperature and electrical conductivity, as well as pH, δ²H, δ¹⁸O, d, δ¹³C_DIC, and ⁸⁷Sr/⁸⁶Sr ratios and major and trace elements at hourly intervals over a 24 h period. Although the data show only slight variations in the measured parameters, four groups were distinguishable using visual grouping, and multivariate analysis (Spearman correlation coefficient analysis, hierarchical cluster analysis, and principal components analysis). Finally, changes in the mixing ratios of the two sources were estimated using a linear mixing model. The results confirm that the relative contribution from each source varied considerably over 24 h.

Legislation addressing the quality of groundwater and increasing concerns over public health calls for the development of analytical methods that can produce accurate and precise results at the ppt level. Passive sampling has been recognised as a helpful tool in identifying various organic pollutants in groundwater, even when their presence had not yet been identified through conventional groundwater quality monitoring. The article presents an analytical method involving a simple and cost-effective passive sampling device using Zorflex^® activated carbon fibres (ACFs) for the qualitative monitoring of a broad range of organic pollutants in water in a single run. The applicability of the method developed was tested in three hydrogeological studies. In the first case, we present a non-targeted qualitative screening and a list of 892 different contaminants detected in the groundwater in Slovenia. In the second case, we discuss the presence and origin of organic compounds in the groundwater from a pilot area of the urban aquifer, Ljubljansko polje. The third case presents a comparison of results between passive and grab sampling. Passive sampling with ACFs confirmed the presence of a pollutant, even when it had not been previously detected through a quantitative method.

Urban water supply systems (WSS) are complex and challenging to manage since the properties of water in the WSS change from source to the end user over time. However, understanding these changes requires a more profound knowledge of the WSS. This study describes the urban water cycle within the WSS of Ljubljana, Slovenia, where different water parameters such as temperature, electrical conductivity, total alkalinity, δ²H, δ¹⁸O, and δ¹³C_DIC were monitored from September to November 2018. Altogether 108 samples were collected, including from the source (3) and at different levels of the WSS: wells (41), joint exits from water pumping stations (7), reservoirs (22), water treatment locations (2), drinking fountains (13), taps (19) and wastewater system (1). The data show that although the ranges of δ²H and δ¹⁸O values were small, each well is represented by a unique fingerprint when considering additional parameters. A statistically significant difference was observed between sampling months, and temperature and most parameters showed higher variability within the wells than across the WSS, suggesting a more unified WSS. Finally, based on δ¹³C_DIC values, a distinction could be made between river/groundwater interactions within the WSS and between shallower and deeper wells and their distance from the river bank.

Small decentralized water supply systems are often sensitive to local pollution and require a clear understanding of recharge conditions and the hydrodynamics within the water resource catchment. This study develops a conceptual hydrogeological model for the Šmarna Gora area based on geological mapping, long-term monitoring of chemical parameters, and stable isotope analyses (δ¹⁸O, δ²H) of precipitation and groundwater. The study was initiated in response to rising pollutant concentrations in the drinking water. Estimates of transit time (TT) and mean residence time (MRT) were used to characterize recharge, mixing processes, and differences between the SG and ZAVRH wells, the existing and alternative water supply wells. Isotope data show that the aquifer is predominantly recharged during colder periods and that Mediterranean air masses have become an increasingly important source of precipitation, suggesting a shift in precipitation patterns. The results indicate that SG has longer TT (6–8 months) and MRT (up to 1–2 years). In contrast, ZAVRH shows shorter TT and MRT (4–6 months), and lower pollutant concentrations. The hydrogeological regime in the catchment of the ZAVRH well is characterized by a dynamic, fast-flowing system with limited storage and more intensive dilution of contaminants by infiltrating water, whereas the catchment of the SG well functions as a deeper and more buffered aquifer with prolonged groundwater residence and a more direct hydraulic linkage to the contaminant source. The findings distinguish two hydrogeological regimes and provide a basis for planning water supply solutions and protection measures.