Optical properties of molecular beam epitaxially grown type II “W” shaped GaSb/AlSb/InAs/GaIn(As)Sb/InAs/AlSb/GaSb quantum wells (QWs) designed for the active region of interband cascade lasers have been investigated. Temperature dependence of Fourier-transformed photoluminescence and photoreflectance was employed to probe the effects of addition of arsenic into the original ternary valence band well of GaInSb. It is revealed that adding arsenic provides an additional degree of freedom in terms of band alignment and strain tailoring and allows enhancing the oscillator strength of the active type II transition. On the other hand, however, arsenic incorporation apparently also affects the structural and optical material quality via generating carrier trapping states at the interfaces, which can deteriorate the radiative efficiency. These have been evidenced in several spectroscopic features and are also confirmed by cross-sectional transmission electron microscopy images. While arsenic incorporation into type II QWs is a powerful heterostructure engineering tool for optoelectronic devices, a compromise has to be found between ideal band structure properties and high quality morphological properties.

The optical gain spectrum has been investigated theoretically for various designs of active region based on InAs/GaInSb quantum wells—i.e., a type II material system employable in interband cascade lasers (ICLs) or optical amplifiers operating in the mid-infrared spectral range. The electronic properties and optical responses have been calculated using the eight-band k·p theory, including strain and external electric fields, to simulate the realistic conditions occurring in operational devices. The results show that intentionally introducing a slight nonuniformity between two subsequent stages of a cascaded device via the properly engineered modification of the type II quantum wells of the active area offers the possibility to significantly broaden the gain function. A −3 dB gain width of 1 µm can be reached in the 3–5 µm range, which is almost an order of magnitude larger than that of any previously reported ICLs. This is a property strongly demanded in many gas-sensing or free-space communication applications, and it opens a way for a new generation of devices in the mid-infrared range, such as broadly tunable single-mode lasers, mode-locked lasers for laser-based spectrometers, and optical amplifiers or superluminescent diodes which do not exist beyond 3 µm yet.

We show that in inverted HgTe quantum wells, the application of a strong in-plane magnetic field restores the normal sequence of the subbands, thus transforming the system from a topological insulator into a normal insulator phase. The transformation consists of two consecutive quantum phase transitions due to the large Zeeman splitting of electron states. On the other hand, due to the negligible Zeeman splitting of hole states, the intermediate phase between the transitions is semimetallic. Both phase transitions and the semimetallic phase have already been observed, and our theory allows for a consistent interpretation of the experimental results.