In this work silica (SiO2) and sulfonic acid-functionalized silica (sul-SiO2) were synthesized by sol–gel method from tetraethoxysilane (TEOS) and 3-mercatopropyltrimethoxysilane (MPTMS) with various ratios between them. The synthesized materials were characterized by x-ray diffraction (XRD) for crystalline structure, Brunauer–Emmet–Teller (BET) specific surface area analysis, transmission electronic microscopy (TEM) and dynamic light scattering (DLS) for particle size analysis, and ion exchange capacity (IEC) for determining sulfur content in Sul-SiO2 materials. The initial results showed that the average particle size of amorphous SiO2 and Sul-SiO2 at different TEOS: MPTMS ratios are in narrow distribution with average diameter about 20–30 nm. The particle size of Sul-SiO2 is almost unaffected by the content of MPTMS while IEC depends strongly on it. Composite membranes of 60 μm thickness were successfully prepared from blending of poly(vinylidene fluoride) (PVDF) and synthesized amorphous SiO2. It was shown that the latter may be used as a reinforced phase for composite membrane electrolytes based on PVDF.

The main aim of this study is to investigate Aganonerion polymorphum leaf-ethyl acetate extract (APL-EAE) and its inhibiting effect for steel in ethanol fuel blend. The immersion test, electrochemical and surface analysis techniques were successfully carried out in this research. Scanning electron microscope images indicated that the ethanol fuel blend induced pitting corrosion of steel. Remarkably, the surface of the sample containing 1000 ppm APL-EAE is smoother than the others submerged in different conditions. The electrochemical impedance spectroscopy result shows that APL-EAE has formed a good protective layer, preventing corrosive factors from hitting the steel surface. The potentiodynamic polarization data argue that the corrosion inhibition efficiency was strengthened with the increase of APL-EAE concentration. The Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy demonstrated less intensity of Fe peaks, higher intensity of C_1s peak and the appearance of organic peaks (N_1s, P_2p, O_1s) from specimens with and without APL-EAE addition. Therefore, the results suggest the formation of the protective film on steel surface and affirm that APL-EAE has served as an effective corrosion inhibitor for steel in ethanol fuel blend.

Battery Thermal Management System (BTMS) is crucial to maintain peak temperature and temperature difference of lithium-ion battery pack in appropriate range, thus ensuring best performance, extended cycle life and safety. Liquid cooling BTMS is extensively researched for prismatic cells, but only a few studies are present on application of liquid cooling BTMS for cylindrical cells. Further, existing studies on liquid cooling for cylindrical cells majorly focus on effect of flowrate, flow direction, and number of channels. In this study, a novel mini-channel cooling plate-based liquid cooling BTMS is proposed for a battery pack of 20 cells. Computational fluid dynamics (CFD)-based numerical analysis was performed on three-dimensional model of battery pack to investigate effects of parameters associated with cooling plate and mini-channel design, flow characteristics, and battery arrangement on temperature uniformity, heat removal rate, parasitic power consumption and weight of the battery pack. The study concluded that installation of aluminum cylindrical enclosure on cells could drastically enhance heat removal and temperature uniformity. Altering flow directions in mini-channel could enhance thermal performance. The research demonstrated that for case 2d (inlet and outlet are staggered in each cooling plate), the temperature difference can be reduced by 16.5% when compared to unidirectional flow. Mini-channel with square cross section offers better heat removal and fewer flow resistance compared to circular and elliptical. Although converging mini-channels offer better thermal performance, it drastically increases the pumping power. The battery pack was successful in limiting peak temperature and temperature difference to 303.26 K and 1.98 K, respectively, for 4 C discharge rate.