Since rigid polyurethane (PU) foams are one of the most effective thermal insulation materials with widespread application, it is an urgent requirement to improve its fire retardancy and reduce the smoke emission. The current work assessed the fire behavior of PU foam with non-halogen fire retardants system, containing histidine (H) and modified graphene oxide (GO_A). For investigated system, three loadings (10, 20, and 30 wt.%) were used. The Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), thermogravimetric analysis, cone calorimetry (CC) and smoke density chamber tests as well as pre- and post-burning morphological evaluation using scanning electron microscope (SEM) were performed. Moreover, TGA combined with FT-IR was conducted to determine the substances, which could be evolved during the thermal decomposition of the PU with fire retardant system. The results indicated a reduction in heat release rate (HRR), maximum average rate of heat emission (MAHRE), the total heat release (THR) as well as the total smoke release (TSR), and maximum specific optical density (Ds_max) compared to the polyurethane with commercial fire retardant, namely ammonium polyphosphate (APP). A significantly improvement, especially in smoke suppression, suggested that HGO_A system may be a candidate as a fire retardant to reduce the flammability of PU foams.

Graphene and its derivatives have attracted scientists’ interest due to their exceptional properties, making them alluring candidates for multiple applications. However, still little is known about the properties of as-obtained graphene derivatives during long-term storage. The aim of this study was to check whether or not 14 months of storage time impacts graphene oxide flakes’ suspension purity. Complementary micro and nanoscale characterization techniques (SEM, AFM, EDS, FTIR, Raman spectroscopy, and elemental combustion analysis) were implemented for a detailed description of the topography and chemical properties of graphene oxide flakes. The final step was pH evaluation of as-obtained and aged samples. Our findings show that purified flakes sustained their purity over 14 months of storage.

This work presents the investigation of graphite and reduced graphene oxide (RGO) reflectance as an important parameter for electronic devices’ protection. These materials should protect electronic circuits against external as well as internal reflected radiation. The investigation was focused on comparing the reflectance of both materials on the metal layers. The measurements of constant electromagnetic parameters, such as permittivity and permeability, were carried out on pure materials without any additives, such as polystyrene foam, resin, wax, etc. The measurements were implemented in a coaxial line within the microwave frequency range from 100 MHz to 10 GHz. The measurements show a high value of reflected power, over 90% for graphite while RGO reflects only 80% of incident power. In addition, due to the half-wavelength effect in reduced graphene oxide, the reflection coefficient is reduced to 70%.