A photocatalytic system for decolorization of double azo reactive black 5 (RB5) dye and water disinfection of E. coli was developed. Sol gel method was employed for the synthesis of Fe-TiO₂ photocatalysts and were characterized using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS) and Brunauer–Emmett–Teller (BET) analysis. Results showed that photocatalytic efficiency was greatly influenced by 0.1 weight percent iron loading and 300 °C calcination temperature. The optimized reaction parameters were found to be the ambient temperature, working solution pH 6.2 and 1 mg g⁻¹ dose to completely decolorize RB5. The isotherm studies showed that RB5 adsorption by Fe-TiO₂ followed the Langmuir isotherm with maximum adsorption capacity of 42.7 mg g⁻¹ and K_ads 0.0079 L mg⁻¹. Under illumination, the modified photocatalytic material had higher decolorization efficiency as compared to unmodified photocatalyst. Kinetic studies of the modified material under visible light irradiation indicated the reaction followed the pseudo-first-order kinetics. The illumination reaction followed the Langmuir-Hinshelwood (L-H) model as the rate of dye decolorization increased with an incremental increase in dye concentration. The L-H constant K_c was 1.5542 mg L^–1∙h^–1 while K_ads was found 0.1317 L mg^–1. The best photocatalyst showed prominent percent reduction of E. coli in 120 min. Finally, 0.1Fe-TiO₂-300 could be an efficient photocatalyst and can provide a composite solution for RB5 decolorization and bacterial strain inhibition.

This paper presents the flexural analysis of functionally graded plates resting on elastic foundations using new two-dimensional (2D) and quasi-three-dimensional (quasi-3D) higher order shear deformation theories. The main interesting feature of this theory is that it proposes a new displacement field with undetermined integral variables which involves only five unknown functions, unlike other shear and normal deformation theories, hence making it easier to use. A parabolic transverse shear deformation shape function satisfying the zero shear stress conditions on the plate outer surfaces is considered. The elastic foundation follows the Pasternak mathematical model. The material properties change continuously across the thickness of the FG plate using different distributions: power law, exponential, and Mori–Tanaka models. The governing equations of FG plates subjected to sinusoidal and uniformly distributed loads are established through the principle of virtual works and then solved via Navier’s procedure. In this work, a detailed discussion on the influence of material composition, geometric parameters, stretching effect, and foundation parameters on the deflection, axial displacements, and stresses is given, and the obtained results are compared with those published in previous works to demonstrate the accuracy and the simplicity of the present formulations. The different obtained results were found to be in good agreement with the available solutions of other higher-order theories. The proposed model is able to represent the cross section warping in the deformed shape and to demonstrate the validity and efficiency of the approach, the findings reported herein prove that this theory is capable of predicting displacements and stresses more accurately than other theories, as its results are closer when compared to numerical methods reported in other literatures.

Preserving cultural heritage through monitoring, registering, and analyzing damage in historical architectural structures presents significant financial and logistical burdens. Developed approaches for monitoring and registering 4D (4-dimensional)-scanned range and raster images of damaged objects were investigated in a case study of historical Baron Palace in Egypt. In the methodology, we first prepared and observed the damaged historical models. The damaged historical models were scanned using a laser scanner at a predetermined date and time. Simultaneously, digital images of the models were captured (by a calibrated digital camera) and stored on a researcher’s tablet device. By observing and comparing the scanned models with the digital images, geometric defects and their extent are identified. Then, the observed data components were detected on the map. Then, damaged statue materials were investigated using system of energy dispersive (SEM; scanning electron microscope, Gemini Zeiss-Ultra 55) and XRF (X-ray fluorescence) spectroscopic analysis to identify the statue’s marble elements, and the results indicate that SEM-EDX and XRF analyses accurately identify major and minor compositions of the damaged statue. Then, the damaged models were registered in two stages. In the registration stages, the corresponding points were determined automatically by detecting the closest points in the clouds and ICP (iterative closest point) algorithm in RiSCAN. The point clouds (of the Palace and damaged statues) gave very detailed resolutions and more realistic images in RiSCAN, but it is a costly program. Finally, the accuracies of the registration tasks were assessed; the standard deviations are within acceptable limits and tend to increase irregularly as the number of polydata observations used in the registration calculations increase.

Use of fly ash by percent replacement of cement is considered as one of the most economical and effective methods for mitigating alkali-silica reaction (ASR) related distress in the concrete. However, fly ash has been proven to be somewhat variable in its effectiveness in inhibiting alkali-silica reactivity, principally because its composition depends on the coal properties from which it is derived. Typically class C fly ashes are not as efficient as class F ashes due to their higher calcium oxide content. Nevertheless, it is important to find out whether the lime content in the fly ash has linear effect on ASR distress mitigation and if the dosage of fly ash is more influential than type of fly ash. This research conducted extensive testing with nine different types of fly ashes with three in each category of fly ashes, class C, class F, and intermediate class. The results indicated that the effect of increased dosage of fly ash on ASR mitigation is linear for both low-lime and high-lime fly ashes and the dosage effect is more significant with rapid effect with high-lime fly ashes compared to low-lime fly ashes.

This study presents a hyperbolic shear deformation theory for free vibration of functionally graded plates on elastic foundations. The field of displacements is chosen based on the assumptions that axial and transverse displacements consist of components due to bending and shear. The components of the axial shear displacements give rise to the parabolic variation in the shear strain through the thickness, such that the shear stresses vanish on the plate boundaries. Therefore, the shear correction factor is not necessary. The material properties of the functionally graded plate are assumed to vary through the thickness according to the power law of the volume fraction of the constituents. The elastic foundation is modeled as a Pasternak foundation. The equations of motion are derived using Hamilton’s principle. The analytical solutions were established from Navier’s approach, and the results obtained are found to be in good agreement with the solutions of three-dimensional elasticity and with the solutions of the various plate theories. The effects of the power law index, the thickness ratio, and the foundation parameters on the natural frequency of the plates were also evaluated.