Dielectric materials with good thermal transport performance and desirable dielectric properties have significant potential to address the critical challenges of heat dissipation for microelectronic devices and power equipment under high electric field. This work reported the role of synergistic effect and interface on through-plane thermal conductivity and dielectric properties by intercalating the hybrid fillers of the alumina and boron nitride nanosheets (BNNs) into epoxy resin. For instance, epoxy composite with hybrid fillers at a relatively low loading shows an increase of around 3 times in through-plane thermal conductivity and maintains a close dielectric breakdown strength compared to pure epoxy. Meanwhile, the epoxy composite shows extremely low dielectric loss of 0.0024 at room temperature and 0.022 at 100 ℃ and 10⁻¹ Hz. And covalent bonding and hydrogen-bond interaction models were presented for analyzing the thermal conductivity and dielectric properties.

This Perspective outlines theoretical, simulation, and experimental studies linking electron emission and gas breakdown. Many studies have investigated field emission-driven microscale gas breakdown, including recent reviews [Garner et al., IEEE Trans. Plasma Sci. 48, 808–824 (2020); Fu et al., Plasma Res. Express 2, 013001 (2020)]. This Perspective focuses on generalizing field emission-driven microscale gas breakdown to consider the contribution of other forms of electron emission, specifically thermionic and space-charge limited. Recent theoretical studies have unified thermionic, field, and space-charge limited emission with and without collisions to derive “nexuses” where the individual solutions match, indicating transitions in the mechanisms. Reducing device size to nanoscale at atmospheric pressure leads to a transition from field emission to space-charge limited emission for nitrogen at ∼250 nm. This Perspective summarizes the derivation of these nexuses and future extensions. We next describe simulation and theoretical studies for field emission-driven microscale gas breakdown and highlight how the nexus theory may be integrated to account for temperature, space-charge, and pulse parameters. Finally, we summarize the development of optical techniques to assess microscale gas breakdown and recent nanoscale experiments at atmospheric pressure that suggest that space-charge may begin to contribute to field emission prior to gas breakdown. We highlight the combination of theory, simulation, and experiment to link electron emission and gas breakdown mechanisms across length, pressure, and temperature scales for applications that include vacuum electronics, pulsed power, and medicine.

Utilizing the latest SCAN-rVV10 density functional, we thoroughly assess the electrochemical properties of 35 Mo-based ordered double transition metal MXenes, including clean Mo₂MC₂ (M = Sc, Ti, V, Zr, Nb, Hf, Ta) and surface functionalized structures Mo₂MC₂T₂ (T = H, O, F and OH), for the potential use as anode materials in lithium ion batteries (LIBs). The first principles molecular dynamics simulations in combination with the calculations of the site adsorption preferences for Li atoms on all investigated MXenes reveal that both Li-saturated adsorption structures and theoretical capacities of Mo-based MXenes are fundamentally influenced by the surface terminations. We find that the adsorption of Li atoms on either –OH or –F functionalized MXenes is chemically unstable. In particular, the F-groups prefer to form a separate fluoride layer with Li atoms, detaching from the Mo₂MC₂ substrates. The Li atoms could form a stable single adsorption layer on the –H, –O and intrinsic MXenes surface, exhibiting theoretical capacities in the range from 121 mA h g⁻¹ to 195 mA h g⁻¹. Besides –F and –OH terminations, the remaining Mo-based MXenes also possess superior flat open circuit voltage (OCV) profiles with the most reversible storage capacity below 1.0 V during the charging/discharging cycles. We further predict the low barrier heights of Li-ion diffusion, at a range of 0.03–0.06 eV for most Mo-based MXenes except –O and –H terminations, exceeding that of graphene or Ti₃C₂. Furthermore, combining the Vineyard transition state theory (TST) with the phonon spectra obtained from density functional perturbation theory (DFPT), the mean planar diffusion coefficient is calculated to be 2 × 10⁻⁸ m² s⁻¹ at 300 K for intrinsic Mo₂MC₂ monolayers. Although the overall specific capacity is fundamentally restricted with the relatively heavy molecular mass of MXenes, we conclude that Mo-based structures, especially the intrinsic Mo₂MC₂ (M = Sc, Ti, V) monolayers, might be promising anode materials from the aspect of fast charging/discharging application for LIBs.

While multiple studies have explored the mechanism for DC and AC microscale gas breakdown, few have assessed the mechanism for pulsed voltage gas breakdown at the microscale. This study experimentally and analytically investigates gas breakdown for gap widths from 1 μm to 25 μm. Using an electrical-optical measurement system with a spatial resolution of 1 μm and a temporal resolution of 2 ns, we measure the breakdown voltages and determine breakdown morphology as a function of the gap width. An empirical fit shows that the breakdown voltage varies linearly with the gap distance at smaller gaps, agreeing with an analytical theory for DC microscale gas breakdown coupling field emission and Townsend avalanche that shows that the slope is a function of field emission properties. Furthermore, the curved breakdown paths captured between 5 μm and 10 μm demonstrate a similar effective length (∼11.7 μm) independent of the gap width, which is consistent with a “plateau” in breakdown voltage. This indicates that Townsend avalanche alone is insufficient to drive breakdown for these gaps and that ion enhanced field emission must contribute, in agreement with theory. The overall agreement of measured breakdown voltage with theoretical predictions from 1 μm to 25 μm indicates the applicability of DC microscale gas breakdown theory to pulsed breakdown, demonstrating that pulsed voltages induce a similar transition from Townsend avalanche to field emission as DC and AC voltages at the microscale.

With the continual miniaturization of electronic devices, there is an urgent need to understand the electron emission and the mechanism of electrical breakdown at nanoscale. For a nanogap, the complete process of the electrical breakdown includes the nano-protrusion growth, electron emission and thermal runaway of the nano-protrusion, and plasma formation. This review summarizes recent theories, experiments, and advanced atomistic simulation related to this breakdown process. First, the electron emission mechanisms in nanogaps and their transitions between different mechanisms are emphatically discussed, such as the effects of image potential (of different electrode's configurations), anode screening, electron space-charge potential, and electron exchange-correlation potential. The corresponding experimental results on electron emission and electrical breakdown are discussed for fixed nanogaps on substrate and adjustable nanogaps, including space-charge effects, electrode deformation, and electrical breakdown characteristics. Advanced atomistic simulations about the nano-protrusion growth and the nanoelectrode or nano-protrusion thermal runaway under high electric field are discussed. Finally, we conclude and outline the key challenges for and perspectives on future theoretical, experimental, and atomistic simulation studies of nanoscale electrical breakdown processes.

The decrease in electronic device size necessitates greater understanding of gas breakdown and electron emission at microscale to optimize performance. While traditional breakdown theory using Paschen’s law (PL), driven by Townsend avalanche, fails for gap distance d $$\lesssim $$≲ 15 μm, recent studies have derived analytic equations for breakdown voltage when field emission and Townsend avalanche drive breakdown. This study derives a new analytic equation that predicts breakdown voltage V_B within 4% of the exact numerical results of a previously derived theory and new experimental results at subatmospheric pressure for gap distances from 1–25 μm. At atmospheric pressure, V_B transitions to PL near the product of pressure and gap distance, pd, corresponding to the Paschen minimum; at lower pressures, the transition to PL occurs to the left of the minimum. We further show that the work function plays a major role in determining which side of the Paschen minimum V_B transitions to PL as pressure approaches atmospheric pressure while field enhancement and the secondary emission coefficient play smaller roles. These results indicate that appropriate combinations of these parameters cause V_B to transition to PL to the left of the Paschen minimum, which would yield an extended plateau similar to some microscale gas breakdown experimental observations.