In this paper, we report a cost-effective and scalable approach to produce highly homogeneous graphene and CNT-based silicone composites with potential applications in diverse fields of research, including biosensors and wearable electronics. This approach includes the fabrication of hybrid fillers based on few-layer graphene and CNTs by water solution blending and manufacturing of graphene/CNT/PDMS composites through calendering in a three-roll mill. The influence of processing parameters, the graphene/CNT ratio, and hybrid filler loading was thoroughly investigated, and the optimal parameters for producing hybrid composites with superior electrical and mechanical properties were found. It was also confirmed that the graphene/CNT hybrid system exhibits a synergistic effect of non-covalent interactions between graphene sheets and CNT sidewalls. This synergistic effect prevents the aggregation of graphene sheets, facilitates the dispersion of graphene and CNTs in the silicone matrix, and contributes to the superior properties of hybrid composites compared to composites with either of these fillers alone.
This review is dedicated to versatile silicone rubber composites based on carbon nanotube/graphene (CNT/G) hybrid fillers. Due to their unique mechanical, electrical, thermal, and biological properties, such composites have enormous potential for medical, environmental, and electronics applications. In the scope of this paper, we have explored CNT/graphene/silicone composites with a different morphology, analyzed the synergistic effect of hybrid fillers on various properties of silicone composites, and observed the existing approaches for the fabrication of hybrid composites with a seamless, assembled, and/or foamed structure. In conclusion, current challenges and future prospects for silicone composites based on CNTs and graphene have been thoroughly discussed.
SERS is a rapidly advancing and non-destructive technique that has been proven to be more reliable and convenient than other traditional analytical methods. Due to its sensitivity and specificity, this technique is earning its place as a routine and powerful tool in biological and medical studies, especially for the analysis of living cells and subcellular components. This paper reviewed the research progress of single-cell SERS that has been made in the last few years and discussed challenges and future perspectives of this technique. The reviewed SERS platforms have been categorized according to their nature into the following types: (1) colloid-based, substrate-based, or hybrid; (2) ligand-based or ligand-free, and (3) label-based or label-free. The advantages and disadvantages of each type and their potential applications in various fields are thoroughly discussed.
Nanographite oxide was synthesized from thermally expanded graphite in an environmentally friendly electrochemical manner, and its adsorption properties were examined in a batch system. Three two-parameter isotherm models (Langmuir, Freundlich, and Dubinin–Radushkevich) were applied for the experimental data processing, and the adsorption kinetics was estimated according to pseudo-first and pseudo-second order simplified kinetic models. The acquired results revealed that obtaned nanographite oxide can be employed as an inexpensive and efficient adsorbent for removal of acidic dyes from aqueous solutions.