The conversion efficiency of a solar cell depends on the degree of non-radiative recombination, and thus efficiency improvements can also be achieved by reducing Shockley–Read–Hall (SRH) recombination losses. This type of loss depends not only on the crystal quality, but also on the device structure. A clear separation of the contributions of these factors would improve our understanding of the control of non-radiative recombination. In this work, we discuss the reduction of the integrated SRH recombination rate in the depletion region ( ) by changing the emitter material, instead of fabricating a base layer with a higher crystal quality. First, we theoretically show that, by employing a suitable n-InGaP/p-GaAs heterojunction structure instead of a GaAs p–n homojunction, the integrated can be reduced, because a significant part of the depletion region in the heterojunction is located in the wide-gap emitter material, which has a lower intrinsic carrier density. Then, the effective SRH recombination coefficient in the depletion region ( ) is obtained from experiments, and the effect of the structural modification on is analyzed. We are able to clearly assess the effect of the heterojunction structure on the non-radiative recombination because the grown samples exhibit the same radiative recombination loss. The analysis reveals that, in suitable heterojunction solar cells with an emitter layer containing a low intrinsic carrier concentration, (and thus also ) is effectively reduced.
3 MeV proton irradiation effects on single junction and tandem solar cells have been investigated for the fluence range from to The overall radiation degradation of tandem cells was higher than single junction cells. It was observed that the spectral response of the GaAs bottom cell degrades more than the InGaP top cell. Proton irradiation decreases the longer wavelength spectral response more significantly than the shorter wavelength in both and cells. The difference in the degradation properties of and polarity InGaP solar cells is discussed. The radiation response of a tandem InGaP/GaAs cell is very nearly that which is predicted from the information of these two cells independently. The minority-carrier diffusion length in the base layer was determined from the spectral response data. The minority-carrier diffusion length damage coefficient was analyzed for and GaAs cells. The minority-carrier injection-enhanced annealing of radiation-induced defects in and cells were also observed.
18 February 2005 in Progress in Photovoltaics: Research and Applications