Remote sensing of suspended particulate matter, SPM, from space has long been used to assess its spatio-temporal variability in various coastal areas. The associated algorithms were generally site specific or developed over a relatively narrow range of concentration, which make them inappropriate for global applications (or at least over broad SPM range). In the frame of the GlobCoast project, a large in situ data set of SPM and remote sensing reflectance, R_rs(λ), has been built gathering together measurements from various coastal areas around Europe, French Guiana, North Canada, Vietnam, and China. This data set covers various contrasting coastal environments diversely affected by different biogeochemical and physical processes such as sediment resuspension, phytoplankton bloom events, and rivers discharges (Amazon, Mekong, Yellow river, MacKenzie, etc.). The SPM concentration spans about four orders of magnitude, from 0.15 to 2626 g·m⁻³. Different empirical and semi-analytical approaches developed to assess SPM from R_rs(λ) were tested over this in situ data set. As none of them provides satisfactory results over the whole SPM range, a generic semi-analytical approach has been developed. This algorithm is based on two standard semi-analytical equations calibrated for low-to-medium and highly turbid waters, respectively. A mixing law has also been developed for intermediate environments. Sources of uncertainties in SPM retrieval such as the bio-optical variability, atmospheric correction errors, and spectral bandwidth have been evaluated. The coefficients involved in these different algorithms have been calculated for ocean color (SeaWiFS, MODIS-A/T, MERIS/OLCI, VIIRS) and high spatial resolution (LandSat8-OLI, and Sentinel2-MSI) sensors. The performance of the proposed algorithm varies only slightly from one sensor to another demonstrating the great potential applicability of the proposed approach over global and contrasting coastal waters.

Increasing our knowledge on dissolved organic carbon (DOC) spatio-temporal distribution in the coastal ocean represents a crucial challenge for better understanding the role of these ecosystems in the global oceanic carbon cycle. The assessment of DOC concentration from the absorption properties of the colored part of the dissolved organic matter (a_cdom) was investigated from an extensive data set covering a variety of coastal environments. Our results confirmed that variation in the a_cdom(412) to DOC ratio (a*_cdom(412)) can be depicted from the CDOM spectral slope in the UV domain (S_275-295). They also evidenced that regional first order variation in both a*_cdom(412) and S_275-295 are highly correlated to variation in a_cdom(412). From these observations, generalized relationships for estimating a*_cdom(412) from S_275-295 or a_cdom(412) were parameterized from our development sites (N = 158; English Channel, French Guiana, Hai Phong Bay) and tested against an independent data set covering others coastal regions (N = 223; French Polynesia, Rhone River estuary, Gulf of Maine, Chesapeake Bay, Southern Middle Atlantic Bight) demonstrating the possibility to derive DOC estimates from in situ CDOM optical properties with an average accuracy of ~16% over very contrasted coastal environments (with DOC ranging from 50 to 250 µmol.L⁻¹). The applicability of these generalized approaches was evaluated in the context of ocean color remote sensing observation emphasizing the limits of S_275-295-based formulations and the potential for a_cdom-based approaches to represent a compelling alternative for assessing synoptic DOC distribution.

The Sentinel-3A satellite was launched on 16 February 2016 with the Ocean and Land Colour Instrument (OLCI-A) on-board for the study of ocean color. The accuracy of ocean color parameters depends on the atmospheric correction algorithm (AC). This processing consists of removing the contribution of the atmosphere from the total measured signal by the remote sensor at the top of the atmosphere. Five ACs: the baseline AC, the Case 2 regional coast color neural network AC, its alternative version, the Polymer AC, and the standard NASA AC, are inter-compared over two bio-optical contrasted French coastal waters. The retrieved water-leaving reflectances are compared with in situ ocean color radiometric measurements collected using an ASD FielSpec4 spectrometer. Statistical and spectral analysis were performed to assess the best-performing AC through individual (relative error (RE) at 412 nm ranging between 23.43 and 57.31%; root mean squared error (RMSE) at 412 nm ranging between 0.0077 and 0.0188) and common (RE(412 nm) = 24.15–50.07%; RMSE(412 nm) = 0.0081–0.0132) match-ups. The results suggest that the most efficient schemes are the alternative version of the Case 2 regional coast color neural network AC with RE(412 nm) = 33.52% and RMSE(412 nm) = 0.0101 for the individual and Polymer with RE(412 nm) = 24.15% and RMSE(412 nm) = 0.0081 for the common ACs match-ups. Sensitivity studies were performed to assess the limitations of the AC, and the errors of retrievals showed no trends when compared to the turbidity and CDOM.

Chlorophyll-a concentration (Chl-a) is a crucial parameter for monitoring the water quality in coastal waters. The principal aim of this study is to evaluate the performance of existing Chl-a band ratio inversion models for estimating Chl-a from Sentinel2-MSI and Sentinel3-OLCI observation. This was performed using an extensive in situ R_rs-Chl-a dataset covering contrasted coastal waters (N = 1244, Chl-a (0.03–555.99) µg/L), which has been clustered into five optical water types (OWTs). Our results show that the blue/green inversion models are suitable to derive Chl-a over clear to medium turbid waters (OWTs 1, 2, and 3) while red/NIR models are adapted to retrieve Chl-a in turbid/high-Chl-a environments. As they exhibited the optimal performance considering these two groups of OWTs, MuBR (multiple band ratio) and NDCI (Normalized Difference Chlorophyll-a Index)-based models were merged using the probability values of the defined OWTs as the blending coefficients. Such a combination provides a reliable Chl-a prediction over the vast majority of the global coastal turbid waters (94%), as evidenced by a good performance on the validation dataset (e.g., MAPD = 21.64%). However, our study further illustrated that none of the evaluated algorithms yield satisfying Chl-a estimates in ultra-turbid waters, which are mainly associated with turbid river plumes (OWT 5). This finding highlights the limitation of multispectral ocean color observation in such optically extreme environments and also implies the interest to better explore hyperspectral Rrs information to predict Chl-a.

The Sentinel-2A and Sentinel-2B satellites, with on-board Multi-Spectral Instrument (MSI), and launched on 23 June 2015 and 7 March 2017, respectively, are very useful tools for studying ocean color, even if they were designed for land and vegetation applications. However, the use of these satellites requires a process called “atmospheric correction”. This process aims to remove the contribution of the atmosphere from the total top of atmosphere reflectance measured by the remote sensors. For the purpose of assessing this processing, seven atmospheric correction algorithms have been compared over two French coastal regions (English Channel and French Guiana): Image correction for atmospheric effects (iCOR), Atmospheric correction for OLI ‘lite’ (ACOLITE), Case 2 Regional Coast Colour (C2RCC), Sentinel 2 Correction (Sen2Cor), Polynomial-based algorithm applied to MERIS (Polymer), the standard NASA atmospheric correction (NASA-AC) and the Ocean Color Simultaneous Marine and Aerosol Retrieval Tool (OC-SMART). The satellite-estimated remote-sensing reflectances were spatially and temporally matched with in situ measurements collected by an ASD FieldSpec4 spectrophotometer. Results, based on 28 potential individual match-ups, showed that the best performance processor is OC-SMART with the highest values for the total score S_tot (16.89) and for the coefficient of correlation R² (ranging from 0.69 at 443 nm to 0.92 at 665 nm). iCOR and Sen2Cor show the less accurate performances with total score S_tot values of 2.01 and 7.70, respectively. Since the size of the in situ observation platform can be significant compared to the pixel resolution of MSI onboard Sentinel-2, it can create bias in the pixel extraction process. Thus, to study this impact, we used different methods of pixel extraction. However, there are no significant changes in results; some future research may be necessary.

Recently, different algorithms have been developed to assess near-surface particulate organic matter (POC) concentration over coastal waters. In this study, we gathered an extensive in situ dataset representing various contrasted bio-optical coastal environments at low, medium, and high latitudes, with various bulk particulate matter chemical compositions (mineral-dominated, 50% of the data set, mixed, 40%, or organic-dominated, 10%). The dataset includes 606 coincident measurements of POC concentration and remote-sensing reflectance, R_rs, with POC concentrations covering three orders of magnitude. Twelve existing algorithms have then been tested on this data set, and a new one was proposed. The results show that the performance of historical algorithms depends on the type of water, with an overall low performance observed for mineral-dominated waters. Furthermore, none of the tested algorithms provided satisfactory results over the whole POC range. A novel approach was thus developed based on a maximum band ratio of R_rs (red/blue, red/yellow or red/green ratio). Based on the standard statistical metric for the evaluation of inverse models, the new algorithm presents the best performance. The root-mean square deviation for log-transformed data (RMSD_log) is 0.25. The mean absolute percentage difference (MAPD) is 37.48%. The mean bias (MB) and median ratio (MR) values are 0.54 μg L⁻¹ and 1.02, respectively. This algorithm replicates quite well the distribution of in situ data. The new algorithm was also tested on a matchup dataset gathering 154 coincident MERIS (MEdium Resolution Imaging Spectrometer) R_rs and in situ POC concentration sampled along the French coast. The matchup analysis showed that the performance of the new algorithm is satisfactory (RMSD_log = 0.24, MAPD = 34.16%, MR = 0.92). A regional illustration of the model performance for the Louisiana continental shelf shows that monthly mean POC concentrations derived from MERIS with the new algorithm are consistent with those derived from the 2016 algorithm of Le et al. which was specifically developed for this region.