Chlorophyll-a concentration (Chl-a) is a crucial parameter for monitoring the water quality in coastal waters. The principal aim of this study is to evaluate the performance of existing Chl-a band ratio inversion models for estimating Chl-a from Sentinel2-MSI and Sentinel3-OLCI observation. This was performed using an extensive in situ R_rs-Chl-a dataset covering contrasted coastal waters (N = 1244, Chl-a (0.03–555.99) µg/L), which has been clustered into five optical water types (OWTs). Our results show that the blue/green inversion models are suitable to derive Chl-a over clear to medium turbid waters (OWTs 1, 2, and 3) while red/NIR models are adapted to retrieve Chl-a in turbid/high-Chl-a environments. As they exhibited the optimal performance considering these two groups of OWTs, MuBR (multiple band ratio) and NDCI (Normalized Difference Chlorophyll-a Index)-based models were merged using the probability values of the defined OWTs as the blending coefficients. Such a combination provides a reliable Chl-a prediction over the vast majority of the global coastal turbid waters (94%), as evidenced by a good performance on the validation dataset (e.g., MAPD = 21.64%). However, our study further illustrated that none of the evaluated algorithms yield satisfying Chl-a estimates in ultra-turbid waters, which are mainly associated with turbid river plumes (OWT 5). This finding highlights the limitation of multispectral ocean color observation in such optically extreme environments and also implies the interest to better explore hyperspectral Rrs information to predict Chl-a.

Estimation of Chlorophyll-a concentration (Chl-a) across diverse aquatic systems using Moderate Resolution Imaging Spectroradiometer-Aqua (MODIS-A) data has posed challenges, particularly the inability of existing algorithms to maintain consistent accuracy across varying optical water conditions, from oligotrophic clear waters to highly turbid productive systems. Traditional Blue/Green ratio approaches often show limitations over optically complex waters where colored dissolved organic matter and suspended sediments interfere with phytoplankton signal detection. In contrast, Red/NIR (Near-Infrared) models perform relatively well in productive coastal domains but are less effective in open ocean waters where phytoplankton absorption is too weak to produce detectable signals in these longer wavelengths. To address these challenges, we developed a Combination Of Neural Network models for Estimating Chlorophyll-a over Turbid and clear waters (CONNECT model) based on the principle that different Optical Water Types (OWTs) require specialized bio-optical algorithms. The methodology involves the development of two Multi-Layer Perceptron (MLP) models (NN-Clear & NN-Turbid) that are trained and evaluated on a comprehensive in-situ dataset with simultaneous measurements of Remote Sensing Reflectance (R_rs) and Chl-a gathered in various environments from clear to ultra-turbid waters (N = 5,358) with Chl-a ranging between 0.017 and 838.24 µg.L^-1. These specialized models are then combined through a weighted blending approach to produce unified Chl-a estimates that adapts to the optical conditions of various water types. In particular, the algorithm merging process involves the use of probability values corresponding to 2 groups of Optical Water Types as the blending coefficients. Accuracy evaluations performed on both in-situ and matchup datasets indicate a remarkable advancement of the CONNECT model compared to the traditional Blue/Green approaches over different trophic conditions with an improvement of 49.65% on the matchup validation considering the Symmetric Signed Percentage Bias (SSPB) metric.

In this study, we characterized phytoplankton biomass variability in El Rincón, a shallow and biologically productive coastal region in the Patagonian Continental Shelf. We used as a proxy 7 years (2017–2024) of high-resolution Sentinel-3 OLCI satellite data to capture the fine scale spatio-temporal variability of Chl-a in this region. To obtain Chl-a concentration, we applied a regionally validated algorithm (MuRB&NDCI) which provides more accurate Chl-a estimates compared to traditional algorithms, particularly in optically complex waters. Self-organizing maps (SOM) neural network was applied to identify four distinct bio-geographical regions with unique bloom dynamics. The phenological estimates revealed that phytoplankton blooms typically initiate in fall (March), peak during winter (May–August), and are more pronounced near the Bahía Blanca Estuary (BBE), where nutrient and sediment inputs drive high productivity. The findings presented in this work highlight the utility of Optical Water Class–based algorithms for capturing the fine-scale spatiotemporal variability of Chl-a in coastal systems. This study advances our understanding of phytoplankton dynamics in El Rincón and underscores the importance of customized satellite-derived approaches for monitoring and managing productivity in shallow coastal environments.

The present study evaluates the influence of industrialization on suspended particulate matter (SPM) dynamics along the northern coast of Rio de Janeiro, focusing specifically on the Açu Port Industrial Complex (APIC). A 20-year MODIS-Aqua (1 km) dataset (2002–2022) was processed using the OC-SMART atmospheric correction. For SPM estimation, a retrieval approach for coastal turbid waters that integrates two optimized bio-optical algorithms based on Optical Water Types (OWTs) was developed. The validity of this approach was substantiated through the utilization of the GLORIA in situ dataset and satellite matchups, which demonstrated its robust performance across a range of turbidity conditions. Its main innovation lies in the OWT-based fusion of two optimized SPM models, enabling robust retrievals across diverse coastal optical conditions. Statistical analyses based on Census X11 decomposition and the Seasonal Mann–Kendall test revealed strong spatial and temporal variability, with SPM concentrations increasing by up to 60% near the APIC during the study period, coinciding with dredging, port expansion, and sediment disposal. These findings indicate a pronounced anthropogenic signal, while spatial and temporal correlation analyses demonstrated that sediment dispersion is consistently directed northward, primarily controlled by currents and wind forcing. The results indicate that industrial activities augment the supply of sediments, while natural hydrodynamic processes govern their dispersion and transport, emphasizing the impact of human pressures and physical drivers on coastal sediments.

Coastal ecosystems play essential ecological, social, and economic roles at the land-ocean interface and are highly sensitive to environmental changes, whether natural or human-induced. Monitoring these regions is crucial for developing sustainable, ecosystem-based environmental policies (UNESCO-IOC). Brazil, with approximately 8,000 kilometers of tropical and subtropical coastline, hosts diverse coastal and marine ecosystems. However, these areas face significant pressures, including climate change, urban expansion, intensive agriculture, and deforestation. Despite their importance, Brazil, like many coastal regions, lacks extensive, long-term in situ data to assess how these pressures impact biogeochemical quality. Ocean color remote sensing helps fill this data gap by continuously providing key biogeochemical variables—such as phytoplankton biomass, particulate and dissolved matter, and associated organic carbon stocks—for over 25 years. This study demonstrates how optimized ocean color data can offer a comprehensive view of coastal ecosystems' responses to human pressures on both land and ocean. Specifically, MODIS ocean color time series have been analyzed to identify trends in the biogeochemical properties of Brazilian coastal and shelf waters, including estuaries, bays, and major lagoons, over the past two decades (COCOBRAZ ANR FAPESP project). This work illustrates how ocean color data can be a major source of information for supporting the preservation and management of coastal ecosystems.