In the absence of high-quality hardwood timber resources, we have gradually turned our attention from natural forests to planted fast-growing forests. However, fast-growing tree timber in general has defects such as low wood density, loose texture, and poor mechanical properties. Therefore, improving the performance of wood through efficient and rapid technological processes and increasing the utilization of inferior wood is a good way to extend the use of wood. Densification of wood increases the strength of low-density wood and extends the range of applications for wood and wood-derived products. In this paper, the effects of ultrasonic and vacuum pretreatment on the properties of high-performance wood were explored by combining sonication, vacuum impregnation, chemical softening, and thermomechanical treatments to densify the wood; then, the changes in the chemical composition, microstructure, and mechanical properties of poplar wood before and after treatment were analyzed comparatively by FT-IR, XRD, SEM, and mechanical tests. The results showed that with ultrasonic pretreatment and vacuum impregnation, the compression ratio of high-performance wood reached its highest level and the MOR and MOE reached their maximums. With the help of this method, fast-growing softwoods can be easily prepared into dense wood materials, and it is hoped that this new material can be applied in the fields of construction, aviation, and automobile manufacturing.
Compared with other materials, polyethylene terephthalate (PET) has high transparency, excellent physical and mechanical properties in a wide temperature range and good hygiene and safety, so it is widely used in the packaging industry, especially in the packaging of beverages and foods. The optimization of PET bottles is mainly reflected in three aspects: material optimization, structure optimization and process optimization, among which there is much research on material optimization and process optimization, but there is no complete overview on structure optimization. A summary of structural optimization is necessary. Aiming at structural optimization, the finite element method is a useful supplement to the beverage packaging industry. By combining the computer-aided design technology and using finite element software for finite element simulation, researchers can replace the experimental test in the pre-research design stage, predict the effect and save cost. This review summarizes the development of PET bottles for beverage packaging, summarizes various optimization methods for preventing stress cracking in beverage packaging, and especially focuses on comparing and evaluating the effects of several optimization methods for packaging structure. Finally, the future development of all kinds of optimization based on structural optimization in the field of beverage packaging is comprehensively discussed, including personalized design, the combination of various methods and the introduction of actual impact factor calculation.
8 July 2019 in The Journal of Physical Chemistry B
The substrate of solar cells with high haze, transparent, flexible, green and low coatings will be needed in the future. This paper reports a method for ultraviolet-assisted delignification of wood in an alkaline solution environment to improve the transmittance of “transparent wood”. Scanning electron microscope (SEM), X-ray diffraction image (XRD), Fourier transform infrared (FTIR) spectroscopy and transmittance-haze and chemical composition analysis were used to explore the mechanisms underlying the effect of ultraviolet-assisted lignin modification on the optical properties of “transparent wood”. The results show that UV-assisted delignification accelerates the rate of removal of lignin and chromogenic groups, which in turn improves the optical properties of the “transparent wood”, with UV-assisted lignin modification for 2 h increasing the light transmission of the “transparent wood” by 20%. UV-assisted delignification for 4 h and impregnation resulted in “transparent wood” with a transparency of 71% and a haze of 90%. This report provides a rapid and easy method to prepare high-quality “transparent wood”. The “transparent wood” with high transmittance and high haze is a potential candidate for transparent solar substrates. Meanwhile, this method is enlightening for high quality, fast and green preparation of other derived functional materials based on lignin wood.
In the modern forestry, the demand for renewable and environmentally friendly wood protection is increasing. This paper reports a green method for preparing stable and self-cleaning superhydrophobic coating for wood protection by dripping polyvinyl alcohol cross-linked hollow silica nanoparticles on the surface of wood in combination with polydimethylsiloxane modification. The coating is based on a laminated structure with layers stacked on the surface of the wood and cured quickly with the assistance of UV. The coatings obtained on wood substrates with appropriate ratios have excellent superhydrophobic properties, with an optimum water contact angle of up to 160.4 ± 0.2°. The coating also exhibits good transparency in the UV–visible spectrum and a maximum transmittance of 91%. With transmission electron microscopy, the microscopic morphology of the self-assembled hollow silica nanoparticles was observed. Scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction were also applied to investigate the morphology and chemical composition of the coatings. A water contact angle of 151.5 ± 0.7° was maintained even after the abrasion tests with sandpaper at a distance of 300 cm. Meanwhile, the resultant coatings exhibit good self-cleaning properties apart from mechanical durability and chemical stability, which enables effective resistance to contamination. Evidenced by the abovementioned data, this composite coating is capable of optimizing the surface wettability of wood, offering a new dimension to the extensive and prolonged application of wood and wood-based products. Furthermore, considering the advantages of this method, it could also be used in other areas in the future, such as glass, solar substrates, and optical devices.