This work aims to synthesize a photocatalyst with high photocatalytic performances and explore the possibility of using it for antibiotic removal from wastewater. For that, the spinel ZnBi₂O₄ (ZBO) was produced with the co-precipitation method and its optical, dielectric, and electrochemical characteristics were studied. The phase has been determined and characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). For the ZBO morphology, a Scanning Electron Microscopy (SEM) has been used. Then, the optical and dielectric properties of ZBO have been evaluated by calculating refractive index n (λ), extinction coefficient (k), dissipation factor (tan δ), relaxation time (τ), and optical conductivity (σopt) using the spectral distribution of T(λ) and R(λ). An optical gap band of 2.8 eV was determined and confirmed. The electrochemical performance of ZBO was investigated and an n-type semiconductor with a flat band potential of 0.54 V_SCE was found. The photocatalytic efficiency of ZBO was investigated in order to degrade the antibiotic Cefixime (CFX) under different light source irradiations to exploit the optical properties. A high CFX degradation of approximately 89% was obtained under solar light (98 mW cm⁻²) only after 30 min, while 88% of CFX degradation efficiency has been reached after 2 h under UV irradiation (20 mW cm⁻²); this is in line with the finding of the optical characterizations. According to the obtained data, solar light assisted nanoparticle ZBO can be used successfully in wastewater to remove pharmaceutical products.

In many nations, particularly those experiencing water scarcity, novel approaches are being applied to clean wastewater. Heterogeneous photocatalysis is the most widely used of these approaches because it entails the decomposition of organic molecules into water and carbon dioxide, which is a more ecologically benign process. In our study, we studied the photocatalytic degradation process on the effluent flumequine. This treatment is made through a solar pilot reactor in the presence of immobilized titanium dioxide with three light intensities and two types of water as solvents. A variety of factors that might influence the rate of deterioration, such as flow rate, light intensity, and initial concentration, have been investigated. The maximal degradation of flumequine was achieved at more than 90% after 2.5 h under optimal conditions (an initial concentration of 5 mg/L, three lamp light intensities, and a flow rate of 29 L/h). By combining the oxidized agent H₂O₂ with this process, the photocatalytic activity was improved further to 97% under the same conditions. The mineralization of this product has also been tested using total organic carbon (TOC) analysis. A high mineralization rate has been recorded at around 50% for a high initial concentration (20 mg/L) at a flow rate of 126 L/h. The results demonstrated the highly effective removal of flumequine and the efficacy of this photocatalytic system.

Photocatalysis has been widely studied for environmental applications and water treatment as one of the advanced oxidation processes (AOPs). Among semiconductors that have been employed as catalysts in photocatalytic applications, bismuth sillenite crystals have gained a great deal of interest in recent years due to their exceptional characteristics, and to date, several sillenite material systems have been developed and their applications in photoactivity are under study. In this review paper, recent studies on the use of Bi-based sillenites for water treatment have been compiled and discussed. This review also describes the properties of Bi-based sillenite crystals and their advantages in the photocatalytic process. Various strategies used to improve photocatalytic performance are also reviewed and discussed, focusing on the specific advantages and challenges presented by sillenite-based photocatalysts. Furthermore, a critical point of certain bismuth catalysts in the literature that were found to be different from that reported and correspond to the sillenite form has also been reviewed. The effectiveness of some sillenites for environmental applications has been compared, and it has demonstrated that the activity of sillenites varies depending on the metal from which they were produced. Based on the reviewed literature, this review summarizes the current status of work with binary sillenite and provides useful insights for its future development, and it can be suggested that Bismuth sillenite crystals can be promising photocatalysts for water treatment, especially for degrading and reducing organic and inorganic contaminants. Our final review focus will emphasize the prospects and challenges of using those photocatalysts for environmental remediation and renewable energy applications.

Sillenite catalysts have shown efficient photocatalytic activity for the removal of various pollutants from water in previous studies, thus enhancing their activity by combining them with other materials will be very promising for environmental applications. In this context, an interesting hybrid system containing Polyaniline (PANI) as an adsorbent and Bi₁₂TiO₂₀ (BTO) sillenite as a catalyst was proposed in this work. Cefixime (CFX) has been selected as a pollutant for this study, and its removal was evaluated using PANI (adsorption), PANI and BTO (combined system) and the hybrid system Bi₁₂TiO₂₀/Polyaniline (BTO/PANI). First, the impact of PANI adsorption was investigated on its own; after that, the solution was filtered to separate the adsorbent from the liquid in order to re-treat the solution using photocatalysis (combining adsorption with photocatalysis). At the same time, a similar technique was used involving the hybrid system BTO/PANI. The results show that the hybrid system can remove a very high Cefixime concentration of 30 mg/L, almost 100%, within only 2 h, and this is better than previous investigations. These results indicate that it is possible to combine photocatalysis and adsorption processes to control water pollution.