The gasification behavior of pine wood sawdust was investigated in CO2 with different heating rates of 5, 10, 15, and 20 °C/min from room temperature to 1400 °C by thermogravimetric analysis (TGA) and mass spectrometry (MS). It was also examined under Ar to compare the differences observed under CO2 at heating rate of 10 °C/min. Kinetics of pine wood sawdust thermal decomposition was determined by the models of FWO, KAS and master plot method. TGA results revealed different reaction sections from pyrolysis to char gasification under CO2. The pyrolysis behavior was similar under CO2 and Ar and had a similar energy required value about 590 kJ/kg from 250 °C to 420 °C. CO, CH4, and H2 were the primary gases obtained from thermal decomposition, and the amounts of which in CO2 atmosphere were higher than those obtained in Ar. The average activation energy for pyrolysis under CO2 was 184.72 kJ/mol.
Steel tire cord and steel saw wire represent typical precision pearlitic steel wire rods of wire products; it is a very important solar energy material with a diameter about 50 μm. This paper mainly discusses the research progress of the wire rod drawing process, and its main contents are as follows: First section—the control of the wire rod surface quality is summarized, including the thickness of the surface decarburization layer, the phase composition and thickness of the surface iron oxide scale, and the removal of surface iron oxide scale. Then, the research progress of the wire rod water bath treatment process during sorbitization is summarized. In addition, the development of brass plating technology for steel wire is summarized, including copper plating technology, coating phase composition, etc. Furthermore, the development of steel wire drawing methods is summarized. Finally, the development of the dies used in steel wire drawings is summarized.
The heat transfer behavior of flying molten droplets during gas atomization significantly impacts the performance of metal powders, and the cooling, deformation, breakup, and defect formation processes of these flying droplets are closely interrelated. In this study, a mathematical model was developed by combining the k-ε turbulence model, the VOF model, and the solidification/melting model to determine the cooling and solidification process of a flying molten droplet. The relationship between the atomization parameters and the cooling rate of the molten droplet, as well as the mechanisms of hollow powder formation, was investigated. The results indicate that an increase in the initial temperature of the molten droplet resulted in a delay in its initial solidification time, while its cooling rate remained essentially unchanged. The cooling rate of the molten droplet increased with the increase in the gas velocity but decreased with the increase in the droplet diameter and gas temperature. Among these factors, the droplet diameter had the greatest impact on the cooling rate. During the solidification process, when the droplet’s surface layer was fully solidified, the trapped gas failed to escape and eventually became encapsulated within the solidified particle, resulting in the formation of hollow powder.