The melt flow, level fluctuation, temperature field, and solidification behavior coupled with electromagnetic stirring (EMS) effects in the continuous casting mold region of U71Mn steel bloom were numerically analyzed by commercial computational fluid dynamics (CFD) software named ANSYS FLUENT. The effects of submerged entry nozzle (SEN) structures and the installation methods for optimized four-port SEN on the flow pattern, level fluctuation, heat transfer and initial solidification behavior in a bloom mold loaded with EMS were investigated. The aim is to propose a better SEN condition for the big bloom casting of high railway steel. The water simulation experiments were conducted to show the flow characteristics under different SEN conditions and verify the numerical model of flow pattern. The experimental and numerical simulation results showed that the optimized four-port SEN with diagonal installation cannot only improve the flow pattern of the molten steel by alleviating the level fluctuation and reducing the impact pressure to the wall. It is also beneficial for temperature variation at both bloom surface and corner, as well as the local solidified shell thinning phenomena due to the elimination of impingement effect.

The flow, temperature, solidification, and solute concentration field in a continuous casting bloom mold were solved simultaneously by a multiphysics numerical model by considering the effect of in-mold electromagnetic stirring (M-EMS). The mold metallurgical differences between cases with and without EMS are discussed first, and then the solute transport model verified. Moreover, the effects of EMS current intensity on the metallurgical behavior in the bloom mold were also investigated. The simulated solute distributions were basically consistent with the test results. The simulations showed that M-EMS can apparently homogenize the initial solidified shell, liquid steel temperature, and solute element in the EMS effective zone. Meanwhile, the impingement effect of jet flow and molten steel superheat can be reduced, and the degree of negative segregation in the solidified shell at the mold corner alleviated from 0.74 to 0.78. However, the level fluctuation and segregation degree in the shell around the center of the wide and narrow sides were aggravated from 4.5 mm to 6.2 mm and from 0.84 to 0.738, respectively. With the rise of current intensity the bloom surface temperature, level fluctuation, stirring intensity, uniformity of molten steel temperature, and solute distribution also increased, while the growth velocity of the solidifying shell in the EMS effective zone declined and the solute mass fraction at the center of the computational outlet (z = 1.5 m) decreased. M-EMS with a current intensity of 600 A is more suitable for big bloom castings.

The solidification behavior and structure of continuous casting high rail U71Mn bloom, under different secondary cooling conditions and superheat, were numerically investigated using the Cellular Automaton-Finite Element (CAFE) model implemented with ProCAST software. Nail shooting and macro etch experiments of the bloom samples under different cooling conditions were conducted to verify the model of macroscopic solidification and structure. The results showed that the simulated results of the solidified shell and solidification structure are basically consistent with experimental results. The secondary cooling condition has little effect on the grain size and distribution of the bloom, while both the bloom surface and corner temperatures are higher and the temperature rise at the beginning of the air-cooling zone is smaller under the super-slow cooling condition. The percentage of center-equiaxed grains decreases from 44.6% to 20.1% and the grain average radius increases from 1.025 to 1.128 mm when the superheat increases from 15 to 40 K, with little change in the grain size occurring between 15 and 20 K. Moreover, for a step increase in the superheat of 5 K, the solidification end is lengthened by about 0.19 m and the surface temperature is enhanced by 3 K. The super-slow secondary cooling condition with the superheat controlled within 20 K is suitable for big-bloom casting.

The nucleation efficiency of substrates towards a specific polymer is usually based on empirical methods, which depend on the employed experimental conditions. A more quantitative method to study the efficiency of nucleating agents promoting polypropylene β-phase is reported here. When a polymer is dispersed into sufficiently small droplets, the overall crystallization kinetics is controlled by nucleation, as growth can be orders of magnitude faster than nucleation. Confinement of polypropylene containing the nucleating agent particles into micro-domains (i.e., droplets) within a polystyrene matrix allows the isolation of the nucleation process and the determination of the surface free energy difference, Δσ. This parameter describes the intrinsic nucleation efficiency of a particular nucleating agent. Isothermal crystallization measurements were performed for dispersed polypropylene droplets containing three nucleating agents which catalyze the formation of both α- and β-phase (N,N′-dicyclohexylterephthalamide, quinacridone quinone, and tris-2,3-dimethyl-hexylamide of trimesic acid), and the data were analyzed via a first-order kinetics model. According to the calculated Δσ values, the nucleating efficiency scale is DCHT > TATA > QQ for α-phase, while DCHT > QQ for β-phase, in spite of the higher total amount of β-crystals generated by QQ particles.

Well-oriented and crystalline WO₃ nanorod arrays (WNRAs) decorated with Mo were synthesized on fluorine doped tin oxide (FTO) substrate by the hydrothermal method. The effects of Mo doping, hydrothermal reaction time, and hydrothermal temperature on the morphologies and electrochromic properties of as-prepared WNRAs were studied thoroughly. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and chronoamperometry techniques were used to characterize the structures and properties of obtained WNRAs. The results demonstrate that the average diameter of the as-prepared WNRAs ranged from 30 to 70 nm. During the decoration of Mo on the WNRAs, the growth density of as-prepared WNRAs decreased and the surfaces became rough. However, the decorated Mo on WNRAs synthesized at 180 °C for 5 h with a Mo/W mole ratio of 1:40 exhibited better electrochromic properties than single WNRAs. They exhibited high optical modulation (61.7%), fast bleaching/coloring response times (3 s/9 s), high coloration efficiency values (73.1 cm²/C), and good cycling stability.