In the last few decades, in the lubricant industry, the request for new performing additives has been becoming imperative. In this scenario, control at the nanoscale can be the key factor for the improvement of more efficient nanolubricants. Herein, after a discussion about the nanoparticles’ four main lubrication mechanisms, considerable attention is devoted to the usage of reduced graphene oxide/graphene oxide (rGO/GO) nanosheets in tribology. Moreover, graphene surface functionalization is reviewed, also including unexplored results in the field of lubrication. As far as the literature is concerned, it can be postulated that rGO/GO nanosheets can reduce wear and friction. Wear reduction is obtained by deposition and film formation, while friction reduction is related more to the shear and lamination of the sheets on the contacting surfaces. Nevertheless, the two phenomena are interrelated and work in sync. In this context, it is of high importance to form a homogenous suspension for a continuous nanosheet supply after deposition and shearing. The focus of this review was placed on the main issues still to be overcome, e.g., the literature results in rationalization; dispersion stability enhancement; and finding the optimum concentration in the delicate balance of different components. Possible solutions for their efficient overcoming are eventually reported.

Nowadays, transition towards green chemistry is becoming imperative. In this scenario, an attractive perspective consists in the generation of CO through the electrochemical reduction of CO₂ under ambient conditions. This approach allows storage of the electrical energy from intermittent renewable sources in the form of chemical bonds, and simultaneously reduces greenhouse gas emissions, giving carbon a second chance of life. However, most catalysts adopted for this process, i.e., noble metal-based nanoparticles, still have several issues (high costs, low current densities, high overpotentials), and in the view of generating syngas through co-electrolysis of H₂O and CO₂, do not enable a widely tunable CO/H₂ ratio. Single-atom catalysts with N-doped carbon supports have been recently introduced to face these challenges. The following review aims to answer the demand for an extended and exhaustive analysis of the metal single-atom catalysts thus far explored for the electro-reduction of CO₂ in aqueous electrolyte solution. Moreover, focus will be placed on the objective of generating a syngas with a tunable CO/H₂ ratio. Eventually, the advantages of single-atom catalysts over their noble metal-based nano-sized counterparts will be identified along with future perspectives, also in the view of a rapid and feasible scaling-up.

Herein, additive manufacturing, which is extremely promising in different sectors, has been adopted in the electrical energy storage field to fabricate efficient materials for supercapacitor applications. In particular, Al₂O₃-, steel-, and Cu-based microparticles have been used for the realization of 3D self-assembling materials covered with reduced graphene oxide to be processed through additive manufacturing. Functionalization of the particles with amino groups and a subsequent "self-assembly" step with graphene oxide, which was contextually partially reduced to rGO, was carried out. To further improve the electrical conductivity and AM processability, the composites were coated with a polyaniline-dodecylbenzene sulfonic acid complex and further blended with PLA. Afterward, they were extruded in the form of filaments, printed through the fused deposition modeling technique, and assembled into symmetrical solid-state devices. Electrochemical tests showed a maximum mass capacitance of 163 F/g, a maximum energy density of 15 Wh/Kg at 10 A/g, as well as good durability (85% capacitance retention within 5000 cycles) proving the effectiveness of the preparation and the efficiency of the as-manufactured composites.

Nowadays, iron (II) selenide (FeSe), which has been widely studied for years to unveil the high-temperature superconductivity in iron-based superconductors, is drawing increasing attention in the electrical energy storage (EES) field as a supercapacitor electrode because of its many advantages. In this study, very small FeSe particles were synthesized via a simple, low-cost, easily scalable, and reproducible solvothermal method. The FeSe particles were characterized using cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) measurements, and electrochemical impedance spectroscopy (EIS), revealing enhanced electrochemical properties: a high capacitance of 280 F/g at 0.5 A/g, a rather high energy density of 39 Wh/kg and a corresponding power density of 306 W/kg at 0.5 A/g, an extremely high cycling stability (capacitance retention of 92% after 30,000 cycles at 1 A/g), and a rather low equivalent series resistance (R_ESR) of ~2 Ω.

This study presents a novel approach to the development of high-performance supercapacitors through 3D printing technology. We synthesized a composite material consisting of silver-doped reduced graphene oxide (rGO) and dodecylbenzenesulfonic acid (DBSA)-doped polyaniline (PANI), which was further blended with polylactic acid (PLA) for additive manufacturing. The composite was extruded into filaments and printed into circular disc electrodes using fused deposition modeling (FDM). These electrodes were assembled into symmetric supercapacitor devices with a solid-state electrolyte. Electrochemical characterization, including cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) tests, demonstrated considerable mass-specific capacitance values of 136.2 F/g and 133 F/g at 20 mV/s and 1 A/g, respectively. The devices showed excellent stability, retaining 91% of their initial capacitance after 5000 cycles. The incorporation of silver nanoparticles enhanced the conductivity of rGO, while PANI-DBSA improved electrochemical stability and performance. This study highlights the potential of combining advanced materials with 3D printing to optimize energy storage devices, offering a significant advancement over traditional manufacturing methods.