A method for printing continuous flax fiber-reinforced plastic (CFFRP) composite parts by five-axis three-dimensional (3D) printer, based on fused filament fabrication (FFF) technology, has been developed. FFF printed parts usually need supporting structures, have a stair step effect, and unfavorable mechanical properties. In order to address these deficiencies, continuous natural fiber prepreg filaments were first manufactured, followed by curved path planning for the model for generation of the G-code, and finally printed by a five-axis 3D printer. The surface quality of printed parts was greatly improved. The tensile strength and modulus of CFFRP increased by 89% and 73%, respectively, compared with polylactic acid (PLA) filaments. The flexural strength and modulus of the 3D-printed CFFRP specimens increased by 211% and 224%, respectively, compared with PLA specimens. The maximal curved bending force load and stiffness of the 3D-printed CFFRP specimens increased by 39% and 115%, respectively, compared with the flat slicing method. Advanced light structures, such as leaf springs, can be designed and manufactured by taking advantage of the favorable properties of these composites, which endow them with significant potential for application in the field of automobiles.

Continuous fiber-reinforced manufacturing has many advantages, but the fabrication cost is high and its process is difficult to control. This paper presents a method for printing fiber-reinforced composite on the common fused filament fabrication (FFF) platform. Polylactic Acid (PLA) and Polyethylene terephthalate (PET) fibers are used as printing materials. A spatial continuous toolpath planning strategy is employed to reduce the workload of post-processing without cutting the fiber. Experimental results show that this process not only enables the printing of models with complex geometric shapes but also supports material recycling and reuse. A material recovery rate of 100% for continuous PET fiber and 83% for PLA were achieved for a better environmental impact. Mechanical tests show that the maximum tensile strength of continuous PET fiber-reinforced thermoplastic composites (PFRTPCs) is increased by 117.8% when compared to polyamide-66 (PA66).

In a unique approach to develop a “green” solution for in-situ monitoring, low-cost inkjet-printed temperature sensors on paper substrate were fully integrated into natural fiber-reinforced lightweight components for which structural health monitoring is becoming increasingly important. The results showed that the sensors remained functional after the vacuum infusion process; furthermore, the integration of the sensors improved the mechanical integrity and stability of the lightweight parts, as demonstrated by tensile testing. To verify the qualification of the printed sensors for the target application, the samples were exposed to varying temperature and humidity conditions inside of a climate chamber. The sensors showed linear temperature dependence in the temperature range of interest (−20 to 60 °C) with a TCR ranging from 1.576 × 10⁻³ K⁻¹ to 1.713 × 10⁻³ K⁻¹. Furthermore, the results from the tests in humid environments indicated that the used paper-based sensors could be made almost insensitive to changes in ambient humidity by embedding them into fiber-reinforced lightweight materials. This study demonstrates the feasibility of fully integrating paper-based printed sensors into lightweight components, which paves the way towards integration of other highly relevant sensing devices, such as strain and humidity sensors, for structural health monitoring of smart, sustainable, and environmentally compatible lightweight composite materials.

The development of environmentally friendly, multifunctional conductive membranes is an ideal candidate for future new electronic components. Some cellulose-based electronic sensors have been studied, such as pressure sensors, hydrothermal sensors, flexible sensors, optoelectronic devices, and electrochemical energy storage, etc. However, there are very few studies on cellulose-based conductive materials in Joule heating. In this study, we adopted a simple and environmentally friendly silane crosslinking method to crosslink cellulose and graphene oxide (GO) together. The cellulose/GO hybrid membrane were characterized by FTIR, Raman, SEM, AFM, TGA, surface wettability, self-cleaning, surface resistance, Joule heating and other tests. Results showed that the covalent bond between cellulose and GO was formed by vinyltrimethoxysilane (VTMS), and GO was successfully cross-linked on the surface of the cellulose membrane. The cellulose/GO hybrid membrane has good thermal stability, strong hydrophobicity and self-cleaning properties. When the GO concentration was 3 w/w%, the Young's modulus of the film reached the maximum (47.38% higher than that of the original sample). In addition, it also exhibited extremely low surface resistivity (720.69 Ω), controllable Joule heating capability, extremely fast thermal response (heating process and cooling process within 5 s) and good electrothermal stability. It showed great potential in multi-functional electronic products such as electric heating electronic devices, electric heating sensors, and smart clothing in the future.

The most widely used 3D process, fused deposition modeling (FDM), has insufficient interlayer adhesion due to its layer-by-layer forming method. A support material is also essential for the hollow parts and cantilevers. Moreover, the polymer materials used have limited mechanical properties. These issues have restricted the application of FDM in high-performance fields. Continuous fiber-reinforced thermoplastic composites (CFRTPCs) have high mechanical properties and have recently become the focus of research in the field of 3D printing. This paper, using pipe parts as an example, proposes a hybrid of pure polymer (pure PLA used) and CFRTPC (flax fiber pre-impregnated filament) material to develop a printing method based on the outstanding mechanical properties of CFRTPC material. After studying the printing path planning algorithm, the CFRTPC filament is laid along the axial and radial directions on the surface of the polymer base to improve the printed parts’ properties. The method feasibility and algorithm accuracy are verified through the development of five-axis printing equipment with a double nozzle. Through the printed sample’s tensile, compression and bending tests, the results show that the tensile, compressive and bending properties of PLA pipe can be significantly enhanced by laying CFRTPC filament along the axial and radial directions of the pipe. To summarize, the introduction of CFRTPCs greatly improved the mechanical properties of the printed parts, and the implementation of our method provides an effective way to solve the defects of the FDM process.