Small-size cutting inserts for assembly cutters are widely used to manufacture a variety of parts for the aerospace, automotive and mechanical engineering industries. Due to their high hardness and chemical stability, cutting Al₂O₃-TiC ceramics significantly outperform hard alloys in machining heat-resistant and difficult-to-machine materials. However, grinding on CNC machines, the most common technology for manufacturing ceramic inserts, is associated with numerous issues when it comes to manufacturing small-size cutting inserts. For example, high cutting forces and high grinding wheel wear rates cause a rapid loss of dimensional accuracy and deterioration of the quality of the surface being machined, while the interference of the grinding wheel with the surface being treated imposes serious limitations on the geometry of the small-size ceramic inserts to be grinded. Here we show that Wire Electrical Discharge Machining (WEDM), which is a contactless and, thus, a more flexible method in terms of the size and geometrical properties of a workpiece to be machined, can be used as a replacement for grinding operations in machining small ceramic inserts. A composite of 70% aluminum oxide and 30% titanium carbide was chosen as a ceramic material because a further increase in the TiC fraction causes a marked decrease in wear resistance, while its decrease results in an undesirable loss of electrical conductivity. While in order to replace grinding with WEDM, WEDM has to be stable in the sense of occurring without frequent wire breakages, achieving WEDM stability is not an easy task due to the low electrical conductivity of Al₂O₃-TiC ceramics and high operational temperatures, which promote the diffusion of dielectric and electrode products in the surface layer of the cutting inserts being machined. These factors may lower the quality of the final product due to damage to the insert surface, marked increases in the roughness RA and in diffusion in the surface layer, which increases the friction coefficient and, hence, reduces the life of the manufactured cutting inserts. We have increased stability of the WEDM process by identifying and applying rational process conditions that lead to a reduced, by a factor of 2.63, roughness Ra and also a reduced, by a factor of 1.3, depth of craters. Performing a chemical and structural analysis, we found that the application of high energies combined with an increasing interelectrode gap (IG) (technological parameter SSol, a complex indicator that determines the speed of the wire electrode depending on the number of pulses per unit of time and the IG size, is set at 80, EDM3 technology) causes increased surface damage and contamination, while a small IG (SSol = 45, EDM1 technology) reduces the material removal rate due to contamination of the working zone between the surface being machined and the electrodes. After reducing the IG by lowering SSol from 80 to 45, the roughness Ra of 0.344 µm was achieved, which allows for replacing grinding operations with WEDM in machining hardening chamfers, front surfaces and, to a lesser degree, the rear and support surfaces of cutting inserts. In this case, when the IG is reduced to SSol = 45, the electroerosion products in the dielectric promote local breakdowns, which in turn produce a large number of deep craters which adversely affect the performance of cutting inserts. However, we found that a slight increase in SSol from 45 to 55 (EDM3 technology) significantly reduces the number of craters and lowers their depth from 50 μm to 37 μm. Although in this case the roughness grows to 0.534 μm due to increased discharge energy, the improved flushing of the IG and the reduced occurrence of local high-temperature breakdowns—evidenced by a decrease in the depth and number of deep craters formed due to current localization during short circuits—significantly reduced contamination of the surface layer and the crater formation rate. Therefore, WEDM can be recommended for use in machining reinforcing chamfers and, to a lesser degree, front surfaces. These considerations lead us to conclude that WEDM is a viable alternative to grinding in machining Al₂O₃-TiC ceramic cutting inserts of a small size and a complex shape, and that its application to manufacturing cutting inserts from poorly conductive cutting ceramics should be studied further.

The field of applied wire electrical discharge machining (WEDM) is rapidly expanding due to rapidly increasing demand for parts made of hard-to-machine materials. Hard alloys composed of WC, TiC and Co are advanced cutting materials widely used in industry due to the excellent combination of hardness and toughness, providing them obvious advantages over other cutting materials, such as cubic boron nitride, ceramics, diamond or high-speed steel. A rational choice of the WEDM modes is extremely important to ensure the dimensional quality of the manufactured cutting inserts, while roughness of the machined surface on the cutting edge is of great importance with regards to the application of wear-resistant coatings, which increases tool life. However, the stock control systems of CNC WEDM machines, which are based on assessment of electrical parameters such as amperage and voltage, are unable to timely detect conditions at which a threat of wire breakage appears and to prevent wire breakage by stopping the electrode feed and flushing out the interelectrode gap (IEG) when hard alloys with high heat resistance and low heat conductivity, such as WC, TiC and Co composites, are being machined, due to the inability to distinguish the working pulses and pulses that expend a part of their energy heating and removing electroerosion products contaminating the working zone. In this paper, the physicomechanical nature of the WEDM of hard alloy WC 88% + TiC 6% + Co 6% was investigated, and the possibility of using acoustic emission parameters for controlling WEDM stability and productivity were explored. Acoustic emission (AE) signals were recorded in octave bands with central frequencies of 1–3 and 10–20 kHz. It was found that at the initial moment, when the dielectric fluid is virtually free of contaminants, the amplitude of the high-frequency component of the VA signal has its highest value. However, as the contamination of the working zone by electroerosion products increases, the amplitude of the high-frequency component of the AE signal decreases while the low-frequency component increases in an octave of 1–3 kHz. By the time of the wire breakage, the amplitude of the high-frequency component in the octave of 10–20 kHz had reduced by more than 5-fold, the amplitude of the low-frequency component in the octave of 1–3 kHz had increased by more than 2-fold, and their ratio, coefficient Kf, decreased by 12-fold. To evaluate the efficiency of Kf as a diagnostic parameter, the quality of the surface being machined was investigated. The analysis of residual irregularities on the surface at the electrode breakage point showed the presence of deep cracks and craters typical of short-circuit machining. It was also found that the workpiece surface was full of deposits/sticks, whose chemical composition was identical to that of the wire material. The presence of the deposits evidenced heating and melting of the wire due to the increased concentration of contaminants causing short circuits. It was also shown that the wire breakage was accompanied by the “neck” formation, which indicated simultaneous impacts of the local heating of the wire material and tensile forces. Due to the elevated temperature, the mechanical properties the wire material are quickly declining, a “neck” is being formed, and, finally, the wire breaks. At the wire breakage point, sticks/deposits of the workpiece material and electroerosion products were clearly visible, which evidenced a partial loss of the pulses’ energy on heating the electroerosion products and electrodes. A further increase in the contamination level led to short circuits and subsequent breakage of the wire electrode. It was shown that in contrast to the conventional controlling scheme, which is based on the assessment of amperage and voltage only, the analysis of VA signals clearly indicates the risk of wire breakage due to contamination of the working zone, discharge localization and subsequent short circuits. The monotonic dependence of WEDM productivity on AE parameters provides the possibility of adaptive adjustment of the wire electrode feed rate to the highest WEDM productivity at a given contamination level. As the concentration of contaminants increases, the feed rate of the wire electrode should decrease until the critical value of the diagnostic parameter Kf, at which the feed stops and the IEG flushes out, is reached. The link between the AE signals and physicomechanical nature of the WEDM of advanced cutting materials with high heat resistance and low heat conductivity in different cutting modes clearly shows that the monitoring of AE signals can be used as a main or supplementary component of control systems for CNC WEDM machines.

Propionamide (PA), an important pollutant emitted into the atmosphere from a variety of sources, is abundant in many areas worldwide, and could be involved in new particle formation (NPF). In this study, the enhancement of the H₂SO₄ (SA)-based NPF by PA was evaluated through investigating the formation mechanism of (PA)_m(SA)_n (m = 0–3 and n = 0–3) clusters using computational chemistry and kinetics modeling. Our study proved that the formation of all the PA-containing clusters is thermodynamically favorable. Furthermore, the O group in PA plays an important role in the clusters with more PA than SA, and the basicity of bases exerts a greater influence with an increasing amount of SA. We demonstrate that although the enhancing potential of PA is lower than that of the strongest enhancers of SA-based NPF such as methylamine (MA) and dimethylamine (DMA), PA can enhance the SA-based NPF at the parts per billion (ppb) level, which is typical for concentrations of C₃-amides in, for example, urban Shanghai (China). The monomer evaporation is the dominant degradation pathway for the (PA)_m(SA)_n clusters, which differs from that of the SA–DMA system. The formation rate of PA-containing clusters is comparable to the rate coefficients for PA oxidation by hydroxyl (OH) radicals, indicating that participating in the SA-based NPF is a crucial sink for PA.

This paper describes a framework for action recognition which aims to recognize the goals and activities of one or more human from a series of observations. We propose an approach for the human action recognition based on the 3D dense micro-block difference. The proposed algorithm is a two-stage procedure: (a) image preprocessing using a 3D Gabor filter and (b) a descriptor calculation using 3D dense micro-block difference with SVM classifier. At the first step, an efficient spatial computational scheme designed for the convolution with a bank of 3D Gabor filters is present. This filter intensifies motion using a convolution for a set of 3D patches and arbitrarily-oriented anisotropic Gaussian. For pre-processed frames, we calculate the local features such as 3D dense micro-block difference (3D DMD), which capture the local structure from the image patches at high scales. This approach is processing the small 3D blocks with different scales from frames which capture the microstructure from it. The proposed image representation is combined with fisher vector method and linear SVM classifier. We evaluate the proposed approach on the UCF50, HMDB51 and UCF101 databases. Experimental results demonstrate the effectiveness of the proposed approach on video with a stochastic textures background with comparisons of the state-of-the-art methods.