The development of nontoxic and biodegradable alginate-based materials has been a continual goal in biological applications. However, their hydrophilic nature and lack of spinnability impart water instability and poor mechanical strength to the nanofiber. To overcome these limitations, sodium alginate (SA) and waterborne polyurethane (WPU) were blended and crosslinked with calcium chloride; 30 wt % of SA exhibited good compatibility. Further addition of 10 wt % calcium chloride improved the water stability to an extremely humid region. Furthermore, the stress–strain curve revealed that the initial modulus and the elongation strength of the WPU/SA and WPU/CA blends increased with SA content, and the crosslinker concentration clearly indicated the dressing material hardness resulted from this simple blend strategy. The WPU/SA₃₀ electrospun nanofibrous blend contained porous membranes; it exhibited good mechanical strength with water-stable, water-absorbable (37.5 wt %), and moisture-permeable (25.1 g/m²–24 h) characteristics, suggesting our cost-effective material could function as an effective wound dressing material.

In this study, when deriving thermoplastic polyurethane (TPU), the researchers replaced 1,4-butanediol (1,4-BDO) with 1,3-butanediol (1,3-BDO) as a chain extender and examined how the structure of the chain extender affected the final polymers. Regarding the raw materials for polymerization, three types of commercial polyols with the same molecular weight (Mn = 1000 g/mol), namely, poly (butyl acrylate) (PBA), poly (tetramethylene ether) glycol (PTMG), and polycarbonate diol (PCDL) were used. These polyols were used in conjunction with butanediol and 4,4’-methylene diphenyl diisocyanate. Three groups of TPUs were successfully synthesized using one-shot solvent-free bulk polymerization. Compared with TPUs polymerized using 1,4-BDO, materials polymerized using 1,3-BDO are more transparent and viscous. Structural analysis revealed that no substantial differences between the final structures of the TPUs were present when different chain extenders were used. Thermal analysis indicated that compared with TPUs polymerized using 1,4-BDO, the glass transition temperature of those with 1,3-BDO was 15 °C higher. Examination of microphase separation in the structure by using morphological analysis revealed that compared with TPUs synthesized using 1,4-BDO, PBA, and PTMG synthesized using 1,3-BDO were relatively separated. PCDL synthesized using 1,3-BDO exhibited no morphological difference. Rheological analysis indicated PCDL synthesized using either 1,4-BDO or 1,3-BDO did not exhibit any obvious differences. In conclusion, TPUs synthesized using PCDL and 1,3-BDO exhibited thermal plasticity at room temperature (15–20 °C). Their basic application could be extended to the development of smart materials. In terms of further application, they could be used in shape memory and temperature-sensitive high molecular polymers.

The pre-experiment of the present study revealed that polyurethane (PU) synthesized using poly (hexamethylene carbonate) glycol (PHC) has high melt viscosity and is difficult to process. Therefore, poly (trimethylene carbonate) glycol (PTC) was employed to synthesize a PU product with low melt viscosity. First, four types of thermoplastic polyurethane (TPU) were formed through one-step solvent-free synthesis. TPU is presented in the format “TPU-X-Y,” with X representing the polyol (PTC or PHC, around 1000 molecular weight) and Y the chain extender (1,3-propane diol [PDO] or 1,4-butane diol [BDO]) used. The TPU was synthesized using a fixed molar ratio of (isocyanate):(polyol):(chain extender) = 2:1:1 and compared. The results indicated that chain entanglement often occurred among the long carbon chains of PHC. The synthesized TPU employed a property of PTC, namely converting polarity into reverse polarity in high temperatures, to resolve the high melt viscosity of TPU of the PHC series, which causes processing difficulties. The synthesized TPU-PTC-PDO exhibited favorable molecular arrangements. Given its polarity, TPU-PTC-PDO has outstanding tensile properties (strength at break: 41.10 ± 10.78 MPa; 100% modulus = 6.73 ± 0.12 MPa), making processing at lower temperatures (180 or 190 °C) feasible. With the inclusion of PTC, the synthesized polycarbonate TPU exhibits the advantages of polycarbonate and is suitable for a wide range of applications.