Cellulose nanofibrils (CNFs) have attracted much attention because of their renewability and potential biocompatibility. However, CNFs are extremely hydrophilic due to the presence of a large number of hydroxyl groups, limiting their use as a water-resistant material. In this work, we controlled the adsorption behavior of silica nanoparticles on the surface of CNFs by adjusting the synthesis conditions. The silica nanoparticle size and packing efficiency on the CNF surface could be controlled by varying the ammonium hydroxide and water concentrations. In addition, hexadecyltrimethoxysilane (HDTMS) was successfully grafted onto CNF or CNF/silica nanocomposite surfaces, and the quantitative content of organic/inorganic substances in HDTMS was analyzed through XPS and TGA. The HDTMS-modified CNF/silica nanocomposites were more advantageous in terms of hydrophobicity than the HDTMS-modified CNF composites. This is because the silica nanoparticles were adsorbed on the surface of the CNFs, increasing the surface roughness and simultaneously increasing the amount of HDTMS. As a result, the HDTMS-modified CNFs showed a water contact angle (WCA) of ~80°, whereas HDTMS-modified CNF/silica nanocomposites obtained superhydrophobicity, with a WCA of up to ~159°. This study can provide a reference for the expansion of recyclable eco-friendly coating materials via the adsorption of silica nanoparticles and hydrophobic modification of CNF materials.

Since the plastic-based multilayer films applied to food packaging are not recyclable, it is necessary to develop easily recyclable single materials. Herein, polypropylene (PP)-based cellulose nanofiber (CNF)/nanoclay nanocomposites were prepared by melt-mixing using a fixed CNF content of 1 wt %, while the nanoclay content varied from 1 to 5 wt %. The optimum nanoclay content in the PP matrix was found to be 3 wt % (PCN3), while they exhibited synergistic effects as a nucleating agent. PCN3 exhibited the best mechanical properties, and the tensile and flexural moduli were improved by 51% and 26%, respectively, compared to PP. In addition, the oxygen permeability was reduced by 28%, while maintaining the excellent water vapor permeability of PP. The improvement in the mechanical and barrier properties of PP through the production of PP/CNF/nanoclay hybrid nanocomposites suggested their possible application in the field of food packaging.

Polypropylene (PP) has poor oxygen barrier properties, therefore it is manufactured in a multi-layer structure with other plastics and metals, and has been widely used as a packaging material in various industries from food and beverage to pharmaceuticals. However, multi-layered packaging materials are generally low in recyclability and cause serious environmental pollution, therefore we have faced the challenge of improving the oxygen barrier performance as a uni-material. In this work, PP/nanoclay nanocomposites were prepared at nanoclay contents ranging from 0.8 to 6.4 wt% by the biaxial stretching method, performed through a sequential stretching method. It was observed that, as the draw ratio increased, the behavior of the agglomerates of the nanoclay located in the PP matrix changed and the nanoclay was dispersed along the second stretching direction. Oxygen barrier properties of PP/nanoclay nanocomposites are clearly improved due to this dispersion effect. As the biaxial stretching ratio and the content of nanoclay increased, the oxygen permeability value of the PP/nanoclay nanocomposite decreased to 43.5 cc·mm/m²·day·atm, which was reduced by about 64% compared to PP. Moreover, even when the relative humidity was increased from 0% to 90%, the oxygen permeability values remained almost the same without quality deterioration. Besides these properties, we also found that the mechanical and thermal properties were also improved. The biaxially-stretched PP/nanoclay nanocomposite fabricated in this study is a potential candidate for the replacement of the multi-layered packaging material used in the packaging fields.

In this study, a comparative life cycle assessment of three different products with reusable and single-use packaging for fresh food distribution was conducted. For the reusable packaging, one utilized a vacuum insulation panel (VIP) box made of recycled polyethylene terephthalate (r-PET), while the other employed expanded polyethylene (EPE). For comparison, a disposable box made of widely used expanded polystyrene (EPS) was selected. We analyzed the environmental impacts of production, transportation, reprocessing (reused boxes), and disposal in 18 impact categories. As a result of analyzing the actual reuse of 300 rounds of fresh food, the cumulative global warming potential (GWP) values of the VIP and EPE box were 136.58 kg carbon dioxide (CO₂) eq and 281.72 kg CO₂ eq, respectively, 87% and 74% lower than those of the EPS box. Additionally, the GWP values were the same as those of the EPS boxes when the VIP and EPE boxes were reused 7 and 12 times, respectively. The best-case scenario was revealed when the reusable packaging with the r-PET VIP was compared with the EPE and EPS boxes. In conclusion, reusable packaging is expected to contribute to the reduction in the environmental burden and better suit global environmental requirements for sustainable food distribution and related industries. In addition, our findings can inform policy and industry decisions to promote more sustainable practices in the food industry, contributing to the advancement of sustainability in this field.

The life cycle assessment (LCA) serves as a crucial tool for assessing the environmental impact of products, with recent emphasis on polyethylene terephthalate (PET) bottles. Our meta-analytical review of 14 LCA research papers (2010–2022) on PET bottles, aligned with PRISMA guidelines, spans six phases: raw material production (MP), bottle production (BP), distribution and transportation (DT), collection and transport (CT), waste management (WM), and environmental benefits (EB). Utilizing the global warming potential (GWP) as the indicator, our study harmonized data into a consistent functional unit, revealing an average emission of 5.1 kg CO₂ equivalent per 1 kg of PET bottles. Major contributors to global warming were identified across the MP, BP, and DT phases. While the MP and BP phases exhibited low variability due to uniform processes, the CT, WM, and EB phases displayed higher variability due to scenario considerations. A comparison with Korean environmental product declaration data affirmed the methodology’s practical utility. Our approach offers potential applicability in diverse product category assessments, emphasizing its relevance for informed decision-making in sustainable product development.