Overheating and overcharging are the core triggering conditions for the thermal runaway of lithium-ion batteries. Studying the behavioral differences of thermal runaway of lithium-ion batteries under these two conditions is crucial for the safety design and protection of lithium-ion batteries. In this study, we investigated the temperature, pressure, gas generation, and heat generation characteristics of lithium batteries under these two conditions. Under overheating conditions, the release of lattice oxygen in the cathode and the decomposition of the electrolyte trigger a self-catalytic reaction, generating CO2 (54.7%) and H2 (29.7%), with a total heat release of 17.6 kJ and a heat accumulation rate of 24.3 W, forming a local high-temperature core area. Under overcharging conditions, the voltage drop, capacity attenuation of 21.1% (2230→1762 mAh), and internal resistance surge (6→21 mΩ) reflect severe damage to the electrode. Accompanied by the oxygenation of the EC electrolyte (CO32− + C2H4↑), the gas production rate is faster. The middle pressure was 0.601 MPa, and the proportion of CO2 was 67.4%. However, the triggering of thermal runaway relies on the synergistic effect of internal electrochemical reactions and ohmic heat accumulation, resulting in a relatively low rate of energy accumulation.
This study explores the dynamic behavior and jet characteristics of underwater explosion (UNDEX) bubble oscillating near a rigid floating body using the arbitrary Lagrangian–Eulerian (ALE) method. Experiments on UNDEX bubble oscillating in a free field or oscillating near a rigid floating body in an explosion tank are used to validate the effectiveness of the ALE method in simulating the behaviors of high pressure bubble oscillating near a boundary in water. The numerical results are in good agreement with the experimental data. On this basis, the distribution of the field pressure and velocity of the oscillating bubble are further analyzed in detail. The evolution characteristics of the bubble jets are discussed for various values of the stand-off distance and explosion attack angle. The results reveal that a bubble produces two jet patterns for close stand-off distances (from γD=0.800 to γD=1.336) and attack angles of 0°, 45°, 75°, and 90°. The first bubble jet results in an annular splitting of the bubble, while the second jet is pointed toward the floating body. The aim of this study is to provide a reference for further understanding the jet dynamics of UNDEX bubble collapsing near a structure and the effective attack on ship sides.
The thermal runaway of lithium-ion batteries is a critical factor influencing their safety. Investigating the thermal runaway characteristics is essential for battery safety design. In this study, the thermal runaway characteristics of 18650 lithium-ion batteries under different SOCs were systematically analyzed by experiment and simulation. It was found that at high SOC (100%), the highly lithium state accelerated lattice oxygen release, promoted the formation of LiNiO and intensified electrolytic liquid oxygenation combustion, while at low SOC (20%), the reduction environment dominated, and the metal Ni and residual graphite were significantly enriched. Gas analysis shows that CO2 and H2 account for more than 80%, and their proportion is regulated by SOC. Temperature and pressure monitoring showed that the increase in SOC significantly increased the thermal runaway peak temperature (100% SOC up to 508.4 °C) and pressure (0.531 MPa).The simulation results show that when the battery pack is out of control, the ejection fire and explosion pressure wave are concentrated in the middle and upper region (overpressure up to 0.8 MPa). This study reveals the mechanism by which SOC affects the path of product and gas generation by regulating the oxidation/reduction balance, which lays a theoretical and simulation foundation for the safe design of batteries and the quantitative evaluation of thermal runaway.
To explore the interaction between underwater explosion bubbles and soil–water interface, a near soil–water interface underwater explosion model based on the arbitrary Lagrangian–Eulerian method was established in this work. The peak pressure of the shock wave, maximum bubble radius, and bubble evolution in free-field and bottom-charge underwater explosions determined from the proposed simulation were highly consistent with the experimental results, thereby validating the proposed numerical model. The effects of the explosion distance and amount of explosive charge on the bubble–soil surface interaction were evaluated. The results showed that the reflection coefficient of the soil–water interface was in the range of 1.204–1.250, suggesting that it was hardly affected by the explosion distance and amount of explosive charge. The attenuation coefficient of the saturated soil was found to be 1.058. With the decrease in the explosion distance, the period and maximum radius of the bubbles slightly increased, and soil deformation increased as the lower surface of the bubbles was closer to the soil surface. For explosion distances of 0.3 and 0.4 m, only an overall movement of the soil surface was observed. When the explosion distance was 0.2 m or lower, a powerful downward jet was generated upon the pulsation of the first bubble, resulting in craters and slender depressions in the soil. With the increase in the amount of explosive charge, the period and maximum radius of the bubbles increased, and soil deformation also increased. These findings are expected to help advance our understanding of underwater explosion dynamics.
Affected by the mining activities of the working face, the surrounding rock of the roadway is easily deformed and destroyed. For deep buried roadways, the deformation and destruction of the surrounding rock is particularly prominent. Under the influence of in situ stress fluctuation, 3−1103 tailgate of the Hongqinghe coal mine was in a complex stress environment with a maximum stress exceeding 20 MPa. Affected by mining stress, the roadway behind the working face was seriously deformed. In order to alleviate the deformation of the roadway, directional blasting and cutting measures for the 3−1103 tailgate were adopted in this paper. The mechanism of crack propagation in single-row to three-hole directional blasting was revealed by numerical simulation. The blasted rock was divided into three regions according to the crack condition. The numerical analysis of the cutting heights of 0 m, 10 m, 12 m, and 14 m, respectively, showed the stress peaks of different cutting heights and the deformation law of the surrounding rock. The pressure relief effect was the best at 14 m cutting height. At this time, the peak stress was 39 MPa with the smallest roadway deformation. Based on numerical simulation and theoretical analysis results, engineering tests were carried out. Field monitoring showed that the deformation of the roadway was inversely proportional to the roof cutting height. The higher the cutting height is, the more preferential the roadway is to reach the stable state. It can be concluded that directional blasting can change the surrounding rock structure, control the deformation of the roadway, and play a role in pressure relief. It provides a new measure to control roadway deformation.
It is of great significance to characterize the dynamics of underwater explosive bubbles in close proximity to mutually perpendicular walls for ensuring the safety of important underwater structures. In this paper, a dynamic experiment on underwater explosion bubbles was carried out near constructed mutually perpendicular walls. High-speed cameras were utilized to capture high-resolution images, while pressure sensors recorded pressure–time history curves. The main focus was on studying the evolution process of bubble morphology and pulse characteristics. When the position of the charge's center relative to the horizontal wall remained fixed, decreasing the distance between the charge's center and the vertical wall resulted in a reduction in the equivalent maximum radius of bubbles and an increase in its pulsation period. Additionally, the asymmetric collapse of bubbles on a single wall transformed into asynchronous collapse on two walls, with most collapsed bubbles tending to migrate and expand toward the corner formed by mutually perpendicular walls. The resulting jet from the collapse of bubbles exhibited deflection toward the vertical wall, with an inclination angle increasing approximately proportionally with dimensionless distance ratio γh/γv. Moreover, it became more difficult for achieving effective focusing of bubble energy as the jet approached the corners formed by mutually perpendicular walls. The experiments also implied that reducing the dead weight of the vertical wall weakened its contact with the horizontal wall, causing an increase in the equivalent maximum radius of bubbles and jet inclination, as well as a decrease in the bubble pulsation period, under the same dimensionless distance γv.