Functionalized interfaces enhancing phase-change processes have immense applicability in thermal management. Here, a methodology for fabrication of surfaces enabling extreme boiling heat transfer performance is demonstrated combining direct nanosecond laser texturing and chemical vapor deposition of a hydrophobic fluorinated silane. Multiple strategies of laser texturing are explored on aluminum with subsequent nanoscale hydrophobization. Both superhydrophilic and superhydrophobic surfaces with laser-engineered microcavities exhibit significant enhancement of the pool boiling heat transfer. Surfaces with superhydrophobic microcavities allow for enhancements of the heat transfer coefficient of over 500%. Larger microcavities with a mean diameter of 4.2 μm, achieved using equidistant laser scanning separation, induce an early transition into the favorable nucleate boiling regime, while smaller microcavities with a mean diameter of 2.8 μm, achieved using variable separation, provide superior performance at high heat fluxes. The enhanced boiling performance confirms that the Wenzel wetting regime is possible during boiling on apparently superhydrophobic surfaces. A notable critical heat flux enhancement is demonstrated on superhydrophobic surfaces with engineered microstructure showing definitively the importance and concomitant effect of both the surface wettability and topography for enhanced boiling. The fast, low-cost and repeatable fabrication process has great potential for advanced thermal management applications.
A vast majority of heat exchangers suffer from unwanted deposition of material on the surface, which severely inhibits their performance and thus marks one of the biggest challenges in heat transfer. Despite numerous scientific investigations, prediction and prevention of fouling remain unresolved issues in process engineering and are responsible for large economic losses and environmental damage. This review article focuses specifically on crystallization fouling, providing a comprehensive overview of the state-of-the-art of fouling in heat exchangers. The fundamentals of the topic are discussed, as the term fouling resistance is introduced along with distinct fouling behaviour, observed in laboratory and industrial environments. Insight into subsequent phases of the fouling process is provided, along with the accompanying microscale events. Furthermore, the effects of fluid composition, temperature, flow velocity, surface condition, nucleate boiling and composite fouling are comprehensively discussed. Fouling modelling is systematically reviewed, from the early work of Kern and Seaton to recently used artificial neural networks and computational fluid dynamics. Finally, the most common fouling mitigation approaches are presented, including design considerations and various on-line strategies, as well as off-line cleaning. According to our review, several topics require further study, such as the initial stage of crystal formation, the effects of ageing, the interplay of two or more fouling mechanisms and the underlying phenomena of several mitigation strategies.
Growing world population and increasing population density are leading to increasing waste production with biological waste amounting to several billion tonnes annually. Together with the increasing need for renewable energy sources, waste-to-biogas conversion as a prime example of waste-to-energy technology represents a facile way of solving two problems simultaneously. This review aims to address the recent progress in the field of waste-to-biogas technology, which is lately facing intensive research and development, and present the current status of this waste treatment method both in technological and legislative terms. The first part provides an overview of waste and waste management issues. This is followed by a detailed description of applicable waste-to-energy (WtE) technologies and their current implementation in selected European countries. Moreover, national energy and climate plans (NECPs) of selected EU Member States are reviewed and compared with a focus on implementation of WtE technologies. In a further section, biogas production from waste around the world is reviewed and compared country wise. Finally, an outlook into the future of WtE technologies is provided alongside the conclusions based upon the reviewed data.
The rapid advancement of engineering systems has spurred the search for innovative thermal management solutions. Boiling, as a phase‐change heat transfer method, has shown promise in heat dissipation, but non‐functionalized surfaces struggle with increasing cooling demands. To improve heat dissipation efficiency across different heat loads, functionalized surfaces with tailored wettability have been proposed. Separately, superhydrophilic and superhydrophobic surfaces each offer benefits and drawbacks in boiling applications but combining them on a single “biphilic” surface simultaneously harnesses their advantages. In this study, laser‐functionalized copper surfaces with spatially tailored wettability are developed by combining two‐step laser texturing with a self‐assembled monolayer coating, while focus is placed on the impact of the size and pitch of superhydrophobic spots. The developed functionalized surfaces exhibit exceptional boiling performance with heat transfer coefficients up to 299 kW m−2 K−1, a 434% enhancement over untreated surfaces. Optimal ratios of superhydrophilic and superhydrophobic areas and optimal spot pitch are identified. Additionally, varying behavior at different heat flux levels is observed, emphasizing the importance of considering thermal loads when determining the optimal surface pattern. This advancement in performance, along with the rapid and cost‐effective functionalization process, represents a significant breakthrough for enhanced thermal management applications.