A new phosphate-containing bio-polyester based on glycerol and citric acid was synthesized and evaluated as fire-retardant (FR) in wooden particleboards. Phosphorus pentoxide was used to first introduce phosphate esters in the glycerol followed by esterification with citric acid to produce the bio-polyester. The phosphorylated products were characterized by ATR-FTIR, ¹H-NMR and TGA-FTIR. After polyester curing, they were grinded and incorporated in laboratory produced particleboards. The fire reaction performance of the boards was evaluated by cone calorimeter. An increased char residue was produced depending on the phosphorus content and the THR (Total Heat Release), PHRR (Peak of Heat Release Rate) and MAHRE (Maximum Average of the Rate of Heat Emission) were considerably reduced in presence of the FRs. Highlights: Phosphate containing bio-polyester as fire retardant in wooden particle board; Fire performance is improved; Bio-polyester acts in the condensed and gas phases; Additive effectiveness similar to ammonium polyphosphate.

Bamboo constitutes a family of plants that are very promising and interesting as renewable materials for both large and small structure construction. To be used as an alternative to traditional materials; the understanding of its morphology and mechanical behavior is of crucial importance. As the distribution of fibers and vascular bundles differs for each type of bamboo; several bamboo types have been characterized: Phyllostachys aurea (PA), Arundinaria amabilis (AA) and Dendrocalamus strictus (DS). Morphological analysis has been performed by optical (OM) and scanning electron microscopy (SEM). Differences in density; surface morphology and wall thickness have been found. In fact; PA and AA have shown a great morphological regularity; while DS presents the greatest thickness; to the point that it can be considered full culm. The plant’s own ducts constitute a very important factor for future impregnations and the optimization of mechanical properties for structure construction.

Bamboo is a material with good tensile and flexural resistance. As a construction material with structural capacity, using bamboo implies considerable environmental advantages in relation to other typical materials such as steel or concrete. For its correct implementation, it is necessary to define its mechanical properties and durability. Bamboo is susceptible to degradation due to the lack of natural toxins and thin walls, which means that shallow decomposition processes can imply appreciable reductions in its mechanical capacity. The main degrading agents considered in this study were beetles, termites, and xylophagous fungi. The aim of this study was to analyze the durability of three different species: DS, PA, and AA. Durability and mechanical tests results after 6 months of exposure to biotic and abiotic agents were compared with their original properties and chemical composition. In this study, durability was analyzed in two ways. Firstly, the loss of mass due to fungal infection was investigated. The results obtained were based on the standard EN 113 using the fungus CP. Secondly, bending and compressive strength was evaluated after a durability test according to the standard EN 335:2013 for the CU3.1 use class after a 6 month period in the city of Donostia/San Sebastian, Spain. The DS and AA varieties were rated as very durable CD1, while the PA variety is durable CD2, thus proving to be an attractive material for construction.