Composite materials usage in several industrial fields is now widespread, and this leads to the necessity of overcoming issues that are still currently open. In the aeronautic industry, this is especially true for Barely Visible Impact Damage (BVID) and humidity uptake issues. BVID is the most insidious kind of impact damage, being rather common and not easily detectable. These, along with the ageing that a composite structure could face during its operative life, could be a cause of fatal failures. In this paper, the influence of water absorption on impacted specimens compressive residual strength was studied. Specimens were impacted using a modified Charpy pendulum. Two different locations were chosen for comparison: Near-Edge (NE) and Central (CI). Accelerated hygrothermal ageing was conducted on impacted and reference nonimpacted coupons, placing them in a water-filled jar at 70 °C. Compressive tests were performed in accordance with the Combined Loading Compression (CLC) test method. A Dynamic Mechanical Analysis (DMA) was performed as well. The results showed the influence of hygrothermal ageing, as expected. Nevertheless, the influence of impact location on compressive residual strength is not clearly noticeable in aged specimens, leading to the conclusion that hygrothermal ageing may have a greater effect on composite compressive strength than the analysed BVI damage.
New inorganic nanostructured matrices for fiber-reinforced composites with enhanced high-temperature stability were developed from alkali aluminosilicate polymers doped with different ultra-high-temperature ceramic (UHTC) particles. The alkali aluminosilicate matrices were synthesized at room temperature with a high SiO2:Al2O3 ratio and then further functionalized by doping with 4–5 wt % of micrometric SiC, ZrB2, ZrC, and HfC powders and finally thermally stabilized as glass–ceramics at 750 °C. The different UHTC-doped matrices were characterized according to their dimensional and microstructural changes after thermal cycling in air flux at 1000 °C. The first results showed that carbide-based UHTC powders improved the thermal stability of the matrices, preventing the excessive swelling of the material and the formation of detrimental voids that might result in the lack of adhesion with reinforcing fibers. Contrarily, the addition of ZrB2 resulted in an excessive matrix swelling at high temperature, thus proving no efficacy compared to the undoped matrix. Impregnation tests carried out on C-fiber fabrics showed good processability, adhesion to the fibers, and fracture pull-out, especially for carbide-based matrices.
Fiber Metal Laminates (FML), produced in both monolithic and sandwich configurations with glass-, basalt- and carbon-reinforced composites, were investigated for application in fire-resistant lithium battery boxes. Different resins, including recyclable and bio-based systems, were tested to improve sustainability; cores of recycled PET (RPET, 150 g/dm3, 10 mm) were considered. The study focused on the effect of core introduction on mechanical performance, with the dual goal of reducing weight and achieving stiffness values compliant with automotive OEM standards for lithium battery housings. Results demonstrated that sandwich structures improved stiffness up to 12-fold compared to monolithic laminates, while preserving the corrosion resistance of the outer aluminium layer and the flexural strength of the laminates after 670 h of Neutral Salt Spray (NSS) exposure.