The aim of this work was to study the effect of anti-wear coatings on the selected frictional phenomena, i.a., frictional heating and tribofilm formation, of model tribological pairs. For this purpose, three popular metallic substrate materials were selected: AISI 316L and AISI 440B stainless steels, as well as Ti6Al4V two-phase titanium alloy. The substrates were tested in the dry sliding conditions in three states: uncoated, as well as titanium nitride (TiN) or diamond-like-carbon (DLC) coated. According to the results provided, under applied frictional conditions TiN coating, even if it is worn off the sample surface, contributes to excessive frictional heating of a tribological pair by altering the tribofilm formation. The analysis also showed that in some tribological pairs, rapid temperature alteration of a counter sample can be used to approximate the sliding distance after which the TiN coating becomes worn off. On the contrary, in all pairs tested, the DLC film became locally damaged, but it sustained its antifriction properties, contributing to low coefficients of friction (COFs) and the lowest frictional temperatures observed.