As a by-product of lignocellulosic depolymerization for furfural production, furfural residue (FR) is composed of residual cellulose, lignin, humic acid, and other small amounts of materials, which have high reuse value. However, due to the limitation of furfural production scale and production technology, the treatment of FR has many problems such as high yield, concentrated stacking, strong acidity, and difficult degradation. This leads to the limited treatment methods and high treatment cost of furfural residue. At present, most of the furfural enterprises can only be piled up at will, buried in soil, or directly burned. The air, soil, and rivers are polluted and the ecological balance is destroyed. Therefore, how to deal with furfural residue reasonably needs to be solved. In this review, value-added products for furfural residue conversion are described in detail in the fields of soil culture, catalytic hydrolysis, thermal decomposition, and porous adsorption. The future studies reporting the FR to convert value-added products could find guidance from this review to achieve specific goals.
In this study, corn cob was used as raw material and modified methods employing KOH and KMnO4 were used to prepare activated carbon with high adsorption capacity for mercury ions. Experiments on the effects of different influencing factors on the adsorption of mercury ions were undertaken. The results showed that when modified with KOH, the optimal adsorption time was 120 min, the optimum pH was 4; when modified with KMnO4, the optimal adsorption time was 60 min, the optimal pH was 3, and the optimal amount of adsorbent and the initial concentration were both 0.40 g/L and 100 mg/L under both modified conditions. The adsorption process conforms to the pseudo-second-order kinetic model and Langmuir model. Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Zeta potential characterization results showed that the adsorption process is mainly physical adsorption, surface complexation and ion exchange.
1 January 2020 in International Journal of Agricultural and Biological Engineering
In this study, a solid-liquid mixing system model was established to simulate the coexistence of floating particles (FP) and sinking particles (SP) in the early stage of anaerobic digestion, and the mixing effect and energy consumption of the system were investigated. Four typical blades were selected to compare the solid phase distribution of straw particles under different blade stirring, and the distribution of FP and SP in the coexistence system was clarified. Then the combination of full-factorial design and numerical simulation was applied to compare the effect of blade diameter and blade width on particle mixing, which was better than that of immersion depth. A comprehensive equation was further established to balance the weight between the particle mixing effect and energy consumption and improve the blade design. It provided theoretical support for the design and amplification of subsequent stirring equipment.