The valorisation of sewage sludge for sustainable agricultural use and biofuel production proposes an effective and beneficial management of sewage sludge in a closed-loop cycle. The management of sewage sludge biowaste is a rising problem due to increasing waste storage expenses. In this sense, the use of circular economy principles in sewage sludge management creates opportunities to develop new technologies for processing. The biorefinery model allows the application of wasteless technologies via sewage sludge valorisation in terms of agricultural use and biofuel production, especially with the hydrothermal carbonisation method. Applying hydrothermal carbonisation in the treatment of biosolid sewage sludge has numerous benefits due to processing highly hydrated organic waste into carbon hydro char, a high-quality solid biofuel. The direct use of sewage sludge in the soil does not allow for full use of its functional properties. However, the hydrothermal carbonisation of sewage sludge results in biocarbon pellets, making it a viable approach. This work also discusses the barriers (legal, chemical, biological, and technical) and possibilities related to sewage sludge biorefining processes.

Combined heat and power generation is the simultaneous conversion of primary energy (in the form of fuel) in a technical system into useful thermal and mechanical energy (as the basis for the generation of electricity). This method of energy conversion offers a high degree of efficiency (i.e., very efficient conversion of fuel to useful energy). In the context of energy system transformation, combined heat and power (CHP) is a fundamental pillar and link between the volatile electricity market and the heat market, which enables better planning. This article presents an advanced model for the production of fuel mixtures based on landfill biogas in the context of energy use in CHP units. The search for optimal technological solutions in energy management requires specialized domain-specific knowledge which, using advanced algorithmic models, has the potential to become an essential element in real-time intelligent ICT systems. Numerical modeling makes it possible to build systems based on the knowledge of complex systems, processes, and equipment in a relatively short time. The focus was on analyzing the applicability of algorithmic models based on artificial intelligence implemented in the supervisory control systems (SCADA-type systems including Virtual SCADA) of technological processes in waste management systems. The novelty of the presented solution is the application of predictive diagnostic tools based on multithreaded polymorphic models, supporting making decisions that control complex technological processes and objects and solving the problem of optimal control for intelligent dynamic objects with a logical representation of knowledge about the process, the control object, and the control, for which the learning process consists of successive validation and updating of knowledge and using the results of this updating to determine control decisions.

Exhaustive experimental study of aluminum incorporation in epitaxial 4H-SiC and 3C‑SiC films grown by chemical vapor deposition (CVD) was performed. The influence of polytype and substrate orientation was verified. Role of principal process conditions (growth temperature and pressure, deposition rate, chemical environment) was investigated in details. Finally, the evolution of optical properties of resulting SiC films with Al content was examined.

Waste from street cleaning is usually of a fine fraction below 10 mm and varies greatly in both quantity and composition. It may be composed of chlorides, especially for that resulting during winter due to the use of street de-icing agents. Chlorides can cause the salinization of surface water and groundwater, and the salinization of soils, which in turn lead to the deterioration of water purity and a decrease in biodiversity of aquatic organisms, changes in microbiological structure, and increases in toxicity of metals. Therefore, it is very important to determine the level of salinity in stored waste and its impact on the environment. The present study was conducted in a city of about 55,000 inhabitants. The highest chloride concentrations were observed after winter in waste from street and sidewalk cleaning around the sewer gullies, amounting to 1468 mg/dm³. The lowest chloride concentration in this waste occurred in summer and amounted to 35 mg/dm³. The multi-criteria analysis indicated that the most beneficial form of street cleaning and, thus, of reductions in chloride concentration in the waste from street cleaning, would be sweeping and daily washing. The objective of this research was to determine the amount of chlorides in sweepings on an annual basis in order to determine the potential risks associated with their impact on select aspects of the environment and to evaluate the frequency of necessary cleaning for city streets, considering the effects. The methodology used was a multi-criteria evaluation, which as a decision analysis, allowed us to determine the frequency of cleaning and washing of streets, in such a way that an ecological effect is achieved with simultaneous economic efficiency.

Removing impurities that occur in landfill gas, from sulphur and silicon compounds, is crucial for the energetic use of biogas in a cogeneration unit for energy purposes. The aim of this study was to analyse the shaped activated carbon, examining its structure and elemental composition as part of the biogas purification. The qualitative study of the purified landfill gas performed in this study showed a significant overshoot of hydrogen sulphide at 304.1 ppm with respect to the gas engine manufacturer’s requirements, while the calculated hydrogen sulphide reduction efficiency was 24.58%. Examination of the surface of the spent carbon and its pores with a scanning microscope revealed a high level of clotting by sulphur compounds, which prevents proper reduction of this compound and reduces the efficiency of the treatment plant. Replacement of the activated carbon bed with a new one showed a hydrogen sulphide value of 7.5 ppm in the purified gas and a calculated reduction efficiency of 97.9%. The results of the study confirmed that continuous monitoring of the quality of the purified gas is necessary to control the adsorption properties of the activated carbon and can be used for the operation of gas engines in cogeneration units. The landfill gas treatment method described in this paper constitutes an environmentally sustainable project within the meaning of the EU regulation on the establishment of a framework to promote and facilitate this type of investment in terms of its financing and operation. The topic of the work fits into three key areas of broad research and implementation activities. The first, technological, is the transition to a low-carbon, sustainable and resource-efficient closed-loop economy; the second, environmental, pollution prevention and control. The third area is economics and finance in terms of making financial products available designed to reduce climate change and reporting on these activities.

Polymer gel electrolytes based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and poly(acrylonitrile-co-butadiene) (PAB) or poly(dimethylsiloxane) bis(3-aminopropyl)-terminated (PDES-bAP) copolymers were prepared and investigated in dye-sensitized solar cells (DSSCs). Selected optical and electrochemical properties of all compositions with various ratio from 9:1 to 6:4 were investigated towards DSSC applications. The highest value of power conversion efficiency equal to 5.07% was found for DSSCs containing a PVDF-HPF:PAB (9:1) gel electrolyte. Compositions of electrolytes were additionally tested by electrochemical impedance spectroscopy. The influence of the ratio and type of polymers used as an additive to PVDF-HPF on absorption wavelengths, energy gap, and Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) levels were investigated. Individual components of DSSCs, such as the TiO₂ layer and platinum nanoparticles, were imaged by scanning electron microscope. Finally, a DSSC module with six electrically separated solar cells with a 7 × 80 mm² active area was constructed based on gel electrolytes and tested.