In this paper, the effect of rare earth Ce content on the morphology, composition, type and size distribution of inclusions in W350 non-oriented silicon steel was investigated by means of ICP-MS (inductively coupled plasma mass spectrometry), SEM/EDS (scanning electron microscope-energy Dispersive Spectrometer), and ASPEX (automated SEM/EDS inclusion analysis). The results showed that with the increase of Ce content in the steel, the modification sequence of inclusions was CeAlO3→Ce2O2S→CexSy. The type and size distribution of inclusions in the steel obviously changed with the difference in added Ce content. When the added Ce content in the steel was 10 ppm, 14 ppm, 20 ppm and 30 ppm respectively, the rare earth inclusions were mainly CeAlO3-Ce2O2S. Furthermore, when the added Ce content increased to 60 ppm, the rare earth inclusions were mainly Ce2O2S with a small amount of CeAlO3 contained in part inclusions. When the added Ce content increased continually to 95 ppm, the rare earth inclusions were mainly CexSy-Ce2O2S. The critical Ce content for the conversion between CeAlO3 and Ce2O2S was 41 ppm. To ensure that inclusions transform from CeAlO3 to Ce2O2S, the Ce content in the steel should be greater than 41 ppm. Under the current experimental conditions, it was found that when the Ce content was 20 ppm, the number density and proportion of inclusions in the steel were lower, and their average size was larger. When the added Ce content increased to 95 ppm, the number density of inclusions in the steel significantly increased, which deteriorated the steel cleanliness.
In order to study the effects of rare earth La–Ce alloying treatment on the characteristics of inclusions in non-oriented silicon steels, industrial experiments were conducted studying the composition, morphology, size and quantity of inclusions in W350 non-oriented silicon steel during the RH (Ruhrstahl-Hereaeus) refining process and tundish process, after rare earth treatment. The products were analyzed by means of ICP-MS (inductively coupled plasma mass spectrometry), SEM/EDS (scanning electron microscope-energy dispersive spectrometry), and ASPEX (automated SEM/EDS inclusion analysis). The research results showed that the types of inclusions in experimental steel changed significantly after rare earth treatment. The types of inclusions after RE (rare earth) treatment are typically rare earth composite inclusions that are mainly composed of (La, Ce)Al2O3, and conventional inclusions. The addition of rare earth promotes the agglomeration of inclusions; the morphologies of the inclusions are mostly blocky, and some are distributed in long strips. After rare earth treatment during the RH refining process, the number of inclusions with sizes of 1.0~3.5 μm in the experimental steel is increased, and the average size of the inclusions is 2.66 μm. In addition, the number of inclusions larger than 4 μm in the specimens increases due to the collision and growth of inclusions caused by the RH circulation. After rare earth treatment during the tundish process, the number of micro inclusions with sizes of 1.0~2.5 μm in the specimen steels decreases, while the number of inclusions larger than 5 μm increases. The size distribution of micro inclusions in hot-rolled sheets after rare earth treatment was studied using TEM (transmission electron microscopy). In the specimens without rare earth, the content of micro inclusions (≤1 μm) is 51,458.2/mm2 and the average size is 0.388 μm. In the specimens with rare earth added, the content of micro inclusions (≤1 μm) is 24,230.2/mm2 and the average size is 0.427 μm. Compared to sheet produced by the original process, the iron loss of the 0.35 mm finished experimental sheet is reduced by 0.068 W/kg, and the magnetic induction is increased by 0.007 T. The iron loss of the 0.50 mm finished experimental sheet is reduced by 0.008 W/kg, and the magnetic induction is increased by 0.004 T. After rare earth treatment, the average size of micro inclusions increases and the magnetic properties are obviously improved.
The multiphase flow and spatial distribution of bubbles inside a continuous casting (CC) mold is a popular research issue due to its direct impact on the quality of the CC slab. The behavior of bubbles in the mold, and how they coalesce and break apart, have an important influence on the flow pattern and entrapment of bubbles. However, due to the limitations of experiments and measurement methods, it is impossible to directly observe the multiphase flow and bubble distribution during the CC process. Thus, a three-dimensional mathematical model which combined the large eddy simulation (LES) turbulent model, VOF multiphase model, and discrete phase model (DPM) was developed to study the transient two-phase flow and spatial distribution of bubbles in a continuous casting mold. The interaction between the liquid and bubbles and the coalescence, bounce, and breakup of bubbles were considered. The measured meniscus speed and bubble diameter were in good agreement with the measured results. The meniscus speed increased first and then decreased from the nozzle to the narrow face, with a maximum value of 0.07 m/s, and appeared at 1/4 the width of the mold. The current mathematical model successfully predicted the transient asymmetric two-phase flow and completely reproduced the coalescence, bounce, and breakup of bubbles in the mold. The breakup mainly occurred near the bottom of the submerged entry nozzle (SEN) due to the strong turbulent motion of the molten steel after hitting the bottom of the SEN. The average bubble diameter was about 0.6 mm near the nozzle and gradually decreased to 0.05 mm from the nozzle to the narrow face. The larger bubbles floated up near the SEN due to the effect of their greater buoyancy, while the small bubbles were distributed discretely in the entire mold with the action of the molten steel jet. Overall, the bubbles were distributed in a fan shape. The largest concentration of bubbles was in the lower part of the SEN and the upper edge of the SEN outlet.
In the current study, the transient flow characteristics on the top surface of a steel slab continuous casting strand were numerically investigated using a large eddy simulation combined with volume of fluid (LES + VOF) model. The validation of numerical simulation was verified via nail board measurement in the industrial continuous casting mold. The effects of casting speed on the top surface level profile and the instantaneous distribution of vortex were discussed. The level variation profile migrated after a period of time, moving from one side of the wide face of the mold to the other. The wave height and transient variation degree of the standing wave increased with an increase in the casting speed. The region near the SEN was more likely to promote the formation of vortices. The vortex generation became easier when the vorticity peaks were concentrated on the outer edge of the low-speed confluence area near the submerged entry nozzle. In addition, the effect of surface velocity on the instantaneous level fluctuation was analyzed. The frequency of level fluctuations was highest at 3~4 mm, and the high-frequency range of velocity fluctuation was 20~60 mm/s at 0.9 m/min casting speed for a 1500 mm × 200 mm caster section. The linear relationship between the level fluctuation and surface velocity magnitude was obtained. The present work aimed at evaluating the dynamic problem of the standing wave at the liquid powder–molten steel interface on the top surface of the mold, which is helpful in optimizing the casting parameters for regular casting practice and improving the quality of the steel slabs.
Improving the efficiency of electric vehicle traction motors requires non-oriented silicon steels with low core loss and favorable magnetic induction. This study aims to clarify the influence of annealing temperature on the microstructure, texture, and magnetic properties of a 3.2%Si–0.9%Al steel, providing guidance for process optimization. Optical metallography, X-ray diffraction, and electron backscatter diffraction were employed to characterize the evolution. Recrystallization was completed between 620 °C and 720 °C, during which fine recrystallized grains replaced the deformed structure, accompanied by the nucleation of {111} and {114} grains. With further annealing from 850 °C to 1050 °C, grain growth occurred, resulting in an α*-fiber texture dominated by {114}. The fraction of high-angle {114} grains increased, while low-angle {111} grains decreased. This microstructural evolution significantly influenced the magnetic properties of non-oriented electrical steel. The P1.5/50 and P1.0/400 core losses reached minimum values of 2.02 W/kg and 16.48 W/kg at 1010 °C and 930 °C, respectively, while B50 decreased slightly from 1.670 T to 1.652 T. These findings indicate that precise control of the annealing temperature is an effective strategy to tailor microstructure and texture, thereby optimizing the magnetic properties of non-oriented electrical steel.