The recent advances in wearable sensors and intelligent human–machine interfaces have sparked a great many interests in conductive fibers owing to their high conductivity, light weight, good flexibility, and durability. As one of the most impressive materials for wearable sensors, conductive fibers can be made from a variety of raw sources via diverse preparation strategies. Herein, to offer a comprehensive understanding of conductive fibers, we present an overview of the recent progress in the materials, the preparation strategies, and the wearable sensor applications related. Firstly, the three types of conductive fibers, including metal-based, carbon-based, and polymer-based, are summarized in terms of their principal material composition. Then, various preparation strategies of conductive fibers are established. Next, the primary wearable sensors made of conductive fibers are illustrated in detail. Finally, a robust outlook on conductive fibers and their wearable sensor applications are addressed.
Because of the dilemma that the current industrial Cu enhancement methods lead to a significant decline in conductivity and ductility, Cu matrix composites reinforced by oriented multi-walled carbon nanotubes (MWCNTs) were prepared through sintering, hot extrusion, and cold drawing. Before sintering, Ni, Cu, and Ni&Cu coatings were electroless plated on MWCNTs as the intermediate transition layer, and then they were mixed with Cu powder through a nitrogen bubbling assisted ultrasonic process. By analyzing the composition, microstructure, and formation mechanism of the interface between MWCNTs and the matrix, the influence and mechanism of the interface on the mechanical properties, conductivity, and ductility of the composites were explored. The results indicated that MWCNTs maintained a highly dispersed and highly consistent orientation in the Cu matrix. The coating on Ni@CNT was the densest, continuous, and complete. The Ni@CNTs/Cu composite had the greatest effect, while the Cu composite reinforced by MWCNT without coating had the smallest reduction in elongation and conductivity. The comprehensive performance of the Cu@CNTs/Cu composite was the most balanced, with an ultimate tensile strength that reached 373 MPa, while the ductility and conductivity were not excessively reduced. The axial electrical and thermal conductivity were 79.9 IACS % (International Annealed Copper Standard) and 376 W/mK, respectively.
The obvious advantages of laser paint removal technology make it a viable alternative to traditional paint removal methods. Infrared nanosecond laser was used to remove paint from car body. The microstructure, composition, surface roughness, hardness and ablative products of the samples were analyzed. The effect of the process combination of laser defocus distance and ambient atmosphere (ambient air, compressed air and inert atmosphere) on the substrate damage and the paint removal effectiveness was explored, and the related mechanism was discussed. Defocus not only changed the fluence of laser spot but also increased the spot diameter. The effect of defocused laser paint removal on the paint and substrate was caused by the superposition of these two factors. The results show that the laser with defocus distance of +4 mm effectively removed the paint in inert atmosphere and has the least adverse effect on the substrate. The content of C element and organic components on the substrate surface was the lowest, and its surface roughness and hardness was very close to the uncoated substrate. Focused laser paint removal in ambient air caused the most serious damage to the substrate. Its surface microhardness increased by 11 HV, and the influence depth reached 37 µm. The mechanism of laser paint removal without auxiliary gas is the superposition of laser plasma effect, laser gasification effect and thermal stress effect. In open atmosphere (compressed air and inert atmosphere), the mechanism of laser paint removal is laser gasification effect and thermal stress effect. This research can provide practical references and theoretical basis for the large-scale industrial application of low/non-damage laser paint removal technology.
To achieve the reinforcement of copper matrix composite by single‐walled carbon nanotubes, a three‐step‐refluxing purification of carbon nanotubes sample with HNO3‐NaOH‐HCl was proposed and demonstrated. A previously reported purification process using an electromagnetic stirring with H2O2/HCl mixture was also repeated. Then, the purified carbon nanotubes were coated with copper by the same electroless plating process. At the end, the effects of the method on carbon nanotubes themselves and on copper coating were determined by transmission electron microscope spectroscopy, scanning electron microscope spectroscopy, X‐ray diffractometry, thermogravimetric analysis, Fourier transformed infrared spectroscopy, and energy dispersive spectrometry. It was clearly confirmed that both of the two processes could remove most of iron catalyst particles and carbonaceous impurities without significant damage to carbon nanotubes. The thermal stability of the sample purified by H2O2/HCl treatment was slightly higher than that purified by HNO3‐NaOH‐HCl treatment. Nevertheless, the purification by HNO3‐NaOH‐HCl treatment was more effective for carboxyl functionalization on nanotubes than that by H2O2/HCl treatment. The Cu‐coating on carbon nanotubes purified by both purification processes was complete, homogenous, and continuous. However, the Cu‐coating on carbon nanotubes purified by H2O2/HCl was oxidized more seriously than those on carbon nanotubes purified by HNO3‐NaOH‐HCl treatment.