In the last decade, China has sharply tightened the monitoring values for wastewater treatment plants (WWTPs). In some regions with sensitive discharge water bodies, the values (24 h composite sample) must be 1.5 mg/L for NH4-N and 10 mg/L for total nitrogen since 2021. Even with the previously less strict monitoring values, around 50% of the wastewater treatment plants in China were permanently unable to comply with the nitrogen monitoring values. Due to the rapid changes on-site to meet the threshold values and the strong relation to energy-intensive aeration strategies to sufficiently remove nitrogen, WWTPs do not always work energy-efficiently. A Chinese WWTP (450,000 Population equivalents or PE) with upstream denitrification, a tertiary treatment stage for phosphorus removal and disinfection, and aerobic sludge stabilisation was modelled in order to test various concepts for operation optimisation to lower energy consumption while meeting and undercutting effluent requirements. Following a comprehensive analysis of operating data, the WWTP was modelled and calibrated. Based on the calibrated model, various approaches for optimising nitrogen elimination were tested, including operational and automation strategies for aeration control. After several tests, a combination of strategies (i.e., partial by-pass of primary clarifiers, NH4-N based control, increase in the denitrification capacity, intermittent denitrification) reduced the air demand by up to 24% and at the same time significantly improved compliance with the monitoring values (up to 80% less norm non-compliances). By incorporating the impact of the strategies on related processes, like the bypass of primary settling tanks, energy consumption could be reduced by almost 25%. Many of the elaborated strategies can be transferred to WWTPs with similar boundary conditions and strict effluent values worldwide.
Hybrid ceramic membranes (i.e., membranes with a layer-by-layer (LbL) coating) are an emerging technology to remove diverse kinds of micropollutants from water. Hybrid ceramic membranes were tested under laboratory conditions as single-channel (filter area = 0.00754 m2) and multi-channel (0.35 m2) variants for the removal of pharmaceuticals (sulfamethoxazole, diclofenac, clofibric acid, and ibuprofen) and typical wastewater pollutants (i.e., COD, TOC, PO4-P, and TN) from drinking water and treated wastewater. The tests were conducted with two low transmembrane pressures (TMP) of 2 and 4 bar and constant temperatures and flow velocities, which showed rejections above 80% for all the tested pharmaceuticals as well for organic pollutants and phosphorous in the treated wastewater. Tests regarding sufficient cleaning regimes also showed that the LbL coating is stable and resistant to pHs between 2 and 10 with the use of typical cleaning agents (citric acid and NaOH) but not to higher pHs, a commercially available enzymatic solution, or backwashing. The hybrid membranes can contribute to the advanced treatment of water and wastewater with low operational costs, and their application at a larger scale is viable. However, the cleaning of the membranes must be further investigated to assure the stability and durability of the LbL coating.
Despite the huge current challenges in sewage sludge treatment and disposal in China, anaerobic sludge stabilisation (AnSS) is still not a state-of-the-art process in WWTP in the country. However, the potential benefits of anaerobic sludge stabilisation may outweigh the drawbacks. One of these drawbacks is the backload from the sludge liquor that increases the nutrient load in the biological treatment stage. This work shows via computer modelling that not only can the sludge production and disposal costs be significantly reduced, but also that, with sensible automation and operational strategies (e.g., bypass of primary clarifiers, use of a centrate dosing strategy, incorporation of ammonium nitrogen sensors, etc.), the effects of the backload can be counteracted for nitrogen removal, even considering that wastewater in China often has an unfavourable C/N ratio for nitrogen removal. The tested strategies would even improve the overall plant performance in terms of norm compliance, sludge production, energy use, and energy production
A process for a more efficient and flexible use of the produced heat in biogas plants is tested under real operational conditions. The process uses a mesophilic digester and a thermophilic secondary digester, and the heat demand of the plant is covered by using the heat stored in the secondary digester. The efficient heat use is achieved by a controlled variation of temperature in combination with a suitable process monitoring, without affecting the biogas production or disturbing the biological process. The concept was previously tested in ideal laboratory conditions. Here, the validation tests, in preparation for a planned large‐scale trial, comprising one‐year semicontinuous fermentation tests in the laboratory (close to real operational conditions) are presented. These real conditions are characterized by a high organic load of the reactors as well as by a more manifold substrate mix. During the experimental phase, it is determined that the maximum temperature, at high variation rates between −4 and +2 K per day, reaches 54 °C, allowing a stable process. These experiments confirm that the adaptability to temperature changes depends on the boundary conditions of the fermentation and case‐specific experiments are required before significant changes are made to the temperature management of anaerobic digestion systems.