In this paper, a method of mathematical modeling for solving the problem of reusing man-made waste from mining and the processing of ores is proposed. The use of intermediate products (man-made waste: tailings of processing plants, rocks from sinking operations and the technical water of mine drainage) in cyclic production presupposes their use as fill material components and placement in the mined-out voids of underground mines. The influence of mining factors on the fill material composition and the parameters of the created fill mass is justified. The results of a practical implementation of the proposed mathematical model are presented, and an algorithm is compiled. Deformation changes and stress concentration are key criteria in the proposed mathematical model. The proposed algorithm allows for the determination of the preferred system of deposit development, and the selection of its parameters and the fill material composition.
Resource-dependent countries and economies are found to be particularly sensitive to global shocks. A unifying parallel is drawn between resource-dependent countries and regions with depleted mineral resources. The objective factors of losses of accessed reserves are analyzed. A unifying parallel is drawn between sub-standard ores and industrial waste. The paper proposes shifting geotechnology development from simple mineral extraction towards technologies that provide a full cycle of geo-resources development. A radical way of ensuring a full cycle of geo-resources development is the involvement of sub-standard ores and industrial waste in a closed processing cycle. The utilization of industrial waste without a valuable component extracting or reducing a harmful component to a background value is palliative. A comparative description of various technologies that allow extracting valuable components from sub-standard ores and industrial waste is made. The paper proposes a variant of chemical–physical technology that makes it possible to extract a valuable component from industrial waste to a minimum value. The activation of industrial waste with a disintegrator before a chemical extraction significantly increases the yield of a valuable component from 2.6 to 218.5%. A differentiated approach is needed regarding the choice of leaching solution, its percentage, as well as the leaching method and the need for activation processing of valuable components and industrial ones. The combined highly efficient physical–chemical and physical–technical technologies will ensure the maximum extraction of the valuable component from 52.6 to 98.8% in the full cycle of natural and industrial geo-resources development.
Rare earth metals (REM) with magnetic properties find application in the recently developed high-tech industries. Sensor magnetic systems based on neodymium are increasingly in demand in modern engineering and geological surveys due to their favorable combination of properties of magnetic materials based on rare earth metals. One of the problems is to obtain high-quality materials for the production of such magnetic sensors. It should be noted that the high activity of REM does not allow obtaining master alloys and REM-based alloys from metallic materials; it is advisable to use halide compounds. This work discusses a method for producing neodymium fluoride from its oxide. REM fluorides can be obtained by fluorinating the oxides of these metals. Various fluorine-containing compounds or elemental fluorine are usually used as fluorinating reagents, which have their own advantages and disadvantages. The thermodynamic and technological analysis of neodymium fluoride production processes has shown the most acceptable fluorinating agent is ammonium hydrofluoride, which was used in this work. In order to increase the productivity and degree of chemical transformation, it was proposed to perform heating stepwise; i.e., at the initial stage, heat at a speed of 3 degrees per minute, after which the heating speed was reduced to 2 degrees per minute, and finally the speed was reduced to 1 degree per minute. Due to proposed heating mode, the same productivity and yield of chemical transformation were achieved, with an increased efficiency up to 30%, which can significantly reduce the cost of production. The obtained product is used in the production of neodymium-based alloys by metallothermic reduction of a mixture of fluorides. The sensor material obtained in this way is characterized by a low (less than 0.05%) oxygen content.
The depletion of shallow coal reserves necessitates a shift from open-pit to underground mining, increasing the need for safe and efficient backfill systems. However, traditional backfill materials—especially cement—are costly and environmentally burdensome. To address this, our study explores a sustainable alternative using industrial waste, contributing to the principles of a circular economy. This research presents a novel backfill formulation that achieves full cement replacement through the use of fly ash, supplemented with nanocrystalline silica and glass fiber to enhance strength and setting dynamics. Eighteen sample sets were prepared for each composition, using consistent mixing, curing, and testing protocols. Mechanical strength was evaluated at multiple curing intervals alongside microstructural characterization using SEM and XRD. The results show that mixtures containing nanomodified silica and fiber exhibit significantly improved compressive, shear, and splitting strength—up to 40% higher than fly ash-only compositions. Microstructural analysis revealed accelerated C-S-H gel development, reduced porosity, and more uniform pore structures over time. These findings confirm the mechanical viability and economic potential of waste-based backfill systems. The proposed formulation enables safer underground operations, improved extraction efficiency, and reduced environmental impact—offering a scalable solution for modern coal mining.