Biochar has been used in various applications, e.g., as a soil conditioner and in remediation of contaminated water, wastewater, and gaseous emissions. In the latter application, biochar was shown to be a suitable alternative to activated carbon, providing high treatment efficiency. Since biochar is a by-product of waste pyrolysis, its use allows for compliance with circular economics. Thus, this research aims to obtain a detailed characterization of three carbonaceous materials: an activated carbon (CARBOSORB NC 1240^®) and two biochars (RE-CHAR^® and AMBIOTON^®). In particular, the objective of this work is to compare the properties of three carbonaceous materials to evaluate whether the application of the two biochars is the same as that of activated carbon. The characterization included, among others, particle size distribution, elemental analysis, pH, scanning electron microscope, pore volume, specific surface area, and ionic exchange capacity. The results showed that CARBOSORB NC 1240^® presented a higher specific surface (1126.64 m²/g) than AMBIOTON^® (256.23 m²/g) and RE-CHAR^® (280.25 m²/g). Both biochar and activated carbon belong to the category of mesoporous media, showing a pore size between 2 and 50 nm (20–500 Å). Moreover, the chemical composition analysis shows similar C, H, and N composition in the three carbonaceous materials while a higher O composition in RE-CHAR^® (9.9%) than in CARBOSORB NC 1240 ^® (2.67%) and AMBIOTON^® (1.10%). Differences in physical and chemical properties are determined by the feedstock and pyrolysis or gasification temperature. The results obtained allowed to compare the selected materials among each other and with other carbonaceous adsorbents.

The influence of two different fluoride-based activator salts (NH₄F and AlF₃) was studied for diffusion aluminide coatings obtained via pack cementation on a Ni-based superalloy (René 108DS). The resistance to oxidation and hot corrosion was assessed as a function of the concentration of activator salts used during the synthesis process by means of pack cementation. Two different concentrations were selected for activator salts (respecting the equimolarity of fluoride in the synthesis) and the obtained diffusion coatings were compared in terms of morphology, thickness and composition, as well as in terms of microstructural evolution after high temperature exposure. Isothermal oxidation tests were conducted at 1050 °C in air for 100 h in a tubular furnace. The oxidation kinetics were evaluated by measuring the weight variation with exposure time. The microstructural evolution induced by the high temperature exposure was investigated by SEM microscopy, EDS analysis and X-ray diffraction. Results showed that the coatings obtained with AlF₃ activator salt are thicker than those obtained using NH₄F as a consequence of different growth mechanism during pack-cementation. Despite this evidence, it was found that the NH₄F coatings show a better oxidation resistance, both in terms of total mass gain and of quality of the microstructure of the thermally grown oxide. On the other hand, coatings produced with high concentration of AlF₃ exhibited a better resistance in hot corrosion conditions, showing negligible mass variations after 200 h of high temperature exposure to aggressive NaCl and Na₂SO₄ salts.