Second-order Zeeman frequency shift is one of the major systematic factors affecting the frequency uncertainty performance of cesium atomic fountain clock. Second-order Zeeman frequency shift is calculated by experimentally measuring the central frequency of the (1,1) or (−1,−1) magnetically sensitive Ramsey transition. The low-frequency transition method can be used to measure the magnetic field strength and to predict the central fringe of (1,1) or (−1,−1) magnetically sensitive Ramsey transition. In this paper, we deduce the formula for magnetic field measurement using the low-frequency transition method and measured the magnetic field distribution of 4 cm inside the Ramsey cavity and 32 cm along the flight region experimentally. The result shows that the magnetic field fluctuation is less than 1 nT. The influence of low-frequency pulse signal duration on the accuracy of magnetic field measurement is studied and the optimal low-frequency pulse signal duration is determined. The central fringe of (−1,−1) magnetically sensitive Ramsey transition can be predicted by using a numerical integrating of the magnetic field “map”. Comparing the predicted central fringe with that identified by Ramsey method, the frequency difference between these two is, at most, a fringe width of 0.3. We apply the experimentally measured central frequency of the (−1,−1) Ramsey transition to the Breit-Rabi formula, and the second-order Zeeman frequency shift is calculated as 131.03 × 10⁻¹⁵, with the uncertainty of 0.10 × 10⁻¹⁵.