This paper presents the results of laboratory tests on photocatalytic pavement blocks from a bicycle lane in Poland after seven years of service. Air purification performance was tested on dusty and clean samples using different light sources and setups, with non-laminar gas circulation. Secondary Electrons Secondary Ions (SESI) and InLens detectors combined with SEM–EDS and X-ray analyses were applied to confirm the presence of TiO₂ in the studied blocks. The obtained results show that TiO₂ was present in the form of agglomerates with a diameter of 0.25–5 µm and was bonded to the cement matrix components. The tested samples still maintained nitric oxide (NO) removal capability with a NO reduction rate of 4–45%, depending on light source and surface cleanliness.

Specific aerosols and cloud properties over large urban regions seem to generate an island, similar to the well-known urban heat island, leading to lower ultraviolet (UV) radiation intensity compared to the surrounding less polluted areas, thus creating a shield against excessive human exposure to UV radiation. The present study focuses on differences between erythemal and UVA (324 nm) doses measured by the Brewer spectrophotometers in Warsaw (52.3° N, 21.0° E) and Belsk (51.8° N, 20.8° E). The latter is a rural region located about 60 km south-west of the city. Ratios between erythemal and UVA partly daily doses, obtained during all-sky and cloudless-sky conditions for the period May 2013–December 2015, were analysed to infer a specific cloud and aerosol forcing on the surface UV doses over Warsaw. Radiative model simulations were carried out to find sources of the observed differences between the sites. It was found that Warsaw urban agglomeration induced 8 and 6 % attenuation of the erythemal and UVA doses respectively. This is mostly due to the lower sun elevation in Warsaw during the near-noon measurements and the larger optical depth of the city aerosols and increased cloudiness. It could be hypothesised that the expected stronger absorption of the solar UV radiation by urban aerosols is compensated for here by a higher surface reflectivity over the city.

This paper presents the development of artificial neural network models for the prediction of the daily maximum hourly mean of surface ozone concentration for the next day at rural and urban locations in central Poland. The models were generated with six input variables: forecasted basic meteorological parameters and the maximum O₃ concentration recorded on the previous day and number of the month. The training data set covered the period from April 2015 to September 2015. An analogous data set of input variables, for the 2014 year, not used during the process of training the networks, was used as test data to examine the quality of these models. From the results of simulations for the year 2014, the average relative error values were equal to 15.3% and 15.7% for Belsk and Warsaw stations, respectively. The mean error (ME) value indicates a tendency to overestimate the predicted values by 4.8 µg/m³ for Belsk station and to underestimate the predicted values by 0.9 µg/m³ for Warsaw station. The analysis of days when the relative error value was >50% revealed that all predictions with extremely high relative error value were associated with relatively low daily maximum surface ozone concentration values that occurred suddenly due to a sharp drop in day-to-day ozone concentration values.

The application of photocatalytic materials has been intensively researched in recent decades. The process of nitric oxide (NO) oxidation during photocatalysis has been observed to result in the formation of nitric dioxide (NO₂). This is a significant factor of the photocatalysis process, as NO₂ is more toxic than NO. However, it has been reported that ozone (O₃) is also formed during the photocatalytic reaction. This study analyzed the formation and oxidationof O₃ during the photocatalytic oxidation of NO under ultraviolet irradiation using commercial photocatalytic powders: AEROXIDE^® TiO₂ P25 by Evonik, KRONOClean^® 7050 by KRONOS^®, and KRONOClean^® 7000 by KRONOS^®. An NO concentration of 100 ppb was assumed in laboratory tests based on the average nitric oxide concentrations recorded by the monitoring station in Warsaw. A mix flow-type reactor was applied in the study, and the appropriateness of its application was verified using a numerical model. The developed model assumed an empty reactor without a photocatalytic material, as well as a reactor with a photocatalytic material at its bottom to verify the gas flow in the chamber. The analysis of the air purification performance of photocatalytic powders indicated a significant reduction of NO and NO_x and typical NO₂ formation. However, no significant formation of O₃ was observed. This observation was verified by the oxidation of pure ozone in the process of photocatalysis. The results indicated the oxidation of ozone concentration during the photocatalytic reaction, but self-decomposition of a significant amount of the gas.