Recent advancements in high-entropy alloys (HEAs) and high-entropy materials (HEMs) show promising potential for different fields of applications. The emergence of HEAs and HEMs has gained significant interest for their exciting nature and properties. As they consist of five or more elements in considerable amounts, properties vary depending on the synergistic effect of combinations of elements. By selecting proper elements and manufacturing methods, better properties can be tuned. Although many unique behaviors of HEAs and HEMs are reported due to their mixing entropy, sluggish diffusion, severe lattice distortion, and multi-metallic cocktail effects, it is necessary to summarize the data to map their feasibility and potential. For example, the combined properties of high thermal stability, thermal fatigue, creep resistance, higher stiffness, and better corrosion resistance for elevated-temperature environments in aerospace applications are pursued. Moreover, gaining the environmental compatibility and longevity of service-life-oxidation behavior of these materials is one of the crucial aspects and, hence, has been recently explored. Therefore, this Research Update aims at summarizing the recent developments and findings in oxidation behavior and highlighting the challenges and controversies for future research perspectives, particularly, on the sustainability for different applications. Moreover, besides the bulk structure, the performance of the HEAs/HEMs coatings is also reviewed.
Nitrogen-doped TiO2 nanotube arrays (N-TNAs) were successfully fabricated by a simple thermal annealing process in ambient N2 gas at 450 °C for 3 h. TNAs with modified morphologies were prepared by a two-step anodization using an aqueous NH4F/ethylene glycol solution. The N-doping concentration (0–9.47 at %) can be varied by controlling N2 gas flow rates between 0 and 500 cc/min during the annealing process. Photocatalytic performance of as-prepared TNAs and N-TNAs was studied by monitoring the methylene blue degradation under visible light (λ ≥ 400 nm) illumination at 120 mW·cm−2. N-TNAs exhibited appreciably enhanced photocatalytic activity as compared to TNAs. The reaction rate constant for N-TNAs (9.47 at % N) reached 0.26 h−1, which was a 125% improvement over that of TNAs (0.115 h−1). The significant enhanced photocatalytic activity of N-TNAs over TNAs is attributed to the synergistic effects of (1) a reduced band gap associated with the introduction of N-doping states to serve as carrier reservoir, and (2) a reduced electron‒hole recombination rate.
A N95 face-piece respirator and a 3M air filter composed of non-woven polypropylene filter material were investigated for their multi-scale microstructure and resulting filtration performance. Filtration mechanisms of each system are found and quantified. Both media showed a gradually decrease of the most penetrating particle size with respect to an increase in face velocity or surface charge density. Increasing the face velocity and porosity dramatically degraded the collection efficiency in the 3M filter rather than in the N95 system. We exploited three-dimensional X-ray tomography to characterize the morphological and geometrical properties of the fiber arrangement and deposition of aerosol on the fiber surface. Tuning the most predominant material parameters to achieve a precedence in lower pressure drop or higher collection efficiency in a specifically captured particle size range is of great requisite to a peculiar application of the filter media.
To minimize the stress shielding effect of metallic biomaterials in mimicking bone, the body-centered cubic (bcc) unit cell-based porous CoCrMo alloys with different, designed volume porosities of 20, 40, 60, and 80% were produced via a selective laser melting (SLM) process. A heat treatment process consisting of solution annealing and aging was applied to increase the volume fraction of an ε-hexagonal close-packed (hcp) structure for better mechanical response and stability. In the present study, we investigated the impact of different, designed volume porosities on the compressive mechanical properties in as-built and heat-treated CoCrMo alloys. The elastic modulus and yield strength in both conditions were dramatically decreased with increasing designed volume porosity. The elastic modulus and yield strength of the CoCrMo alloys with a designed volume porosity of 80% exhibited the closest match to those of bone tissue. Different strengthening mechanisms were quantified to determine their contributing roles to the measured yield strength in both conditions. The experimental results of the relative elastic modulus and yield strength were compared to the analytical and simulation modeling analyses. The Gibson–Ashby theoretical model was established to predict the deformation behaviors of the lattice CoCrMo structures.
The coaxial core/shell composite electrospun nanofibers consisting of relaxor ferroelectric P(VDF-TrFE-CTFE) and ferroelectric P(VDF-TrFE) polymers are successfully tailored towards superior structural, mechanical, and electrical properties over the individual polymers. The core/shell-TrFE/CTFE membrane discloses a more prominent mechanical anisotropy between the revolving direction (RD) and cross direction (CD) associated with a higher tensile modulus of 26.9 MPa and good strength-ductility balance, beneficial from a better degree of nanofiber alignment, the increased density, and C-F bonding. The interfacial coupling between the terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for comparable full-frequency dielectric responses between the core/shell-TrFE/CTFE and pristine terpolymer. Moreover, an impressive piezoelectric coefficient up to 50.5 pm/V is achieved in the core/shell-TrFE/CTFE composite structure. Our findings corroborate the promising approach of coaxial electrospinning in efficiently tuning mechanical and electrical performances of the electrospun core/shell composite nanofiber membranes-based electroactive polymers (EAPs) actuators as artificial muscle implants.
16 August 2017 in Journal of Materials Chemistry C