The coaxial core/shell composite electrospun nanofibers consisting of relaxor ferroelectric P(VDF-TrFE-CTFE) and ferroelectric P(VDF-TrFE) polymers are successfully tailored towards superior structural, mechanical, and electrical properties over the individual polymers. The core/shell-TrFE/CTFE membrane discloses a more prominent mechanical anisotropy between the revolving direction (RD) and cross direction (CD) associated with a higher tensile modulus of 26.9 MPa and good strength-ductility balance, beneficial from a better degree of nanofiber alignment, the increased density, and C-F bonding. The interfacial coupling between the terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for comparable full-frequency dielectric responses between the core/shell-TrFE/CTFE and pristine terpolymer. Moreover, an impressive piezoelectric coefficient up to 50.5 pm/V is achieved in the core/shell-TrFE/CTFE composite structure. Our findings corroborate the promising approach of coaxial electrospinning in efficiently tuning mechanical and electrical performances of the electrospun core/shell composite nanofiber membranes-based electroactive polymers (EAPs) actuators as artificial muscle implants.

Coaxial core/shell electrospun nanofibers consisting of ferroelectric P(VDF-TrFE) and relaxor ferroelectric P(VDF-TrFE-CTFE) are tailor-made with hierarchical structures to modulate their mechanical properties with respect to their constituents. Compared with two single and the other coaxial membranes prepared in the research, the core/shell-TrFE/CTFE membrane shows a more prominent mechanical anisotropy between revolving direction (RD) and cross direction (CD) associated with improved resistance to tensile stress for the crystallite phase stability and good strength-ductility balance. This is due to the better degree of core/shell-TrFE-CTFE nanofiber alignment and the crystalline/amorphous ratio. The coupling between terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for phase stabilization, comparing the core/shell-TrFE/CTFE with the pristine terpolymer. Moreover, an impressive collective deformation mechanism of a two-length scale in the core/shell composite structure is found. We apply in-situ synchrotron X-ray to resolve the two-length scale simultaneously by using the small-angle X-ray scattering to characterize the nanofibers and the wide-angle X-ray diffraction to identify the phase transformations. Our findings may serve as guidelines for the fabrication of the electrospun nanofibers used as membranes-based electroactive polymers.

This study proposes an improved methodology based on life cycle assessment (LCA), which is used to calculate the carbon footprint of agriculture, provides a simple and feasible calculation path, and constructs a streamlined framework for calculating the carbon footprint based on the agricultural traceability system records. Using important economic crop (Onion) as research subject, and choose the largest planting area in R.O.C. (southern Taiwan) as a case study. A total of 64 farm production history records have been collected, includes all of farms certified with a traceable agricultural products (TAP) label. Through a detailed analysis of the traditional carbon footprint calculation method, found that agricultural traceability system records could replace the data source in carbon footprint verification (CFV) process, and system records could be used as activity data after being organized. With our method, no need to go through a complicated CFV process, just download the existing data on agricultural traceability system, can start calculating carbon footprint as soon as possible. To compared to traditional assessment method, results show a margin of error is less than 6% compared to traditional assessment methods. Advantages of improved method were be found, such as easy data acquisition, simplified calculation steps, and improved data transparency and accuracy. From statistical data, show that at least seven categories of carbon emission sources for carbon footprints, the most significant of carbon emission impact are fertilizers. The result of improved methodology based on life cycle assessment (LCA), show that using the improved methods can help promote the carbon footprint management efficiency of agricultural organizations such as Farmers’ Association or Agricultural Production Marketing Group, promptly monitor the carbon footprint status of their fields and adjust strategies to reduce carbon footprints in real-time, advancing towards the goal of net-zero carbon emissions.