Laser cladding is a promising surface treatment for refurbishing worn-out cast-iron brake rotors. Previous studies on laser-cladded brake rotors have demonstrated their extensively higher wear and greater airborne particle emissions, compared with traditional cast iron rotors. In order to overcome this, a commercial non-asbestos organic (NAO) brake material is tested against Fe-based laser-cladded and traditional cast-iron brake rotors. Two low-metallic brake pad materials are also tested as references. The materials’ coefficients of friction, specific wear rates and particle number concentrations are evaluated. The results indicate that the NAO brake material showed lower wear and had fewer particle emissions than the low-metallic brake materials when deployed against both cast iron and laser-cladded brake rotors. The NAO/laser-cladding friction pairing showed wear, particle concentration and fraction of fine particles (sub 1 μm) equivalent to those of the low-metallic/cast-iron friction pairing, creating significant potential for application in refurbishing worn-out cast-iron brake rotors.
Nanoparticles (ultrafine particles) are prevalent in various environments and raise concerns due to their potential health effects. In this study, we aimed to enhance the understanding of the toxicity associated with nanoparticles generated within subway systems. Specifically, we investigated nanoparticles produced using spark discharge from electrodes made of the same material as the third rail (which provides electric power), rail, and wheel components in the Stockholm subway system. Characterization revealed that the generated nanoparticles typically had a primary size of 6-10 nm and exhibited high agglomeration. They consisted mainly of iron, along with varying amounts of manganese and silicon. Despite having low oxidative potential, they showed some cytotoxicity and clearly induced DNA strand breaks in both dTHP-1 cells (monocyte-derived macrophages) and A549 cells (lung epithelial cells). In addition, gene expression analysis showed an upregulation of the cytokine IL-8 in dTHP-1 cells. No increased release of IL-1β, IL-8, IL-6, and TNF-a was noted. Consistent differences in toxicity between the nanoparticles from different materials were not observed. In conclusion, the results show that subway-related nanoparticles can cause DNA damage in cultured lung cells, but the inflammatory potential in terms of cytokine release was limited.
The manuscript investigates the synthesis and characterization of Aluminum alloys, comprising Si, Ti and B as alloying elements, as anodes for Al-ion batteries. Deposition/stripping measurements, impedance spectroscopy, metallographic, energy dispersive X-ray spectroscopy (EDXS) and X-ray diffraction (XRD) techniques unveil the complex interplay existing between the microstructures of the alloys and the obtained electrochemical performance. Prototype cycling and post-mortem battery failure analysis are performed as well. It is demonstrated that a remarkable improvement in the: a) oxidation/reduction currents and overvoltages; and b) interfacial stability with the electrolyte; can be obtained, with respect to a conventional Al anode.
Traffic-related air pollution is a major public health concern, contributing to respiratory and cardiovascular diseases worldwide. The aim of this study was to investigate the feasibility of using a mobile Air-Liquid Interface (ALI) system to assess the cytotoxicity and inflammatory potential of freshly generated PM2.5 (particle matter with aerodynamic diameter <2.5 μm) in a road tunnel in Stockholm. We hypothesized that cellular effects would be detectable at lower doses compared to submerged exposures. The mean particle dose in ALI was 1.4 ± 0.8 μg/cm2, whereas a wide range of doses was used for submerged exposures. ALI and submerged results showed that PM2.5 from the road tunnel did not affect the viability of A549 cells, whereas a significant and dose-dependent decrease in viability of dTHP-1 (in submerged exposure) was observed. Furthermore, in A549 in ALI a slight increase in inflammatory response (IL-8, IL-6, and IL-1β) was observed. In submerged exposure, the inflammatory response was clearer, particularly in the dTHP-1 cells. In conclusion, this study presents the first successfully conducted in situ ALI exposure in a road tunnel. The results demonstrate that dTHP-1 cells exhibit clear cytotoxic and inflammatory responses, while A549 show only weak effects. These findings suggest that co-cultures of A549 and dTHP-1 may be valuable in future ALI studies.