One of the solutions for overheating the interior in the summer without increasing energy consumption is the integration of phase change material (PCM) into interior plasters. However, adding PCM to plasters deteriorates their properties and thus their usability. The aim of this paper is to determine how the microencapsulated PCM affects the mechanical, thermal, and fire properties of plasters and how much PCM can be added to the plaster. Two sets of samples were prepared: in set S, part of the aggregate was replaced by PCM; and in set R, only PCM was added. The bulk density, flexural strength, compressive strength, tensile strength perpendicular to the surface, thermal conductivity coefficient, specific heat capacity, melting, and solidification temperatures and enthalpy were measured. A single-flame source fire test and a gross heat of combustion fire test were performed to determine the reaction to the fire class. The results show that with an increasing proportion of PCM, the strength of the samples of set R decreased more significantly than it did with the samples of set S. It was found that only up to about 10% PCM could be added to set R, while up to 30% PCM could be added to set S.
Alkali-activated materials are alternative building binders, where secondary raw materials are processed. The possibility of using landfilled waste materials in the building industry increases their potential application in construction practice, and they are therefore subject to extensive research, especially in recent years. This paper briefly summarizes the interesting results of an experiment aimed at verifying the possibility of applying cement by-pass dust (CBPD) in the preparation of alkali-activated materials. The research was focused on the possibilities of using these wastes for the preparation of small elements of garden architecture. This work also briefly summarized the interesting results of an experiment aimed at verifying the possibility of applying cement by-pass dust (CBPD) in the preparation of alkali-activated materials. In the experiment, a mixture of blast furnace granulated slag, fly ash and cement by-pass dust was alkali activated with sodium metasilicate.
The results of ground granulated blast furnace slag (GGBS) tests in alkali-activated systems show that, with its use, it is possible to produce promising materials with the required properties. Unfortunately, GGBS is becoming a scarce commodity on the market, so the effort is to partially replace its volume in these materials with other secondary materials, while maintaining the original properties. This paper focuses on a comparison of two basic types of mixtures. The first mixture was prepared only from ground granulated blast furnace slag (GGBS) and the second type of mixture was prepared with admixtures, where the admixtures formed a total of 30% (15% of the replacement was fly ash after denitrification—FA, and 15% of the replacement was cement by-pass dust—CBPD). These mixtures were prepared with varying amounts of activator and tested. The experiment monitored the development of strength over time and the influence of different types of aggressive environments on the strength characteristics. Thermal analysis and FTIR were used in the experiment to determine the degradation products. The paper provides an interesting comparison of the resistance results of different composites in aggressive environments and at the same time an evaluation of the behavior of individual mixtures in different types of aggressive environment. After 28 days of maturation, the highest strengths were obtained with mixtures with the lowest doses of activator. The difference in these compressive strengths was around 25% in favor of the mixtures with only GGBS; in the case of flexural strength, this difference was around 23%. The largest decreases in strength were achieved in the XA3 environment. This environment contains the highest concentration of sulfate ions according to the EN 206-1 standard. The decreases in compressive strength were 40–45%, compared to the same old reference series. The surface degraded due to sulfate ions. Calcium sulphate dihydrate was identified by FTIR, thermal analysis and SEM as a degradation product.
This article deals with the possibility of using cement by-pass dust (CBPD) in the garden architecture elements, specifically in curbs for park use. To increase the positive effect on the environment, other secondary raw materials were also used in the research, specifically blast furnace granulated slag and silica fly ash. Mixtures were based on alkali activation, where cement as a binder was 100% replaced by raw materials with waste properties. In the research, properties of used materials and also the basic physical-mechanical and durability properties of prepared mixtures were determined Part of the research focused on the effect of the tested beams on the grassland planted around the beams. Any significant negative impact was not registered, except for low pH increase of soil. Infrared spectroscopy and thermal analysis were performed on selected samples. Testing has shown that the products are in accordance with the Czech standard requirements for concrete curbs in garden architecture. The samples did not pass only the scaling test, which is, however, a condition for concrete curbs used for roads. For garden architecture this test is not required.
This article deals with the possibility of partial replacement of blast furnace slag (GGBFS) with fly ash after denitrification (FAD) in alkali-activated materials. Physical-mechanical and durability properties were tested, hydration reaction was monitored, and infrared spectroscopy was performed. Results were compared between mixtures prepared with fly ash without denitrification (FA), and also with a mixture based only on GGBFS. The basic result is that hybrid alkali-systems with FAD show similar trends to FA. The significant effect of fly ash is manifested in terms of its resistance to freeze-thaw processes. Reactions in a calorimeter show a slower development of reactions with increasing replacement of GGBFS due to the lower reactivity of the fly ash. Through testing the leaching resistance, a decrease in flexural strength was found. This may be due to the descaling of the main hydration product, C–(A)–S–H gel. After 28 days of maturation, compressive strengths of all monitored mixtures ranged from 96 to 102 MPa. The flexural strengths ranged from 6.8 to 8.0 MPa. After 28 days of maturation, the higher strengths reached mixtures without replacing GGBFS. In terms of resistance to freeze-thaw processes, the largest decrease (almost 20%) of flexural strength was achieved by a mixture with 30% of GGBFS replacement by FA. No fundamental differences were found for the mixtures in the FTIR analysis.
This article deals with the possibility of partial replacement of blast furnace slag with fly ash after denitrification by the Selective Non-Catalytic Reduction (SNCR) method in alkali-activated materials. In the experiment, the basic physical-mechanical properties and durability properties were tested, the hydration reaction was monitored in a calorimeter and infrared spectroscopy was performed. Results were compared between mixtures prepared with fly ash without denitrification and also with reference mixture based only on alkali-activated blast furnace slag. The basic result is the finding, that hybrid alkali-systems with fly ash after denitrification show similar trends as hybrid alkali-systems with fly ash without denitrification. The significant effect of fly ash is manifested especially in terms of resistance to freeze-thaw. The reactions in the calorimeter show a slower development of reactions with increasing replacement of slag by fly ash. In the case of testing resistance to leaching in demineralised water, a decrease of flexural strength was found, which corresponds to the conclusions of strength testing, that long-term deposition of bodies in water causes deterioration of mechanical properties.