Inorganic lead halide perovskite is one of the most excellent fluorescent materials, and it plays an essential role in high-definition display and visible light communication (VLC). Its photochromic properties and stability determine the final performance of light-emitting devices. However, efficiently synthesizing perovskite with high quality and stability remains a significant challenge. Here, we develop a facile and environmentally friendly method for preparing high-stability and strong-emission CsPbBr3/Cs4PbBr6 composites using ultrasonication and liquid paraffin. Tuning the contents of liquid paraffin, bright-emission CsPbBr3/Cs4PbBr6 composite powders with a maximum PLQY of 74% were achieved. Thanks to the protection of the Cs4PbBr6 matrix and liquid paraffin, the photostability, thermostability, and polar solvent stability of CsPbBr3/Cs4PbBr6-LP are significantly improved compared to CsPbBr3 quantum dots and CsPbBr3/Cs4PbBr6 composites that were prepared without liquid paraffin. Moreover, the fabricated CsPbBr3/Cs4PbBr6-LP-based WLEDs show excellent luminescent performance with a power efficiency of 129.5 lm/W and a wide color gamut, with 121% of the NTSC and 94% of the Rec. 2020, demonstrating a promising candidate for displays. In addition, the CsPbBr3/Cs4PbBr6-LP-based WLEDs were also demonstrated in a VLC system. The results suggested the great potential of these high-performance WLEDs as an excitation light source to achieve VLC.
7 April 2025 in Journal of Materials Processing Technology
The traditional data-driven models and pure physics models have been widely employed in quality prediction for additive manufacturing (AM). However, data-driven models rely on a large amount of labele...
Laser clad AlCr2FeCoNiNbx (x = 0, 0.5, 1.0, 1.5, 2.0, with x values in molar ratio) high-entropy alloy (HEA) coatings were fabricated on Q345 carbon steel. This study delves into the impact of Nb incorporation on the reciprocating sliding wear resistance of these laser clad coatings against a Φ6 mm silicon nitride ball. The microstructure of the as-clad AlCr2FeCoNiNbx coatings transformed from a single Face-Centered Cubic (FCC) solid solution (when x = 0) to the hypoeutectic state (when x = 0.5) and progressed to the hypereutectic state (when x ≥ 1.0). This evolution was marked by an increase in the Laves phase and a decrease in FCC. Consequently, the HEA coatings exhibited a gradually increasing Vickers hardness, reaching a peak at HV 820. Despite a decline in corrosion resistance, there was a notable enhancement in wear resistance, and the friction of the HEA coating could be reduced by Nb addition. The phase evolution induced by Nb addition led to a shift in the predominant wear mechanism from delamination wear to abrasive wear. The wear rate of Nb0.5 was impressively low, at 6.2 × 10−6 mm N−1 m−1 when reciprocating sliding under 20 N in air. In comparison to Nb0, Nb0.5 showcased 3.6, 7.2, and 6.5 times higher wear resistance at 5 N, 10 N, and 20 N, respectively. Under all applied loads, Nb1.5 has the lowest wear rate among all HEA coatings. This substantiates that the subtle introduction of Laves phase-forming elements to modulate hardness and oxidation ability proves to be an effective strategy for improving the wear resistance of HEA coatings.