Several studies have addressed the benefits of mentoring from the mentor’s perspective, especially those related to soft skills. However, to the best of our knowledge, there are no studies that either relate the mentoring in STEM areas with female role models or that analyze them from a data-mining perspective. In this work, a questionnaire was elaborated to address the mentor’s benefits related to soft skills and technical knowledge; afterward, a data-mining methodology was used to analyze the mentor’s perceptions related to female role models and STEM reinforcement. In addition, sentiment analysis was performed in order to determine the emotional polarity in the text used by the mentors to describe their mentoring experience. The results show that soft and technical skills are acquired by the mentors, and participating in mentoring programs allows them to perceive themselves as female role models. Additionally, by using decision trees, it was possible to determine the mentors’ characteristics that perceive a STEM reinforcement or that produce attraction. In addition, the results show that the general perception of the mentors’ experience was positive. Finally, the use of machine learning techniques, specifically data mining and sentiment analysis, allowed us to both confirm the results obtained in a qualitative way and to obtain new interesting results.
The green synthesis of metal oxide nanoparticles (NPs) offers an alternative to chemical procedures, which can be harmful to human health due to exposure to hazardous substances and harsh synthesis conditions. The following work synthesized titanium dioxide nanoparticles (TiO2 NPs) using a green synthesis method. As a precursor, food-grade TiO2 was used with blueberry extract. This approach makes the process safer, cheaper, and simpler, requiring minimal effort to achieve effective TiO2 NP synthesis. The TiO2 NP characterization was performed by solid-state techniques, such as Ultraviolet-visible (UV-Vis) spectroscopy, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). According to the XRD diffractograms, TiO2 NPs were obtained in the anatase phase with incidence peaks of 25.28 (101). TEM confirmed their pseudo-spherical shape with an average size of 170 nm. The 3.2 eV bandgap of TiO2 NPs enables UV absorption, making them ideal for efficient photocatalytic degradation under sunlight. On the other hand, the photocatalytic activity of TiO2 NPs was examined using malachite green (MG) dye as a pollutant model under direct sunlight. After 30 min, a degradation of 94% was achieved. The kinetic analysis identified parabolic diffusion and modified-Freundlich kinetics as primary mechanisms, emphasizing diffusion and adsorption in electron transfer. The main reactive oxygen species (ROS) involved in the photodegradation of MG dye were h+ and OH•.
Water contamination by synthetic dyes is a pressing environmental and social issue, particularly in the textile industry, which is among the largest consumers of freshwater and sources of wastewater pollutants. Malachite green (MG), a synthetic triphenylmethane dye, was selected as a model contaminant due to its persistence, toxicity, and international regulatory restrictions. In this study, a spinel-type cobalt–manganese oxide (CoMn2O4) photocatalyst was synthesized by calcination at 500 °C and characterized through X-ray diffraction (XRD) and transmission electron microscopy (TEM), confirming the formation of the spinel phase with nanoscale morphology. Photocatalytic activity was evaluated under visible-light irradiation using UV-Vis spectrophotometry to monitor MG degradation. Control experiments and scavenger assays identified hydroxyl radicals (•OH), superoxide anions (O2−), and photogenerated holes (h+) as the main reactive species. The catalyst achieved over 90% dye removal within 300 min and retained high activity over four consecutive reuse cycles, with only a slight decrease in efficiency from 97% to 94%. These results confirm both the efficiency and stability of CoMn2O4 under visible light. The study underscores the potential of this material as a sustainable option for wastewater treatment while contributing to environmental governance and supporting the fulfillment of the Human Right to Water.