Cost-effective activated carbons for CO₂ adsorption were developed from molasses using H₂SO₄, H₃PO₄, HCl, NaOH, and KOH as activating agents. At the temperature of 0 °C and a pressure of 1 bar, CO₂ adsorption equal to 5.18 mmol/g was achieved over activated carbon obtained by KOH activation. The excellent CO₂ adsorption of M-KOH can be attributed to its high microporosity. However, activated carbon prepared using HCl showed quite high CO₂ adsorption while having very low microporosity. The absence of acid species on the surface promotes CO₂ adsorption over M-HCl. The pore size ranges that are important for CO₂ adsorption at different temperatures were estimated. The higher the adsorption temperature, the more crucial smaller pores were. For 1 bar pressure and temperatures of 0, 10, 20, and 30 °C, the most important were pores equal and below: 0.733, 0.733, 0.679, and 0.536 nm, respectively.

Zeolite 13X (NaX) was modified through ion-exchange with alkali and alkaline earth metal cations. The degree of ion exchange was thoroughly characterized with ICP, EDS and XRF methods. The new method of EDS data evaluation for zeolites was presented. It delivers the same reliable results as more complicated, expensive, time consuming and hazardous ICP approach. The highest adsorption capacities at 273 K and 0.95 bar were achieved for materials containing the alkali metals in the following order K < Na < Li, respectively, 4.54, 5.55 and 5.94 mmol/g. It was found that it is associated with the porous parameters of the ion-exchanged samples. The Li_0.61Na_0.39X form of zeolite exhibited the highest specific surface area of 624 m²/g and micropore volume of 0.35 cm³/g compared to sodium form 569 m²/g and 0.30 cm³/g, respectively. The increase of CO₂ uptake is not related with deterioration of CO₂ selectivity. At room temperature, the CO₂ vs. N₂ selectivity remains at a very high stable level prior and after ion exchange in co-adsorption process (X_CO2 during adsorption 0.15; X_CO2 during desorption 0.95) within measurement uncertainty. Additionally, the Li_0.61Na_0.39X sample was proven to be stable in the aging adsorption-desorption tests (200 sorption-desorption cycles; circa 11 days of continuous process) exhibiting the CO₂ uptake decrease of about 6%. The exchange with alkaline earth metals (Mg, Ca) led to a significant decrease of SSA and micropore volume which correlated with lower CO₂ adsorption capacities. Interestingly, the divalent cations cause formation of mesopores, due to the relaxation of lattice strains.

The electronic structure of N-TiO₂ samples prepared by a sol-gel method was investigated by EPR (Electronic Paramagnetic Resonance) measurements and the energy-resolved distribution of electron traps. In EPR spectra, some of the resonance lines assigned to paramagnetic species of nitrogen and Ti³⁺ were detected. Sample prepared at 300 °C revealed the highest intensity line of the nitrogen paramagnetic centers, whereas that prepared at 400 °C showed a paramagnetic line for Ti³⁺. Measurements of the electron trap distribution showed higher density of electron traps for sample prepared at 400 °C than that at 300 °C. Sample prepared at 300 °C, which revealed the highest amount of nitrogen built in the titania in the interstitial position was the most active under visible light. It was evidenced that photocatalytic decomposition of acetaldehyde was dependent strongly on the BET surface area and electrokinetic potential of the photocatalyst surface. The UV content in the fluorescent lamp affected the yield of acetaldehyde decomposition.

The aim of the research was to determine how the admixture of nanosilica affects the structure and mechanical performance of cement concrete exposed to high temperatures (200, 400, 600, and 800 °C). The structural tests were carried out on the cement paste and concrete using the methods of thermogravimetric analysis, mercury porosimetry, and scanning electron microscopy. The results show that despite the growth of the cement matrix’s total porosity with an increasing amount of nanosilica, the resistance to high temperature improves. Such behavior is the result of not only the thermal characteristics of nanosilica itself but also of the porosity structure in the cement matrix and using the effective method of dispersing the nanostructures in concrete. The nanosilica densifies the structure of the concrete, limiting the number of the pores with diameters from 0.3 to 300 μm, which leads to limitation of the microcracks, particularly in the coarse aggregate-cement matrix contact zone. This phenomenon, in turn, diminishes the cracking of the specimens containing nanosilica at high temperatures and improves the mechanical strength.

This work presents studies on the preparation of porous carbon materials from waste biomass in the form of orange peels, coffee grounds, and sunflower seed husks. The preparation of activated carbons from these three waste materials involved activation with KOH followed by carbonization at 800 °C in an N₂ atmosphere. This way of obtaining the activated carbons is very simple and requires the application of only two reactants. Thus, this method is cheap, and it does not generate much chemical waste. The obtained activated carbons were characterized by XRD, SEM, XPS, and XRF methods. Moreover, the textural properties, acidity, and catalytic activity of these materials were descried. During catalytic tests carried out in the alpha-pinene isomerization process (the use of the activated carbons thus obtained in the process of alpha-pinene isomerization has not been described so far), the most active were activated carbons obtained from coffee grounds and orange peels. Generally, the catalytic activity of the obtained materials depended on the pore size, and the most active activated carbons had more pores with sizes of 0.7–1.0 and 1.1–1.4 nm. Moreover, the presence of potassium and chlorine ions in the pores may also be of key importance for the alpha-pinene isomerization process. On the other hand, the acidity of the surface of the tested active carbons did not affect their catalytic activity. The most favorable conditions for carrying out the alpha-pinene isomerization process were the same for the three tested activated carbons: temperature 160 °C, amount of the catalyst 5 wt.%, and reaction time 3 h. Kinetic studies were also carried out for the three tested catalysts. These studies showed that the isomerization over activated carbons from orange peels, coffee grounds, and sunflower seed husks is a first-order reaction.