Currently, the production of one ton of ordinary Portland cement (OPC) releases considerable amounts of CO₂ into the atmosphere. As the need and demand for this material grows exponentially, it has become a challenge to increase its production at a time when climate-related problems represent a major global concern. The two main CO₂ contributors in this process are fossil fuel combustion to heat the rotary kiln and the chemical reaction associated with the calcination process, in the production of the clinker, the main component of OPC. The current paper presents a critical review of the existent alternative clinker technologies (ACTs) that are under an investigation trial phase or under restricted use for niche applications and that lead to reduced emissions of CO₂. Also, the possibility of transition of clinker production from traditional rotary kilns based on fuel combustion processes to electrification is discussed, since this may lead to the partial or even complete elimination of the CO₂ combustion-related emissions, arising from the heating of the clinker kiln.