Persistent pharmaceutical pollutants (PPPs) have been identified as potential endocrine disruptors that mimic growth hormones when consumed at nanogram per litre to microgram per litre concentrations. Their occurrence in potable water remains a great threat to human health. Different conventional technologies developed for their removal from wastewater have failed to achieve complete mineralisation. Advanced oxidation technologies such as dielectric barrier discharges (DBDs) based on free radical mechanisms have been identified to completely decompose PPPs. Due to the existence of pharmaceuticals as mixtures in wastewater and the recalcitrance of their degradation intermediate by-products, no single advanced oxidation technology has been able to eliminate pharmaceutical xenobiotics. This review paper provides an update on the sources, occurrence, and types of pharmaceuticals in wastewater by emphasising different DBD configurations previously and currently utilised for pharmaceuticals degradation under different experimental conditions. The performance of the DBD geometries was evaluated considering various factors including treatment time, initial concentration, half-life time, degradation efficiency and the energy yield (G₅₀) required to degrade half of the pollutant concentration. The review showed that the efficacy of the DBD systems on the removal of pharmaceutical compounds depends not only on these parameters but also on the nature/type of the pollutant.

The need for rare earths elements (REEs) in high tech electrical and electronic based materials are vital. In the global economy, deposits of natural REEs are limited except for countries such as China, which has prompted current attempts to seek alternative resources of REEs. This increased the dependence on major secondary rare earth-bearing sources such as scrap alloy, battery waste, spent catalysts, fly ash, spent magnets, waste light-emitting diodes (LEDs), and phosphogypsum (PG) for a substantial recovery of REEs for use. Recycling of REEs from these alternative waste sources through hydrometallurgical processes is becoming a sustainable and viable approach due to the low energy consumption, low waste generation, few emissions, environmentally friendliness, and economically feasibility. Industrial wastes such as the PG generated from the production of phosphoric acid is a potential secondary resource of REEs that contains a total REE concentration of over 2000 mg/kg depending upon the phosphate ore from which it is generated. Due to trace concentration of REEs in the PG (normally < 0.1% wt.) and their tiny and complex occurrence as mineral phases the recovery process of REE from PG would be highly challenging in both technology and economy. Various physicochemical pre-treatments approaches have been used up to date to up-concentrate REEs from PG prior to their extraction. Methods such as carbonation, roasting, microwave heating, grinding or recrystallization have been widely used for this purpose. This present paper reviews recent literature on various techniques that are currently employed to up-concentrate REs from PG to provide preliminary insight into further critical raw materials recovery. In addition, the advantages and disadvantages of the different strategies are discussed as avenues for realization of REE recovery from PG at a larger scale. In all the different approaches, recrystallization of PG appears to show promising advantages due to both high REE recovery as well as the pure PG phase that can be obtained.

Microplastic (MPs) pollution has become a subject of environmental concern due to its wide ubiquity in the environment. Microplastics are possible sources of other hazardous chemicals to aquatic organisms due to their composition and sorption properties. In this study, MPs occurrence in water and sediment samples of the Plankenburg River, Western Cape, South Africa was investigated. The physicochemical characterization of the river water was done onsite. 30 L water samples were collected and filtered in 10 L triplicates through a 250 μm mesh onsite using a metal bucket. An additional 12 L sample was collected and filtered in 4 L triplicates through 20 μm mesh in the laboratory. The extraction of MPs from water in the laboratory was by density separation. Sediment samples were also collected at the selected sites, oven-dried and microplastics in the laboratory. Sampling was conducted over four seasons - spring, summer, autumn, and winter. Microplastics were classified by visual observation and Fourier Transform Infrared Spectroscopy (FTIR-ATR). The seasonal distribution of MPs in the surface water samples varied across all sites. However, spring samples had the highest MPs occurrence (5.13 ± 6.62 MP/L) and the least, in autumn (1.52 ± 2.54 MP/L). The MPs in sediment samples were observed in spring (1587.50 ± 599.32 MP/kg). Fibres were the most dominant microplastic particle type (shape), with a size range of 500-1000 μm at the different sites. The infrared spectroscopic analysis confirmed the dominant polymer type to be polyethylene. This study provides an understanding of the microplastic occurrence in the Plankenburg River system and gives a baseline for future monitoring and assessment of water and sediment in the South African freshwater systems.