This work presents the natural radioactivity distribution of 21 surface soil samples taken in the city of Novi Sad, Serbia. The analysis for radioactivity was performed using a gas low-level proportional counter for gross alpha and gross beta activity, while the specific activities of radionuclides were determined using HPGe detectors. The gross alpha activity of 20 samples was below the minimum detectable concentration (MDC), while in 1 sample it was 243 Bq kg⁻¹; the gross beta activity ranged from the MDC (11 samples) to 566 Bq kg⁻¹. The gamma spectrometry measurements showed naturally occurring radionuclides ²²⁶Ra, ²³²Th, ⁴⁰K, and ²³⁸U in all investigated samples, with average values (Bq kg⁻¹) of 33.9, 36.7, 513.8, and 34.7, respectively. Natural radionuclide ²³⁵U was detected in 18 samples with activity concentrations in the range of 1.3–4.1 Bq kg⁻¹, while in the other 3 samples, the values were below the MDC. The artificial ¹³⁷Cs radionuclide was detected in 90 percent of the samples, with a maximum value of 21 Bq kg⁻¹, while the other artificial radionuclides were not detected. Based on the obtained concentrations of natural radionuclides, hazard indexes were estimated, and radiological health risk was assessed. The results present the absorbed gamma dose rate in the air, annual effective dose, radium equivalent activity, external hazard index, and lifetime cancer risk.

Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.

Forests, with a large coverage of lands area, represent important ecosystem. They have greater ability to absorb atmospheric pollutant, including radionuclides compared to other vegetation types. Thus it is important to monitor radionuclides concentration in forest ecosystems. The results of the first gamma-spectrometric measurements in 16500 ha large region of South-western Serbia are presented. It is investigated activity concentrations of 40K, 137Cs and 210Pb in different deciduous and evergreen trees in the region. For all investigated isotopes, it was observed tendency that the smallest activity concentrations in average were found in tree stem, than in leaves, while the highest ones were in soil. Statistical analysis did not show any differences between activity concentrations of leaves and needles, showing that both leaves and needles could be equally well used as a biomonitors.