In this study, the arc evaporation of pure graphite and composite cathodes with small amounts of metals (Mo, Fe) or nonmetals (B, Si) was investigated by means of a laser-arc process. Both specific aspects of the arc evaporation and the effects on the deposition of the doped and undoped carbon coatings were studied. The deposition rate, the chemical composition and the mechanical properties of the generated films were evaluated. In addition, the dependence of the deposition rate and the composition on the height position of the substrates in relation to the cathode were also the subject of the investigations. Finally, the erosion rate and the arc spot behavior on the cathode were analyzed. It is shown that homogeneously doped (t)a-C:X coatings can be reliably synthesized with the laser-arc technique. There are differences in the various properties of the coatings and the deposition rate. The latter is attributed in particular to the erosion behavior of the cathodes.

In recent years, high-entropy alloys have attracted increasing scientific interest. Due to their promising combination of properties, such as high hardness and high temperature stability, they are attractive for use as tool coatings for machining applications, to give but one example. Previous studies often focused on layer deposition using magnetron sputtering. Comparatively little research has been carried out to date on coating deposition using direct current cathodic vacuum arc deposition (CAE), with higher achievable rates and almost completely ionized plasmas. The aim of this work is to investigate (HfNbTaTiZr)N-coatings produced by CAE. The nitrogen content was varied and the effects on the coating properties were investigated. Changing the N₂/(N₂ + Ar) ratio between 0.1 and 1.0 and varying the working pressure in the chamber from 2 Pa to 5 Pa resulted in variations of the nitrogen content of the coatings, ranging from 30 at% to 50 at%. Although different microstructures of the coatings were obtained, there was only a minor influence on the hardness and Young’s modulus.

The edge area is especially essential for cutting tools, since this is the contact zone between the work piece and the tool. Hard coatings (PVD or CVD coatings) can protect the edge against wear and they are commonly used. The geometries of the cutting edges change during the coating process, with the edge radius increasing. Therefore, the film thickness is limited and the initial radius of the uncoated tool must be smaller than the target radius of the coated edge. A new coating process based on vacuum arc PVD was developed to overcome this limitation. The film growth at the edges can be properly controlled by means of selected coating materials and process conditions. Thus, it is possible to grow edges sharper than the initial edge geometry. Different substrates were coated with different coating systems. Parameters such as the bias voltage, coating pressure, and initial radius were varied within this work. It was found that the application of a bias voltage is crucial for the generation of sharp edges. It was also found that the edge sharpening caused by coatings works best on samples with an initial radius of around 15 µm.