In this study, both the plasma process of filtered laser-arc evaporation and the resulting properties of tetrahedral amorphous carbon coatings are investigated. The energy distribution of the plasma species and the arc spot dynamics during the arc evaporation are described. Different ta-C coatings are synthesized by varying the bias pulse time and temperature during deposition. An increase in hardness was observed with the increased overlapping of the bias and arc pulse times. External heating resulted in a significant loss of hardness. A strong discrepancy between the in-plane properties and the properties in the film normal direction was detected specifically for a medium temperature of 120 °C during deposition. Investigations using electron microscopy revealed that this strong anisotropy can be explained by the formation of nanocrystalline graphite areas and their orientation toward the film’s normal direction. This novel coating type differs from standard amorphous a-C and ta-C coatings and offers new possibilities for superior mechanical behavior due to its combination of a high hardness and low in-plane Young’s Modulus.

In this study, the arc evaporation of pure graphite and composite cathodes with small amounts of metals (Mo, Fe) or nonmetals (B, Si) was investigated by means of a laser-arc process. Both specific aspects of the arc evaporation and the effects on the deposition of the doped and undoped carbon coatings were studied. The deposition rate, the chemical composition and the mechanical properties of the generated films were evaluated. In addition, the dependence of the deposition rate and the composition on the height position of the substrates in relation to the cathode were also the subject of the investigations. Finally, the erosion rate and the arc spot behavior on the cathode were analyzed. It is shown that homogeneously doped (t)a-C:X coatings can be reliably synthesized with the laser-arc technique. There are differences in the various properties of the coatings and the deposition rate. The latter is attributed in particular to the erosion behavior of the cathodes.

Vacuum and air atmospheres impose very different requirements on tribological-loaded contacts, which usually require different surface materials. While hard tetrahedral amorphous carbon (ta-C) coatings provide good tribological properties in air, soft coatings such as molybdenum disulfide (MoS2) work well in a vacuum. Tribological performance in the respective other environment, however, is poor. In this work, the combination of laser microstructured (direct laser interference patterning) steel substrates and the deposition of ta-C and MoSx coatings with vacuum arc evaporation (LaserArc™) was studied, resulting in steel/DLIP, steel/DLIP/ta-C, steel/DLIP/MoSx, steel/DLIP/ta-C/MoSx, and steel/MoSx surface combinations. The tribological properties were studied using a ball-on-disk tribometer with a steel ball counter body in air and in a vacuum (p < 5 × 10⁻⁷ mbar). The type of the topmost coating governed their tribological properties in the respective atmosphere, and no general beneficial influence of the microstructure was found. However, steel/DLIP/ta-C/MoSx performed best in both conditions and endured the highest contact pressure, which is attributed to the mechanical support of the ta-C coating and MoSx reservoir in the remaining structure, as evidenced by Raman spectroscopy. The findings suggest that such combination allows for surfaces bearing a high load capacity that can be applied in both a vacuum and in air, for example, in multi-use space applications.

In this study, we analyze the extent to which thin hard coatings can serve as tribological protective layers for the selected plastic substrate materials PA12 (polyamide 12) und PEEK (polyetheretherketone), with and without fiber reinforcement. The approximately 1 µm thick coating variants ta-C, ta-C:N, and ta-C:B, which were applied using the laser arc process, are investigated. In oscillating sliding wear tests against a steel ball in an air atmosphere without lubricant, the wear of the coating and counter body is compared to analogous coating variants applied in parallel to AISI 52100 steel. The ta-C-based coatings show good adhesion strength and basic suitability as wear protection layers on the plastic substrates in the tribological tests. However, there are variations depending on the coating type and substrate material. The use of a Cr interlayer and its thickness also plays an important role. It is demonstrated that by coating under conditions where the uncoated plastic substrate would normally fail, a similarly good performance as with analogously coated steel substrates can be achieved by ta-C:N.