In this work, the electrospinning technique is used for the fabrication of electrospun functional fibers with desired properties in order to show a superhydrophobic behavior. With the aim to obtain a coating with the best properties, a design of experiments (DoE) has been performed by controlling several inputs operating parameters, such as applied voltage, flow rate, and precursor polymeric concentration. In this work, the reference substrate to be coated is the aluminum alloy (60661T6), whereas the polymeric precursor is the polyvinyl chloride (PVC) which presents an intrinsic hydrophobic nature. Finally, in order to evaluate the coating morphology for the better performance, the following parameters—such as fiber diameter, surface roughness (Ra, Rq), optical properties, corrosion behavior, and wettability—have been deeply analyzed. To sum up, this is the first time that DoE has been used for the optimization of superhydrophobic or anticorrosive surfaces by using PVC precursor for the prediction of an adequate surface morphology as a function of the input operational parameters derived from electrospinning process with the aim to validate better performance.

The expansion and low cost of additive manufacturing technologies have led to a revolution in the development of materials used by these technologies. There are several varieties of materials that can be used in additive manufacturing by fused deposition modeling (FDM). However, some of the properties of these materials are unknown or confusing. This article addresses the need to know the thermal conductivity in different filaments that this FDM technology uses, because there are multiple applications for these additive manufacturing products in the field of thermal insulation. For the study of thermal conductivity, the DTC-25 commercial conductivity measurement bench was used, where the tests were carried out on a set of seven different materials with 100% fabrication density—from base materials such as acrylonitrile butadiene styrene (ABS) or polylactic acid (PLA), to materials with high mechanical and thermal resistance such as thermoplastic polyurethane (TPU), polyether ether ketone (PEEK), and high-performance polyetherimide thermoplastic (ULTEM), to materials with metal inclusions (aluminum 6061) that would later be subjected to thermal after-treatments. This study shows how the parts manufactured with aluminum inclusions have a higher thermal conductivity, at 0.40 ± 0.05 W/m·K, compared to other materials with high mechanical and thermal resistance, such as TPU, with a conductivity of 0.26 ± 0.05 W/m·K.

The most important difficulties when the behaviour of a part that is subjected to external mechanical forces is simulated deal with the determination of both the material thermo-mechanical properties and its boundary conditions. The accuracy of the results obtained from the simulation is directly related to the knowledge of the flow stress curve. Therefore, the determination of a material flow rule which is valid for both a wide temperature range and different initial deformation conditions in the starting material presents a great deal of interest when simulation results close to the experimental values are required to be obtained. In this present study, a novel flow stress curve is proposed that is able to accurately predict the behaviour of both materials with no previous accumulated strain and materials that have been previously subjected to severe plastic deformation processes. Moreover, it is possible to use it both for hot and cold working. The results are analysed in a wide test temperature range, which varies from room temperature to 300 °C, and from material previously processed by angular channel extrusion or with no previous strain accumulated. It is shown that the flow rule proposed is effective to model the material behaviour in a wide temperature range and it makes it possible to take the recrystallization phenomena that appear in previously deformed materials into account. In addition, the results obtained are compared with those predicted by other flow rules that exist in the prior literature. Furthermore, the study is complemented with finite element simulations and with a comparison between simulation and experimental results.

In the present study, the wear behaviour of two aluminium alloys (AA-5754 and AA-5083) is analysed where these have been previously processed by severe plastic deformation (SPD) with equal channel angular pressing (ECAP). In order to achieve the objectives of this study, several disks made of these alloys are manufactured by isothermal forging from different initial states. The microstructures of the initial materials analysed in this study have different accumulated deformation levels. In order to compare the properties of the nanostructured materials with those which have not been ECAP-processed, several disks with a height of 6 mm and a diameter of 35 mm are manufactured from both aluminium alloys (that is, AA-5754 and AA-5083) isothermally forged at temperatures of 150 and 200 °C, respectively. These thus-manufactured disks are tested under a load of 0.6 kN, which is equivalent to a stress mean value of 18 MPa, and at a rotational speed of 200 rpm. In order to determine the wear values, the disks are weighed at the beginning, at 10,000 revolutions, at 50,000 revolutions and at 100,000 revolutions, and then the volume-loss values are calculated. This study was carried out using specific equipment, which may be considered to have a block-on-ring configuration, developed for testing in-service wear behaviour of mechanical components. From this, the wear coefficients for the two materials at different initial states are obtained. In addition, a comparison is made between the behaviour of the previously ECAP-processed aluminium alloys and those that are non-ECAP-processed. A methodology is proposed to determine wear coefficients for the aluminium alloys under consideration, which may be used to predict the wear behaviour. It is demonstrated that AA-5754 and AA-5083 aluminium alloys improve wear behaviour after the ECAP process compared to that obtained in non-ECAP-processed materials.

In this work, a one-step electrospinning technique has been implemented for the design and development of functional surfaces with a desired morphology in terms of wettability and corrosion resistance by using polycaprolactone (PCL) and zinc oxide nanoparticles (ZnO NPs). The surface morphology has been characterized by confocal microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM) and water contact angle (WCA), whereas the corrosion resistance has been evaluated by Tafel polarization curves. Strict control over the input operational parameters (applied voltage, feeding rate, distance tip to collector), PCL solution concentration and amount of ZnO NPs have been analyzed in depth by showing their key role in the final surface properties. With this goal in mind, a design of experiment (DoE) has been performed in order to evaluate the optimal coating morphology in terms of fiber diameter, surface roughness (Ra), water contact angle (WCA) and corrosion rate. It has been demonstrated that the solution concentration has a significant effect on the resultant electrospun structure obtained on the collector with the formation of beaded fibers with a higher WCA value in comparison with uniform bead-free fibers (dry polymer deposition or fiber-merging aspect). In addition, the presence of ZnO NPs distributed within the electrospun fibers also plays a key role in corrosion resistance, although it also leads to a decrease in the WCA. Finally, this is the first time that an exhaustive analysis by using DoE has been evaluated for PCL/ZnO electrospun fibers with the aim to optimize the surface morphology with the better performance in terms of corrosion resistance and wettability.