Our world is facing an environmental crisis that is driving scientists to research green and smart solutions in terms of the use of renewable energy sources and low polluting technologies. In this framework, photovoltaic (PV) technology is one of the most worthy of interest. Dye-sensitized solar cells (DSSCs) are innovative PV devices known for their encouraging features of low cost and easy fabrication, good response to diffuse light and colour tunability. All these features make DSSCs technology suitable for being applied to the so-called agrovoltaic field, taking into account their dual role of filtering light and supporting energy needs. In this project, we used 40 DSSC Z-series connected modules with the aim of combining the devices’ high conversion efficiency, transparency and robustness in order to test them in a greenhouse. A maximum conversion efficiency of 3.9% on a 221 cm² active area was achieved with a transparency in the module’s aperture (312.9 cm²) area of 35%. Moreover, different modules were stressed at two different temperature conditions, 60 °C and 85 °C, and under light soaking at the maximum power point, showing a strong and robust stability for 1000 h. We assembled the fabricated modules to form ten panels to filter the light from the roof of the greenhouse. We carried out panel measurements in outdoor and greenhouse environments in both sunny and cloudy conditions to find clear trends in efficiency behaviour. A maximum panel efficiency in outdoor conditions of 3.83% was obtained in clear and sunny sky conditions.

An optimization work on dye-sensitized solar cells (DSSCs) based on both artificial and natural dyes was carried out by a fine synthesis work embedding gold nanoparticles in a TiO₂ semiconductor and perfecting the TiO₂ particle sizes of the scattering layer. Noble metal nanostructures are known for the surface plasmon resonance peculiarity that reveals unique properties and has been implemented in several fields such as sensing, photocatalysis, optical antennas and PV devices. By embedding gold nanoparticles in the mesoporous TiO₂ layer and adding a scattering layer, we were able to boost the power conversion efficiency (PCE) to 10.8%, using an organic ruthenium complex. The same implementation was carried out using a natural dye, betalains, extracted from Sicilian prickly pear. In this case, the conversion efficiency doubled from 1 to 2% (measured at 1 SUN illumination, 100 mW/cm² under solar simulation irradiation). Moreover, we obtained (measured at 0.1 SUN, 10 mW/cm² under blue light LED irradiation) a record efficiency of 15% with the betalain-based dye, paving the way for indoor applications in organic natural devices. Finally, an attempt to scale up the system is shown, and a betalain-based- dye-sensitized solar module (DSSM), with an active area of 43.2 cm² and a PCE of 1.02%, was fabricated for the first time.