The paper presents and discusses modern methods and technologies of CO₂ capture (pre-combustion capture, post-combustion capture, and oxy-combustion capture) along with the principles of these methods and examples of existing and operating installations. The primary differences of the selected methods and technologies, with the possibility to apply them in new low-emission energy technologies, were presented. The following CO₂ capture methods: pre-combustion, post-combustion based on chemical absorption, physical separation, membrane separation, chemical looping combustion, calcium looping process, and oxy-combustion are discussed in the paper. Large-scale carbon capture utilization and storage (CCUS) facilities operating and under development are summarized. In 2021, 27 commercial CCUS facilities are currently under operation with a capture capacity of up to 40 Mt of CO₂ per year. If all projects are launched, the global CO₂ capture potential can be more than ca. 130–150 Mt/year of captured CO₂. The most popular and developed indicators for comparing and assessing CO₂ emission, capture, avoiding, and cost connected with avoiding CO₂ emissions are also presented and described in the paper.

The article presents results of thermodynamic analysis using a zero-dimensional mathematical models of a negative CO₂ emission power plant. The developed cycle of a negative CO₂ emission power plant allows the production of electricity using gasified sewage sludge as a main fuel. The negative emission can be achieved by the use this type of fuel which is already a “zero-emissive” energy source. Together with carbon capture installation, there is a possibility to decrease CO₂ emission below the “zero” level. Developed models of a novel gas cycle which use selected codes allow the prediction of basic parameters of thermodynamic cycles such as output power, efficiency, combustion composition, exhaust temperature, etc. The paper presents results of thermodynamic analysis of two novel cycles, called PDF0 and PFD1, by using different thermodynamic codes. A comparison of results obtained by three different codes offered the chance to verify results because the experimental data are currently not available. The comparison of predictions between three different software in the literature is something new, according to studies made by authors. For gross efficiency (54.74%, 55.18%, and 52.00%), there is a similar relationship for turbine power output (155.9 kW, 157.19 kW, and 148.16 kW). Additionally, the chemical energy rate of the fuel is taken into account, which ultimately results in higher efficiencies for flue gases with increased steam production. A similar trend is assessed for increased CO₂ in the flue gas. The developed precise models are particularly important for a carbon capture and storage (CCS) energy system, where relatively new devices mutually cooperate and their thermodynamic parameters affect those devices. Proposed software employs extended a gas–steam turbine cycle to determine the effect of cycle into environment. First of all, it should be stated that there is a slight influence of the software used on the results obtained, but the basic tendencies are the same, which makes it possible to analyze various types of thermodynamic cycles. Secondly, the possibility of a negative CO₂ emission power plant and the positive environmental impact of the proposed solution has been demonstrated, which is also a novelty in the area of thermodynamic cycles.

Direct contact heat exchangers can be smaller, cheaper, and have simpler construction than the surface, shell, or tube heat exchangers of the same capacity and can operate in evaporation or condensation modes. For these reasons, they have many practical applications, such as water desalination, heat exchangers in power plants, or chemical engineering devices. This paper presents a comprehensive review of experimental and numerical activities focused on the research about direct condensation processes and testing direct contact condensers on the laboratory scale. Computational Fluid Dynamics (CFD) methods and CFD solvers are the most popular tools in the numerical analysis of direct contact condensers because of the phenomenon’s complexity as multiphase turbulent flow with heat transfer and phase change. The presented and developed numerical models must be carefully calibrated and physically validated by experimental results. Results of the experimental campaign in the laboratory scale with the test rig and properly designed measuring apparatus can give detailed qualitative and quantitative results about direct contact condensation processes. In this case, the combination of these two approaches, numerical and experimental investigation, is the comprehensive method to deeply understand the direct contact condensation process.

The liquid-driven two-phase ejector condenser is the object of the numerical investigation. The spray-ejector condenser is one of the critical components of the developed gas power plant with negative CO2 emission. The task of the ejector is to entrain exhaust gas and condense steam contained in it. Computational fluid dynamics (CFD) modeling allows analyzing complex phenomena and predicting the influence of a wide range of operating parameters on the local structure of the multiphase flow with condensation. The geometrical model of the ejector was designed to provide efficient steam condensation and generate sub-pressure region at the gas inlet. The 2D, axisymmetric CFD model was created using simcenter star ccm+ software. The multiphase mixture model was used to take into account two-phase flow. Turbulent flow was computed using k–ω SST model. Direct contact condensation of steam was calculated using two different approaches: the Spalding/evaporation model and the thermally-driven boiling/condensation model. The influence of various gas inlet velocities and the presence of CO2 on the operation of the ejector condenser were investigated based on scalar fields and charts representing changes in the most important variables along the flow path. The condensation is the most intense in the suction chamber. The boiling/condensation model predicts lower suction pressure and higher condensation effectivity than Spalding/evaporation model. The CO2 considerably affects the pressure and temperature distributions and reduces the condensation rate.

The paper deals with the problem of accurate measuring techniques and experimental research methods for performance evaluation of direct contact jet-type flow condensers. The nominal conditions and range of temperature, pressure and flow rate in all characteristic points of novel test rig installation were calculated using the developed model. Next, the devices for measurement of temperature, pressure and flow rate in a novel test rig designed for testing the two-phase flow spray ejector condensers system (SEC) were studied. The SEC can find application in gas power cycles as the device dedicated to condensing steam in exhaust gases without decreasing or even increasing exhaust gas pressure. The paper presents the design assumptions of the test rig, its layout and results of simulations of characteristic points using developed test rig models. Based on the initial thermal and flow conditions, the main assumptions for thermal and flow process monitoring were formulated. Then, the discussion on commercially available measurement solutions was presented. The basic technical parameters of available sensors and devices were given, discussed with details.

The application of a two-phase ejector allows for the mixing of liquid and gas and provides effective heat transfer between phases. The aim of the study is a numerical investigation of the performance of a water-driven, condensing two-phase ejector. The research was performed using CFD methods, which can provide an opportunity to analyze this complex phenomenon in 2D or 3D. The 2D axisymmetric model was developed using CFD software Siemens StarCCM+ 2022.1.1. The Reynolds-Averaged Navier–Stokes (RANS) approach with the Realisable k-ε turbulence model was applied. The multiphase flow was calculated using the mixture model. The boiling/condensation model, where the condensation rate is limited by thermal diffusion, was applied to take into account direct contact condensation. Based on the mass balance calculations and developed pressure and steam volume fraction distributions, the ejector performance was analyzed for various boundary conditions. The influence of the suction pressure (range between 0.812 and 0.90) and the steam mass flow rate (range between 10 g/s and 25 g/s) is presented to investigate the steam condensation phenomenon inside the ejector condenser. The provided mixture of inert gas (CO₂) with steam (H₂O) in the ejector condenser was investigated also. The weakening of the steam condensation process by adding CO₂ gas was observed, but it is still possible to achieve effective condensation despite the presence of inert gas.