For managing the freshwater in the worldwide coastal aquifers, it is imperative to understand the hydrogeochemical processes and flow patterns in the mixing freshwater/saltwater zone. The Egyptian Nile Delta aquifer is a typical example. The management of seawater intrusion (SWI) requires detailed investigations of the intrusion wedge and the dynamic processes in the mixing zone. Thus, a multidisciplinary approach was applied based on holistic hydrogeochemical, statistical analysis, and DC resistivity measurements to investigate the lateral and vertical changes in groundwater characteristics undergoing salinization stressor. The results of cross plots and ionic deviations of major ions, hydrochemical facies evolution diagram (HFE-D), and seawater mixing index (SMI) were integrated with the resistivity results to show the status of the SWI where the intrusion phase predominates in ~2/3 of the study are (~70 km radius) and the compositional thresholds of Na, Mg, Cl, and SO₄ are 600, 145, 1200, and 600 mg/L, respectively, indicating that the wells with higher concentrations than these thresholds are affected by SWI. Moreover, the results demonstrate the efficiency of combining hydrogeochemical facies from heatmap and resistivity investigations to provide a large-scale characterization of natural and anthropogenic activities controlling aquifer salinization to support decision-makers for the long-term management of coastal groundwater.

The objective of the current study is to investigate the hydrogeochemistry of the Quaternary groundwater and evaluating its suitability for drinking and irrigation needs using statistical analysis, water quality indicators and physicochemical parameters, in west of the Nile Delta, Egypt. The study area has high population growth and agricultural activities, which require groundwater protection, and predicting probable environmental problems. For these reasons, 54 groundwater samples were collected during April 2021. Hierarchical cluster analysis, Pearson, and factor analysis used for statistical analysis. Biplots, Gibbs and Piper diagrams were used to infer the geochemical processes controlling groundwater chemistry. The groundwater is affected by silicate weathering, reveres ion exchange, dissolution of CO₂, and recharge from the Nile. According to the WQI_CCME drinking value, the groundwater ranged between fair to marginal water quality. The distribution of integrated-weight water quality index of the samples, showed that it is excellent for irrigation (< 25). The nine physicochemical parameters sodium percent (Na%), permeability index, sodium adsorption ratio, Kelley Index, residual sodium carbonate, magnesium hazard, Potential Salinity, Corrosive Ratio and Chloro-alkaline Indices revealed that most of the groundwater are of good quality and can be safely used for agricultural activities, albeit few samples due the west needs some treatment. It is recommended to minimize the fertilizers and nutrients use to decrease the anthropogenic impact on the groundwater. The reuse of irrigation water without treatment should be limited. As well, the pumping rates should be controlled to avoid aquifer salinization.

Wadi El Raiyan is a great depression located southwest of Cairo in the Western Desert of Egypt. Lake Qarun, located north of the study area, is a closed basin with a high evaporation rate. The source of water in the lake is agricultural and municipal drainage from the El Faiyum province. In 1973, Wadi El Raiyan was connected with the agricultural wastewater drainage system of the Faiyum province and received water that exceeded the capacity of Lake Qarun. Two hydrogeological regimes have been established in the area: (i) higher cultivated land and (ii) lower Wadi El Raiyan depression lakes. The agricultural drainage water of the cultivated land has been collected in one main drain (El Wadi Drain) and directed toward the Wadi El Raiyan depression, forming two lakes at different elevations (upper and lower). In the summer of 2012, the major chemical components were studied using data from 36 stations distributed over both hydrogeological regimes in addition to one water sample collected from Bahr Youssef, the main source of freshwater for the Faiyum province. Chemical analyses were made collaboratively. The major ion geochemical evolution of the drainage water recharging the El Raiyan depression was examined. Geochemically, the Bahr Youssef sample is considered the starting point in the geochemical evolution of the studied surface water. In the cultivated area, major-ion chemistry is generally influenced by chemical weathering of rocks and minerals that are associated with anthropogenic inputs, as well as diffuse urban and/or agricultural drainage. In the depression lakes, the water chemistry generally exhibits an evaporation-dependent evolutionary trend that is further modified by cation exchange and precipitation of carbonate minerals.

This study integrates multivariate statistical analysis and hydrogeochemical modeling to investigate the processes controlling the groundwater composition of a shallow aquifer where increased pumping rates and anthropogenic impacts were prevalent. Eighteen groundwater samples were collected and analyzed for major elements and selected heavy metals. The data were classified on the basis of multivariate statistical analysis into three clusters: C1 (Na-Cl facies), C2 (Ca-SO₄ facies), and C3 (Ca-HCO₃ facies). The application of factor analysis gave four factors affecting the groundwater chemistry, namely the salinization factor, anthropogenic/secondary enrichment factor, the secondary and the micro-nutrient fertilizers, and the aluminum fertilizer factor. The hydrogeochemical study of the groundwater revealed that the processes controlling the groundwater chemistry in the study area are mainly affected by the groundwater occurrence either to the east or to the west of Bahr Youssef Canal. Generally, the dominant hydrogeochemical processes affecting the groundwater are silicate weathering, ion exchange, irrigation return flow, gypsum applications in soil, and evaporation. The groundwater quality evaluation shows that water quality varies from fair to excellent for drinking purposes, where the best water is located in the northern and central parts of the study area. The suitability of groundwater for irrigation was evaluated using several indices indicating that groundwater is suitable for irrigation in the northwest and western parts of the study area. As some groundwater samples lie in high salinity classes on the US Salinity diagram, it is recommended to use this water for plants with good salt tolerance under good drainage conditions. The integration between the statistical and geochemical tools helps reveal the dominant processes through data reduction and classification.